Citation: ZHAO Yan-Chun, ZHAN Lu, TIAN Jian-Niao, NIE Su-Lian, NING Zhen. N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 91-96. doi: 10.3866/PKU.WHXB20110128 shu

N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation

1.
Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, Guangxi Province, P. R. China

Received Date: 3 June 2010
Available Online: 10 December 2010
Fund Project: 广西自然科学基金创新团队项目(2010GXNSFF013001, 0728043) (2010GXNSFF013001, 0728043)广西教育厅科研项目(桂教科研[2006]26 号)资助 (桂教科研[2006]26 号)

We prepared a new kind of N-doped amorphous carbon (C_xN) by the calcination of poly-o-toluidine (POT) at 800 °C. The prepared C_xN consisted of about 8.5% (w) nitrogen. Pd nanoparticles were deposited on C_xN because of the inherent chemical activity arising from nitrogen incorporation. The Pd/C_xN composite catalyst has a large electrochemically active surface area and it shows od electrocatalytic performance and stability toward methanol oxidation in alkaline media. All the results suggest that C_xN can potentially find application in fuel cells.
- Alkaline direct methanol fuel cell,
- Poly-o-toluidine,
- Calcination,
- N-doped amporphous carbon,
- Pd nanoparticle
1. [1]
  
  1 Peng, F.; Zhou, C.;Wang, H.; Yu, H.; Liang, J.; Yang, J. Catal. Commun., 2009, 10(5): 533
2. [2]
  2 Singh, R. N.; Singh, A.; Anindita. Int. J. Hydrog. Energy, 2009, 34(4): 2052
3. [3]
  3 Qiu, C.; Shang, R.; Xie, Y.; Bu, Y.; Li, C.; Ma, H. Mater. Chem. Phys., 2010, 120(2-3): 323
4. [4]
  4 Shobha, T.; Aravinda, C. L.; Bera, P.; Devi, L. G.; Mayanna, S. M. Mater. Chem. Phys., 2003, 80(3): 656
5. [5]
  5 Zhao, D. J.; Yin, G. P. Appl. Chem. Industry, 2009, 38(9): 1371
6. [6]
  [赵东江, 尹鸽平. 应用化工, 2009, 38(9):1371]
7. [7]
  6 Zhao, Y.; Yang, X.; Tian, J.;Wang, F.; Zhan, L. Int. J. Hydrog. Energy, 2010, 35(8): 3249
8. [8]
  7 Chetty, R.; Kundu, S.; Xia,W.; Bron, M.; Schuhmann,W.; Chirila, V.; Brandl,W.; Reinecke, T.; Muhler, M. Electrochim. Acta, 2009, 54(17): 4208
9. [9]
  8 Ismagilov, Z. R.; Shalagina, A. E.; Podyacheva, O. Y.; Ischenko, A. V.; Kibis, L. S.; Boronin, A. I.; Chesalov, Y. A.; Kochubey, D. I.; Romanenko, A. I.; Anikeeva, O. B.; Buryakov, T. I.; Tkachev, E. N. Carbon, 2009, 47(8): 1922
10. [10]
  9 Du, H. Y.;Wang, C. H.; Hsu, H. C.; Chang, S. T.; Chen, U. S.; Yen, S. C.; Chen, L. C.; Shih, H. C.; Chen, K. H. Diamond Relat. Mater., 2008, 17(4-5): 535
11. [11]
  10 Zhao, Y.; Yang, X.; Tian, J. Electrochim. Acta, 2009, 54: 7114
12. [12]
  11 Ma, Y.; Jiang, S.; Jian, G.; Tao, H.; Yu, L.;Wang, X.;Wang, X.; Zhu, J.; Hu, Z.; Chen Y. Energy Environ. Sci., 2009, 2: 224
13. [13]
  12 Wang, M. L.; Huang, C. D. Chin. J. Power Sources, 2010, 34(2): 144
14. [14]
  [王美丽, 黄成德. 电源技术, 2010, 34(2): 144]
15. [15]
  13 Singh, R. N.; Singh, A.; Anindita. Carbon, 2009, 47(1): 271
16. [16]
  14 Sun, Z. P.; Zhang, X. G.; Liang, Y. Y.; Li, H. L. Electrochem. Commun., 2009, 11(3): 557
17. [17]
  15 Vidakovi?, T.; Christov, M.; Sundmacher, K. Electrochim. Acta, 2007, 52: 5606
18. [18]
  16 Zhao, Y.; Yang, X.; Tian, J.;Wang, F.; Zhan, L. J. Power Sources, 2010, 195: 4634
1. [1]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
2. [2]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
3. [3]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
4. [4]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
5. [5]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
6. [6]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
7. [7]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
8. [8]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
9. [9]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
10. [10]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
13. [13]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
14. [14]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
15. [15]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
16. [16]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
17. [17]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
18. [18]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
19. [19]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
20. [20]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002

Get Citation

PDF

XML

Metrics

PDF Downloads(1434)
Abstract views(2401)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142