Citation: SHI Yan-Hua, MENG Hui-Min. Electrochemical Behavior of IrO₂ Electrodes in the Anodic Electrodeposition of MnO₂[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 461-467. doi: 10.3866/PKU.WHXB20110216 shu

Electrochemical Behavior of IrO₂ Electrodes in the Anodic Electrodeposition of MnO₂

SHI Yan-Hua ^1,2, ,
MENG Hui-Min ¹

1.
1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. Center for Corrosion and Protection Technology in Petro-Chemical Industry (CCPT) of Liaoning Shihua University, Fushun 113001, Liaoning Province, P. R. China

Received Date: 26 July 2010
Available Online: 29 December 2010
Fund Project: 国家高技术研究发展计划(863)项目(2007AA05Z103)资助 (863)项目(2007AA05Z103)

The electrochemical behavior of IrO₂ electrodes in a MnSO₄ plating solution and in a H₂SO₄ solution at different temperatures was investigated by polarity curve and cyclic voltammetry methods. The anodic electrode deposition was carried out at different current densities according to the polarity curve obtained in the bath and the deposition velocity was measured. The results show that the anodic electrode deposition reactions and the O₂ production reaction on the IrO₂ electrode in the bath occur simultaneously and the former reaction obviously restrains O₂ production. The process of MnO₂ electrodeposition onto IrO₂ is complicated and a Mn³⁺ intermediate product is produced, which can be oxidized to Mn⁴⁺ during the electrode deposition. Mn³⁺ is hydrolyzed at the same time as the oxidation and its hydrolysate desorbs, which causes an obvious reduction in current efficiency for the MnO₂ anodic electrodeposition. A potential range exists for the MnO₂ anodic electrode deposition and we also found a maximum value for the deposition velocity within the potential range.
- Manganese dioxide,
- Anode electrode position,
- Electrochemical behavior,
- Current efficiency
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Electrochemical Behavior of IrO₂ Electrodes in the Anodic Electrodeposition of MnO₂