Citation: CHEN Shi-Yu, WANG Zhao-Xiang, FANG Xiang-Peng, ZHAO Hai-Lei, LIU Xiao-Jiang, CHEN Li-Quan. Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 97-102. doi: 10.3866/PKU.WHXB20110134 shu

Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries

1.
1. Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China;
2. Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China

Received Date: 20 August 2010
Available Online: 16 December 2010
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB220100)资助 (973) (2009CB220100)

Hexa nal TiS₂ was synthesized as a high-capacity anode material for lithium ion batteries.X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicated that this material had a layeredstructure with particle sizes between 10 and 20 μm. It shows three discharge plateaus between 3.00 and0.00 V with a reversible capacity of up to 668 mAh·g^-1. It has excellent cycling performance between 3.00and 1.40 V. Particle pulverization and formation of Li₂S lead to performance degradation because of theirreversible dissolution of Li₂S into the electrolyte below 0.50 V. The addition of extra acetylene black and adecrease in particle size markedly improve the electrochemical performance of the TiS₂ anode.
- TiS₂,
- Lithium ion battery,
- Anode material,
- Charge-discharge mechanism,
- Modification
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Characterization of TiS₂ as an Anode Material for Lithium Ion Batteries