Citation: CHEN Shi-Yu, WANG Zhao-Xiang, FANG Xiang-Peng, ZHAO Hai-Lei, LIU Xiao-Jiang, CHEN Li-Quan. Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 97-102. doi: 10.3866/PKU.WHXB20110134 shu

Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries

1.
1. Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China;
2. Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China

Received Date: 20 August 2010
Available Online: 16 December 2010
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB220100)资助 (973) (2009CB220100)

Hexa nal TiS₂ was synthesized as a high-capacity anode material for lithium ion batteries.X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicated that this material had a layeredstructure with particle sizes between 10 and 20 μm. It shows three discharge plateaus between 3.00 and0.00 V with a reversible capacity of up to 668 mAh·g^-1. It has excellent cycling performance between 3.00and 1.40 V. Particle pulverization and formation of Li₂S lead to performance degradation because of theirreversible dissolution of Li₂S into the electrolyte below 0.50 V. The addition of extra acetylene black and adecrease in particle size markedly improve the electrochemical performance of the TiS₂ anode.
- TiS₂,
- Lithium ion battery,
- Anode material,
- Charge-discharge mechanism,
- Modification
1. [1]
  
  1. Idota, Y.; Kubota, T.; Matsufuji, A.; Maekawa, Y.; Miyasaka, T.Science, 1997, 276: 1395
2. [2]
  2. Poizot, P.; Laruelle, S. ; Grugeon, S.; Dupont, L.; Tarascon, J.M.Nature, 2000, 407: 496
3. [3]
  3. Li, Y. G.; Tan, B.;Wu, Y. Y. Nano Letters, 2008, 8(1): 265
4. [4]
  4. Fang, L.; Chowdari, B. V. R. J. Power Sources, 2001, 97-98: 181
5. [5]
  5. Li, H.; Shi, L. H.;Wang, Q.; Chen, L. Q.; Huang, X. J. SolidState Ionics, 2002, 148(3-4): 247
6. [6]
  6. Doh, C. H.; Kalaiselvi, N.; Park, C.W.; Jin, B. S.; Moon, S. I.;Yun, M. S. Electrochem. Commun., 2004, 6: 965
7. [7]
  7. Bichat, M. P.; Politova, T.; Pfeiffer, H.; Tancret, F.; Monconduit,L.; Pascal, J. L.; Brousse, T.; Favier, F. J. Power Sources, 2004,136: 80
8. [8]
  8. Brousse, T.; Lee, S. M.; Pasquereau, L.; Defives, D.; Schleich, D.M. Solid State Ionics, 1998, 113-115: 51
9. [9]
  9. Poizot, P.; Laruelle, S.; Grugeon, S.; Tarascon, J. M.J. Electrochem. Soc., 2002, 149(9): A1212
10. [10]
  10. Feng, X.; He, X. M.; Pu,W. H.;Wan, C. R.; Jiang, C. Y. ProgressIn Chemistry, 2008, 20(2/3): 396
11. [11]
  [冯旭, 何向明, 蒲薇华, 万春荣, 姜长印. 化学进展, 2008, 20(2/3): 396
12. [12]
  11. Concheso, A.; Santamar.′a, R.; Blanco, C.; Menéndez, R.;Jiménez-Mateos, J. M.; Alcántara, R.; Lavela, P.; Tirado, J. L.Carbon, 2005, 43: 923
13. [13]
  12. Brousse, T.; Lee, S. M.; Pasquereau, L.; Defives, D.; Schleich, D.M. Solid State Ionics, 1998, 113-115: 51
14. [14]
  13. Zhang, N.; Yi, R.;Wang, Z.; Shi, R. R.;Wang, H. D.; Qiu, G. Z.;Liu, X. H. Materials Chemistry and Physics, 2008, 111: 13
15. [15]
  14. Débart, A.; Dupont, L.; Patrice, R.; Tarascon, J. M. Solid StateSciences, 2006, 8: 640.
16. [16]
  15. Whittingham, M. S. Chem. Rev., 2004, 104: 4271
17. [17]
  16. Winter, M.; Besenhard, J. O.; Spahr, M. E.; Novák, M. AdvancedMaterials, 1998, 10:725
18. [18]
  17. Yan, J. M.; Huang, H. Z.; Zhang, J.; Liu, Z. J.; Yang, Y. J. PowerSources, 2005, 146: 264
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
5. [5]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
6. [6]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
7. [7]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
8. [8]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
9. [9]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
12. [12]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
17. [17]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
18. [18]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
19. [19]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
20. [20]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050

Get Citation

PDF

XML

Metrics

PDF Downloads(1394)
Abstract views(3062)
HTML views(64)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Characterization of TiS2 as an Anode Material for Lithium Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries