Citation: ZHENG Jing-Wu, LU Guo-Ying, QIAO Liang, JIANG Li-Qiang, JIANG Mei-Yan. Copper Electrodeposition from Non-Cyanide Alkaline Baths Containing Methylene Diphosphonic Acid as a Complexing Agent[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 143-148. doi: 10.3866/PKU.WHXB20110118 shu

Copper Electrodeposition from Non-Cyanide Alkaline Baths Containing Methylene Diphosphonic Acid as a Complexing Agent

1.
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 20 July 2010
Available Online: 2 December 2010
Fund Project: 浙江省自然科学基金(Y406406)资助项目 (Y406406)

A cyanide-free alkaline copper deposition bath was developed using methylene diphosphonic acid (MDPA, H₄L) as a complexing agent for Cu²⁺. The plating bath was investigated using potentiometric titrations, voltammetric curves, and polarization curves. The potentiometric titration gave dissociation constants for MDPA of: pK₁=1.86, pK₂=2.65, pK₃=6.81, pK₄=9.04, and the stability constants were: pK_ML= 10.65, pK_ML₂ = 5.59, pK_ML₃ = 2.50. Three different complex species were present in the bath as the pH increases: Cu(H₃L)₂, [Cu(H₃L)(H₂L)]^-, and [Cu(H₂L)₂]^2-. MDPA was found to be more likely to form complex species with Cu²⁺ than 1-hydroxyethylene-1,1-diphosphonic acid (HEDPA) from pH 7 to pH 10. At pH 9, [Cu(H₃L)(H₂L)]^- and [Cu(H₂L)₂]^2- were reduced to Cu at the cathode. Compared with the HEDPA system at 10 °C the peak potential shifted to more negative values and the rate of diffusion was faster.
- Non-cyanide bath,
- Methylene diphosphonic acid,
- Copper electrodeposition,
- pH potentiometric titration,
- 1-Hydroxyethylene-1,1-diphosphonic acid
1. [1]
  
  1. Feng, S. B.; Shang, S. B.; Bao, X.; Feng, L. T.; Zhang, J.W.; Li,Z. H. Acta Physico-Chimica Sinica, 2005, 21(5): 463.
2. [2]
  [冯绍彬,商士波, 包祥, 冯丽婷, 张经纬, 李宗慧. 物理化学学报, 2005,21(5): 463]
3. [3]
  2. Radisic, A.; Long, J. G.; Hoffmann, P. M.; Searson, P. C. Journal of the Electrochemical Society, 2001, 148(1): C41
4. [4]
  3. Zheng, J.W.; Jiang, M. Y.; Qiao, L.; Jiang, L. Q.; Sheng, J.W.; Zhang, C. Acta Physico-Chimica Sinica, 2008, 24(9): 1733.
5. [5]
  [郑精武, 蒋梅燕, 乔梁, 姜力强, 盛嘉伟, 张诚. 物理化学学报,2008, 24(9): 1733]
6. [6]
  4. Shao, C.; Feng, H.;Wei, Y. L. Shao, T. J. Inner Mon lia Petrochemical Industry, 2007, (2): 20.
7. [7]
  [邵晨, 冯晖, 卫应亮,邵同镜. 内蒙古石油化工, 2007, (2): 20]
8. [8]
  5. Hebert, K. R.; Adhikari, S.; Houser, J. E. Journal of the Electrochemical Society, 2005, 152(5): C324
9. [9]
  6. Stoychev, D.; Tsvetanov, C. Journal of Applied Electrochemistry, 1996, 26(7): 741
10. [10]
  7. Abd El Rehim, S. S.; Sayyah, S. M.; El Deeb, M. M. Applied Surface Science, 2000, 165(4): 249
11. [11]
  8. Duan, G. L. Non-cyanide alkaline bath for copper deposition
12. [12]
  [D]. Nanjing: Nanjing University of Science and Technology, 2008
13. [13]
  [段光亮. 无氰碱性镀铜研究
14. [14]
  [D]. 南京: 南京理工大学, 2008]
15. [15]
  9. Konno, H.; Nagayama, M. Electrochimica Acta, 1977, 22(4): 353
16. [16]
  10. Popov, K.; R?nkk?m?ki, H.; Lajunen, L. H. J. Pure Appl. Chem.,2001, 73(10): 1641
17. [17]
  11. Fang, J. L. Electroplating and Finishing, 2009, 28(9): 6.
18. [18]
  [方景礼. 电镀与涂饰, 2009, 28(9): 6]
19. [19]
  12. Kline, G. A. Cyanide-free copper plating process: US, 4933051
20. [20]
  [P]. 1990-7-12
21. [21]
  13. Szotek, J. Purification of cyanide-free copper plating baths: US, 5266212
22. [22]
  [P]. 1993-11-30
23. [23]
  14. Fang, J. L. Electroplating and Finishing, 2009, 28(10): 1.
24. [24]
  [方景礼.电镀与涂饰, 2009, 28(10): 1. ]
25. [25]
  15. Chen, C. C. Electroplating and Pollution Control, 2003, 23(4):10.
26. [26]
  [陈春成. 电镀与环保, 2003, 23(4): 10]
27. [27]
  16. Ergün, E. L.; Kiratli, P. O.; Günay, E. C.; Erba, B. Nuclear Medicine Communications, 2006, 27(11): 877
28. [28]
  17. Cukrowski, I.; Mogano, D. M.; Zeevaart, J. R. Journal of Inorganic Biochemistry,2005, 99(12): 2308
29. [29]
  18. Burkholder, E.; lub, V. O.; O’Connor, C. J. ; Zubieta, J. Inorganica Chimica Acta, 2002, 340: 127
30. [30]
  19. Chen, Z. M.;Wu, E. M; Yu, Y. H. Pharmaceutical and Clinical Research, 2008, 16(4): 268.
31. [31]
  [陈志明, 吴二明, 虞燕华. 药物与临床研究. 2008, 16(4): 268]
32. [32]
  20. Yang, F. Coordination chemistry. 1st ed. Shanghai: East China Normal University Press, 2002: 77-83.
33. [33]
  [杨帆. 配位化学.第一版. 上海: 华东师范大学出版社, 2002: 77-83]
34. [34]
  21. Wang, K.; Chen, X. X. Chinese Journal of Analysis Laboratory, 1985, 4: 48.
35. [35]
  [王夔, 陈贤萱. 分析实验室, 1985, 4: 48. ]
36. [36]
  22. Barbosa, L. L.; de Almeida, M. R. H.; Carlos, R. M.; Yonashiro, M.; Oliveira, G. M.; Carlos, I. A. Surface & Coationgs Technology, 2005, 192: 145
37. [37]
  23. de Almeida, M. R. H.; Carlos, I. A.; Barbosa, L. L.; Carlos, R. M.; Lima-Neto, B. S.; Pallone, E. M. J. A. Journal of Applied Electrochemistry, 2002, 32: 763
38. [38]
  24. He, J. B.; Li, X. L.; Lin, J. X. Acta Chimica Sinica, 1997, 55: 1103.
39. [39]
  [何建波, 李学良, 林建新. 化学学报, 1997, 55: 1103]
40. [40]
  25. Plakhotnaya, O. N.; richev, I. G.; Batrakov, V. V.; Izotov, A. D. Russian Russian Journal of Coordination Chemistry, 2006, 32(9): 680
1. [1]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
2. [2]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
3. [3]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
4. [4]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
5. [5]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
7. [7]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
8. [8]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
9. [9]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
10. [10]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
11. [11]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
12. [12]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
15. [15]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
16. [16]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
17. [17]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
18. [18]
  Zhanhong Tong , Xiaoyu Xie , Fangfang Chen . Appreciating Autumn Leaves: A Brief Analysis of the Causes behind “Frost Leaves Redder than February Flowers”. University Chemistry, 2024, 39(9): 183-188. doi: 10.12461/PKU.DXHX202404005
19. [19]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
20. [20]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006

Get Citation

PDF

XML

Metrics

PDF Downloads(1067)
Abstract views(2275)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142