Citation: LI Guo-Xian, WANG Tao, HE Jian-Ping, ZHOU Jian-Hua, XUE Hai-Rong, HU Yuan-Yuan. Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al₂O₃-TiO₂ Nanocomposites with a Dual Pore System[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 248-254. doi: 10.3866/PKU.WHXB20110131 shu

Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al₂O₃-TiO₂ Nanocomposites with a Dual Pore System

1.
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 13 July 2010
Available Online: 13 December 2010
Fund Project: 航空科学基金(2007ZF52061) (2007ZF52061)国家自然科学基金(50871053)资助项目 (50871053)

C-Al₂O₃-TiO₂ nanocomposites with a dual pore system were synthesized via the sol-gel tri-constituent co-assembly process using an amphiphilic triblock copolymer F127 (PEO₁₀₆PPO₇₀PEO₁₀₆, M_W=12600) as a template, aluminum isopropoxide and tetrabutyl titanate as metallic sources and resol as an organic precursor. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption were used to characterize the structures of these nanocomposites. The results show that the nanocomposite with a Al/Ti molar ratio of 1:10 has ordered mesoporous structures with a dual system of 3.9 and 6.5 nm, a high specific surface area of 259 m²·g^-1 and a pore volume of 0.37 cm³·g^-1. Low infrared emissivity coatings were obtained using the ethylenepropylene- diene monomer (EPDM) as an adhesive and the ordered mesoporous C-Al₂O₃-TiO₂ nanocomposites as a filling. As the Al/Ti molar ratio and coat thickness changed the infrared emissivities changed from 0.450 to 0.617.
- Mesoporous,
- Ordered,
- C-Al₂O₃-TiO₂ nanocomposites,
- Dual-porosity,
- Infrared emissivity
1. [1]
  
  1 Vinu, A.; Miyahara, M.; Sivamurugan, V.; Mori, T.; Ariga, K. J. Mater. Chem., 2005, 15: 5122
2. [2]
  2 Feng, X.; Fryxell, G. E.;Wang, L. Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science, 1997, 276: 923
3. [3]
  3 Roussel, T.; Pellenq, R. J. M.; Bienfait, M.; Vix-Guterl, C.; adiou, R.; Beguin, F.; Johnson, M. Langmuir, 2006, 22: 4614
4. [4]
  4 Lu, A. H.; Schmidt,W.; Matoussevitch, N.; Bonnemann, H.; pliethoff, B.; Tesche, B.; Bill, E.; Kiefer,W.; Schuth, F. Angew. Chem. Int. Edit., 2004, 43: 4303
5. [5]
  5 Liu, R. L.; Ren, Y. J.; Shi, Y. F.; Zhang, F.; Zhang, L. J.; Tu, B.; hao, D. Y. Chem. Mater., 2008, 20: 1140
6. [6]
  6 Kresge, C. T.; Leonowicez, M. E.; Roth,W. J.; Vartuli, J. C.; eck, J. S. Nature, 1992, 359: 710
7. [7]
  7 Wang, J. C.; Xiang, C. S.; Liu, Q.; Pan, Y. B.; Guo, J. K. Adv. Funct. Mater., 2008, 18: 2995
8. [8]
  8 Liu, Q. L.; Zhang, D.; Fan, T. X. Appl. Phys. Lett., 2008, 93: 013110
9. [9]
  9 Zhou, J. H.; He, J. P.; Li, G. X.;Wang, T.; Sun, D.; Ding, X. C.; hao, J. Q.;Wu, S. C. J. Phys. Chem. C., 2010, 114: 7611
10. [10]
  10 Fang, Z. G.; Li, C. S.; Sun, J. Y.; Zhang, H. T.; Zhang, J. S. Carbon, 2007, 45: 2873
11. [11]
  11 Yang, J.; Shen, Z. M.; Hao, Z. B. Carbon, 2004, 42: 1882
12. [12]
  12 Yu, H. J.; Xu, G. Y.; Shen, X. M.; Yan, X. X.; Chen, C.W. Appl. Surf. Sci., 2009, 255: 6077
13. [13]
  13 Wang, Z. R.; Yu, D. B.; Yu, D. H.; Zhu, X. Y.; Ye, X. Y. Infrared echnology, 1999, 1: 49
14. [14]
  [王自荣, 余大斌, 於定华, 朱晓颍, 叶源. 红外技术, 1999, l: 41]
15. [15]
  14 Liu, R. L.; Shi, Y. F.;Wan, Y.; Meng, Y.; Zhang, F. Q.; Gu, D.; hen, Z. X.; Tu, B.; Zhao, D. Y. J. Am. Chem. Soc., 2006, 128: 11652
16. [16]
  15 Liu, R. L.; Ren, Y. J.; Shi, Y. F.; Zhang, F.; Zhang, L. J.; Tu, B.; hao, D. Y. Chem. Mater., 2008, 20: 1140
17. [17]
  16 Wang, T.; Zhou, J. H.;Wang, D. J.; Sun, D.; Di, Z. Y.; He, J. P. Acta Phys. -Chim. Sin., 2009, 25: 2155
18. [18]
  [王涛, 周建华, 王道 , 孙盾, 狄志勇, 何建平. 物理化学学报, 2009, 25: 2155]
19. [19]
  17 Sun Y. Q.; Zhou, Y. M. Journal of Inorgnic Materials, 2007, 2: 227
20. [20]
  [孙艳青, 周钰明. 无机材料学报, 2007, 2: 227]
21. [21]
  18 Zhu, D. M.; Li, K.; Luo, F.; Zhou,W. C. Applied Surface Science, 2009, 255: 6145
22. [22]
  19 Song, X. H.; Yu, D. H. Infrared Technology, 2003, 6: 49
23. [23]
  [宋兴 , 於定华. 红外技术, 2003, 6: 49]
24. [24]
  20 Phanga, S.W.; Tadokorob, M.;Watanabeb, J.; Kuramot, N. Synthetic. Met., 2008, 158: 251
25. [25]
  21 Phanga, S.W.; Tadokorob, M.;Watanabeb, J.; Kuramot, N. Polym. Adv. Technol., 2009, 6: 550
26. [26]
  22 Li, J. M.; Cai, X.; Mao J. F. Materials for Mechanical ngineering, 2004, 28: 34
27. [27]
  [李景明, 蔡殉, 茅及放. 械工程材料, 2004, 28: 34]
28. [28]
  23 Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Edit., 2005, 44: 7053
29. [29]
  24 Rojas, F.; Kornhauser, I.; Felipe, C.; Esparza, J. M.; Cordero, S.; omingueza, A.; Riccardo, J. L. Phys. Chem. Chem. Phys., 2002, 4: 2346
30. [30]
  25 Yu, H. J.; Xu, G. Y.; Shao, C. M.; Chen, C.W.; Hu, C. Infrared Technology, 2008, 30: 154
31. [31]
  [余慧娟, 徐国跃, 邵春明, 程传伟, 晨. 红外技术, 2008, 30: 154]
32. [32]
  26 Dai, G. P. Journal of Sichuan Ordnance, 1996, 17: 2
33. [33]
  [戴光平. 川兵工学报, 1996, 17: 2]
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al2O3-TiO2 Nanocomposites with a Dual Pore System

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Synthesis and Infrared Emissivity of Ordered Mesoporous C-Al₂O₃-TiO₂ Nanocomposites with a Dual Pore System