Citation: LUO Ying, CUI Xiao-Li, XIE Jing-Ying. Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 135-142. doi: 10.3866/PKU.WHXB20110103 shu

Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films

LUO Ying ^1,2 ,
CUI Xiao-Li ^1,3, ,
XIE Jing-Ying ²

1.
1. Department of Materials Science, Fudan University, Shanghai 200433, P. R. China;
2. Institute of Space Power-Sources, Shanghai 200233, P. R. China;
3. State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou, 350002, P. R. China

Received Date: 21 June 2010
Available Online: 19 November 2010
Fund Project: 国家重点基础研究发展规划项目(973)(2010CB933703)以及上海市科学技术委员会纳米专项(1052nm01800) 及福建省福州大学光催化重点实验室&mdash (973)(2010CB933703)以及上海市科学技术委员会纳米专项(1052nm01800)省部共建国家重点实验室培育基地资助项目(K-081018) (K-081018)

TiO₂-MoO₃ composite nanotube thin films were obtained by the thermal treatment of titanium dioxide nanotube thin films in the presence of MoO3. Titanium dioxide nanotubes (TiO₂ NTs) thin films were prepared by the anodic oxidation of titanium foil. The resultant thin films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), Mott-Schottky analysis, and photoelectrochemical methods. The XRD patterns showed that an anatase type TiO₂ was present in the thin films. Nanotube structures for the thin films were observed by SEM. MoO₃ was dispersed on the TiO₂ NT top surface. Elemental analysis by XPS showed that MoO₃ recombined with the TiO₂ NTs to form TiO₂-MoO₃ composite nanotube thin films. The influence of time and temperature of thermal treatment on the photoelectrochemical response for the TiO₂-MoO₃ composite nanotube thin film electrodes were investigated. The photoelectrochemical response of the TiO₂-MoO₃ composite nanotube thin film increased under visible light illumination compared with the pristine TiO₂ NTs. The highest photoelectrochemical response was observed for the TiO₂-MoO₃ composite nanotube thin film obtained by thermal treatment at 450 °C for 60 min.
- TiO₂ nanotubes
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Visible Light Photoelectrochemical Response of TiO2-MoO3 Composite Nanotube Thin Films

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通讯作者: 陈斌, bchen63@163.com

Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films