Citation: PENG Kai-Mei, SHAO Wen-Li, WANG Hua-Hua, YING Xiao, WANG Hui, JI Liang-Nian, LIU Hai-Yang. Effects of Solvents on the Spectral Properties of Gallium Corrole[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 199-206. doi: 10.3866/PKU.WHXB20110129 shu

Effects of Solvents on the Spectral Properties of Gallium Corrole

1.
1. Depatment of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China;
2. State Key Laboratory of Optoelectronics Materials and Technologies, Sun Yat-Sen University, Guangzhou 510275, P. R. China;
3. Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Received Date: 20 July 2010
Available Online: 10 December 2010
Fund Project: 国家自然科学基金(20771039, 20871122, 20971046)资助项目 (20771039, 20871122, 20971046)

A series of peripherally substituted free base corroles (1, 2, 3, 4) and their gallium complexes 1-Ga(Py), 2-Ga(Py), 3-Ga(Py), 4-Ga(Py) were synthesized and characterized by proton nuclear magnetic resonance (¹H NMR), UV-visible (UV-Vis) spectroscopy and electrospray ionization mass spectra (ESI-MS). The UV-visible spectra, steady state fluorescence spectra，and time resolved fluorescence spectra of the free base corroles and their gallium complexes were recorded in different solvents. Fluorescence lifetimes were obtained by fitting fluorescence decay kinetics curves using a single exponential simulation. The effects of non or weak polar solvents on the UV spectrum of gallium corrole were fitted to the Bayliss equation and the non-radiative energy loss hc(ν¹_A-ν_F) of gallium corrole and F(n) showed a linear correlation.
- Corrole,
- Gallium,
- Florescence,
- Solvent effect
1. [1]
  
  1 Gross, Z.; Galili, N.; Saltsman, I. Angew. Chem., Int. Edit., 1999, 38: 1427
2. [2]
  2 Paolesse, R.; Jaquinod, L.; Nurco, D. J.; Mini, S.; Sa ne, F.; Boschi, T.; Smith, K. M. Chem. Commun., 1999, 999: 1307
3. [3]
  3 Gross, Z.; Gray, H. B. Adv. Synth. Catal., 2004, 346: 165
4. [4]
  4 Mahammed, A.; Gross, Z. Angew. Chem, Int. Edit., 2006, 45: 6544
5. [5]
  5 Liu, H. Y.; Yam, F.; Xie, Y. T.; Li, X. Y.; Chang, C. K. J. Am. Chem. Soc., 2009, 131: 12890
6. [6]
  6 Kowalska, D.; Liu, X.; Tripathy, U.; Mahammed, A.; Gross, Z.; Hirayama, S.; Steer, R. P. Inorg. Chem., 2009, 48: 2670
7. [7]
  7 Simkhovich, L.; ldberg, I.; Gross, Z. J. Inorg. Biochem., 2000, 80: 235
8. [8]
  8 Bendix, J.; Dmochowski, I. J.; Gray, H. B.; Mahammed, A.; Simkhovich, L.; Gross, Z. Angew. Chem. Int. Edit., 2000, 39: 4048
9. [9]
  9 Liu, X.; Mahammed, A.; Tripathy, U.; Gross, Z.; Steer, R. P. Chem. Phys. Lett., 2008, 459: 113
10. [10]
  10 Ventura, B.; Esposti, A. D.; Koszarna, B.; Gryko, D. T.; Flamigni, L. New J. Chem., 2005, 29: 1557
11. [11]
  11 Saltman, I.; Mahammed, A.; ldberg, I.; Tkachenko, E.; Botoshansky, M.; Gross, Z. J. Am. Chem. Soc., 2002, 124: 7411
12. [12]
  12 Tripathy, U.; Steer, R. P. J. Porphyrins Phthalocyanines, 2007, 11: 228
13. [13]
  13 Aviv, I.; Gross, Z. Chem. Commun., 2007: 1987
14. [14]
  14 Agadjanian, H.; Ma, J.; Rentsendorj, A.; Valluripalli, V. ; Hwang, Y. J.; Mahammed, A. ; Farkas, D. L.; Gray, H. B. ; Gross, Z.; Medina-Kauwe, L. K. Proceedings of the National Academy of Sciences, 2009, 106: 6105
15. [15]
  15 Mahammed, A.; Gross, Z. Dalton Trans., 2010, 39: 2998
16. [16]
  16 Nardis, S.; Monti, D.; Paolesse, R. Mini-Rev. Org. Chem., 2005, 2: 355
17. [17]
  17 Lian, P.; Liu, H. Y.; Chen, L.; Yam, F.; Chang, C. K. Chinese Journal of Inorganic Chemistry, 2009, 25: 1420
18. [18]
  [练萍, 刘海洋, 陈玲, 任飞, 张启光. 无机化学学报, 2009, 25: 1420]
19. [19]
  18 Jin, Z. P.; Peng, X. J.; Sun, L. C. Chemistry Online, 2003, 7: 464
20. [20]
  [金志平, 彭孝军, 孙立成. 化学通报, 2003, 7: 464]
21. [21]
  19 Hu, Z. Z.; Yang, S. J.; Lu, J. L. Journal of Hubei University, 1994, 14: 90
22. [22]
  [胡珍珠, 杨水金, 陆江林. 湖北学院学报, 1994, 14: 90]
23. [23]
  20 Strat, G.; Strat, M.; Grecu, I. Spectros. Lett., 1994, 27: 177
24. [24]
  21 Bayliss, N. S. J. Chem. Phys., 1950, 18: 292
25. [25]
  22 Smith, K. M.; Porphyrins and metalloporphyrins. New York: Elserier, 1975: 667-700
26. [26]
  23 Gao, F.; Pu, B. S. Chemical Reagents, 1988, 10: 328
27. [27]
  [高福, 蒲宝珊. 化学试剂, 1988, 10: 328]
28. [28]
  24 Ghosh, A.; Jynge, K. Chem. Eur. J., 1997, 3: 823
29. [29]
  25 Liu,W. Y.; Zhang, F. S.; Tang, Y.W.; Song, X. Q. Acta Phys. -Chim. Sin., 1986, 1: 12
30. [30]
  [刘文渊, 张复实, 唐应武, 宋心琦. 物理化学学报, 1986, 1: 12]
31. [31]
  26 Haber, A.; Agadjanian, H.; Medina-Kauwe, L. K.; Gross, Z. J. Inorg. Biochem., 2008, 102: 446
32. [32]
  27 Kowalska, D.; Liu, X.; Tripathy, U.; Maham med, A.; Gross, Z.; Hirayama, S.; Steer R. P. Inorg. Chem., 2009, 48: 2670
33. [33]
  28 Prochorow, J.; Deperasinska, I.; Dresner, J.; Sobolewski, A. J. Mol. Struct., 1978, 45: 471
34. [34]
  29 Reiser, A.; Leyshon, L. J. J. Chem. Phys., 1972, 56: 1011
35. [35]
  30 Mahammed, A.; Gross, Z. J. Inorg. Biochem., 2002, 88: 305
1. [1]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
2. [2]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
3. [3]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
4. [4]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
5. [5]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
6. [6]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
7. [7]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
8. [8]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
9. [9]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
10. [10]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
11. [11]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
12. [12]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
13. [13]
  Xinyi Hong , Tailing Xue , Zhou Xu , Enrong Xie , Mingkai Wu , Qingqing Wang , Lina Wu . Non-Site-Specific Fluorescent Labeling of Proteins as a Chemical Biology Experiment. University Chemistry, 2024, 39(4): 351-360. doi: 10.3866/PKU.DXHX202310010
14. [14]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
15. [15]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
16. [16]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
17. [17]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
18. [18]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
19. [19]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
20. [20]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094

Get Citation

PDF

XML

Metrics

PDF Downloads(1153)
Abstract views(3089)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142