Citation: CHEN Hua-Rong, CHANG Ran-Ran, LI Li, YUAN Wen-Hui. High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 241-247. doi: 10.3866/PKU.WHXB20110119 shu

High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface

1.
1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China;
2. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 8 September 2010
Available Online: 2 December 2010
Fund Project: 国家自然科学基金(20976057)资助项目 (20976057)

Positively charged organic-functionalized α-Al₂O₃ ceramic hollow fiber was obtained by dip-coating the substrate with a 3-aminopropyl-(diethoxy)methylsilane (ADMS) solution. Negatively charged NaA zeolite particles were deposited on the substrate surface and used as seed for further secondary growth by the electrostatic adsorption of a positively charged organic-functionalized substrate and NaA zeolite particles. The NaA zeolite membrane was synthesized on a porous α-Al₂O₃ ceramic hollow fiber support by the microwave heating-secondary growth method. The as-synthesized NaA zeolite membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), zeta potential, and gas permeation tests. The differences in morphology, structure, and gas permeability between the NaA zeolite and the ADMS-modified substrate supported NaA zeolite membrane were determined. XRD results show that only NaA zeolite is present on the support. The zeta potential results indicate that opposite charges exist between the NaA zeolite seed or precursor and the organic-functionalized substrate surface, which confirms the electrostatic adsorption between them. SEM images show that a smooth and dense membrane (5 μm thick) is obtained and the particles are twinborn by od intergrowth on the ADMS-modified substrate supported NaA zeolite membrane surface. Gas permeation tests with H₂, O₂, N₂, and C₃H₈ at different temperatures show that the permeability of H₂ on the ADMS-modified substrate supported NaA zeolite membrane at 35 °C is 3.6×10^-7 mol·m^-2·s^-1·Pa^-1, which is lower than that (4.0×10^-7 mol·m^-2·s^-1·Pa^-1) of the NaA zeolite membrane. The ideal permselectivity of H₂/C₃H₈ is 11.25, which is far higher than that (5.06) of the NaA zeolite membrane.
- Hollow fiber,
- Organic-functionalization,
- NaA zeolite membrane,
- Microwave heating,
- Hydrogen separation
1. [1]
  
  1. Rosen, M. A. Energy, 2010, 35: 1068
2. [2]
  2. Haryanto, A.; Fernando, S.; Murali, N.; Adhikari, S. Energy & Fuels, 2005, 19(5): 2098
3. [3]
  3. Barelli, L.; Bidini, G.; Gallorini, F.; Servili, S. Energy, 2008, 33 (4): 554
4. [4]
  4. Li, Y. S.; Chen, H. L.; Liu, J.; Yang,W. S. J. Membr. Sci., 2006,277(1-2): 230
5. [5]
  5. Aoki, K.; Kusakabe, K.; Morooka, S. J. Membr. Sci.,1998, 141:197
6. [6]
  6. Okamoto, K.; Kita, H.; Horii, K. Ind. Eng. Chem. Res.,2001, 40(1): 163
7. [7]
  7. Wang, Z. X.; Yan,W. F.; Tian, D. Y.; Cao, X. J.; Yu, J. H.; Xu, R.R. Acta Phys. -Chim. Sin., 2010, 26: 2044.
8. [8]
  [王周翔, 闫文付, 田大勇, 曹学静, 于吉红, 徐如人. 物理化学学报, 2010, 26: 2044]
9. [9]
  8. Kondo, M.; Kita, H. J. Membr. Sci.,2010, 361(1-2): 223
10. [10]
  9. Huang, A. S.; Caro, J. Chem. Mater, 2010, 22(15): 4353
11. [11]
  10. Verweij, H.; Lin, Y. S.; Dong, J. H. MRS Bull., 2006, 31(10): 756
12. [12]
  11. Yuan,W. H.; Lin, Y. S.; Yang,W. S. J. Am. Chem. Soc., 2004, 126(15): 4776
13. [13]
  12. Yang,W. S.; Zhang, B. Q.; Liu, X. F. Microporous Mesoporous Mat., 2009, 117(1-2): 391
14. [14]
  13. Xu, X. C.; Yang,W. S.; Liu, J.; Lin, L.W.; Stroh, N.; Brunner, H. J. Membr. Sci., 2004, 229: 81
15. [15]
  14. Zhong, Y. J.; Xu, X. H.; Xiao, Q.; Jiang, L.; Zhu,W. D.; Ma, C. A. Acta Phys. -Chim. Sin., 2008, 24: 1875.
16. [16]
  [钟依均, 许晓华,肖强, 姜丽, 朱伟东, 马淳安. 物理化学学报, 2008, 24:1875]
17. [17]
  15. Morigami, Y.; Kondoa, M.; Abe, J.; Kita, H.; Okamoto, K. Sep. Purif. Technol., 2001, 25, 251
18. [18]
  16. Ge, Q. Q.;Wang, Z. B.; Yan, Y. S. J. Am. Chem. Soc., 2009, 131(47): 17056
19. [19]
  17. Zeng,C. F.; Zhang, L. X.; Cheng, X. H.;Wang, H. T.; Xu, N. P.Sep. Purif. Technol., 2008, 63(3): 628
20. [20]
  18. Cui, J. Y.; Zhang, X. F.; Liu, H. O.; Liu, S. Q.; King, L.Y. J. Membr. Sci., 2008, 325(1): 420
21. [21]
  19. Shah, D.; Kissick, K.; Ghorpade, A.; Hannah, R.; Bhattacharyya, D. J. Membr. Sci., 2000, 179: 185
22. [22]
  20. Sato, K.; Nakane, T. J. Membr. Sci., 2007, 301: 151
23. [23]
  21. Malekpour, A.; Millani, M. R.; Kheirkhah, M. Desalination,2008, 225: 199
24. [24]
  22. Das, N. Ceram. Int., 2010, 36: 1193
25. [25]
  23. Dogan, H.; Hilmioglu, N. D. Desalination, 2010, 258: 120
26. [26]
  24. Huang, Z.; Shi, Y.;Wen, R.; Guo, Y. H.; Su, J. F.; Matsuura, T.Sep. Purif. Technol., 2006, 51: 126
27. [27]
  25. Lin, L. G.; Zhang, Y. H.; Li, H. J. Colloid Interface Sci., 2010, 350(1): 355
28. [28]
  26. Varela-Gandía, F. J.; Berenguer-Murcia, A.; Lozano-Castelló, D.; Cazorla-Amorós, D. J. Membr. Sci., 2010, 351: 123
29. [29]
  27. Moróna, F.; Pinaa, M. P.; Urriolabeitiab, E.; Menéndeza, M; Santamaría, J. Desalination, 2002, 147: 425
30. [30]
  28. Suer, M. G.; Bac, N.; Yilmaz, L. J. Membr. Sci., 1994, 91: 7
31. [31]
  29. Lee, G. S.; Lee, Y. J.; Yoon, K. B. J. Am. Chem. Soc., 2001, 123(40): 9769
32. [32]
  30. Huang, A. S.; Liang, F. Y.; Steinbach, F.; Caro, J. J. Membr. Sci., 2010, 350: 5
1. [1]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
2. [2]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
3. [3]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
4. [4]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
5. [5]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
6. [6]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
7. [7]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
8. [8]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
9. [9]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
10. [10]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
11. [11]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
12. [12]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
13. [13]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
14. [14]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
15. [15]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
16. [16]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
19. [19]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
20. [20]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082

Get Citation

PDF

XML

Metrics

PDF Downloads(1473)
Abstract views(2400)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al2O3 Ceramic Hollow Fiber Surface

Metrics

通讯作者: 陈斌, bchen63@163.com

High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al₂O₃ Ceramic Hollow Fiber Surface