Citation: SUN De-Hui, ZHANG Ji-Lin, SUN De-Xin. Structure and Photochromic Properties of a Histidine Salt of 12-Silicotungstate Supramolecular Compound[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 25-31. doi: 10.3866/PKU.WHXB20110123 shu

Structure and Photochromic Properties of a Histidine Salt of 12-Silicotungstate Supramolecular Compound

1.
1. Faculty of Science, Changchun Institute of Technology, Changchun 130012, P. R. China;
2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
3. The Amour Technology Institute of PLA, Changchun 130117, P. R. China

Received Date: 23 July 2010
Available Online: 7 December 2010
Fund Project: 国家自然科学基金(20871083)资助项目 (20871083)

We synthesized a novel histidine salt of 12-silicotungstate supramolecular compound ((HisH₂)₂SiW₁₂O₄₀·6H₂O) by a solution method. Its composition, thermostability, and structure were characterized by elemental analysis, thermal gravimetric and differential thermal analysis (TG-DTA), and single crystal X-ray diffraction, respectively. The experimental results show that the supramolecular compound has a composition of C₁₂H₃₄N₆O₅₀SiW₁₂ and it is stable under 135 °C in air. It belongs to a monoclinic system (space group C2/c) with a=2.44005(18) nm, b=1.29788(10) nm, c=1.86898(14) nm, β=124.0380(10)°, V= 4.9048(6) nm3, Z=4, and D_c=4.465 g·cm^-3. The final statistics based on F² are odness-of-fit ( F) = 1.268, R₁=0.0344 and wR₂=0.0851 for (I>2σ(I)). X-ray diffraction analysis further reveals that this supramolecular compound mainly consists of polyoxometalate anions [SiW₁₂O₄₀]^4-, protonated histidine cations [HisH₂]²⁺ and lattice water. A three-dimensional (3D) network is formed through hydrogen bonding. The resulting sample shows photochromism under UV irradiation. We propose a possible photochromic mechanism by an analysis of the chromic sample′s electron spin resonance (ESR) spectrum.
- Supramolecular compound,
- Polyoxometalate,
- Histidine,
- Photochromism
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