Citation: WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai. Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3317-3321. doi: 10.3866/PKU.WHXB20101226 shu

Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor

1.
College of Physics Science & Technology, Hebei University, Baoding 071002, Hebei Province, P. R China

Received Date: 2 August 2010
Available Online: 10 November 2010
Fund Project: 国家自然科学基金(50902042) (50902042) 河北省自然科学基金(E2009000209, E2010000283) (E2009000209, E2010000283) 河北省教育厅基金(2009313) (2009313)发光与光信息技术教育部重点实验室研究基金(2010LOI12)资助项目 (2010LOI12)

We synthesized a kind of green phosphor, NaBaPOM₄:Tb³⁺, by the high temperature solid-state method, and investigated its luminescent characteristics. NaBaPO₄:Tb³⁺ has several emission peaks, and these are located at 437, 490, 543, 587, and 624 nm, which correspond to the ⁵D₃→⁷D₄ and ⁵D₄→⁷F_{J=6. 5, 4, 3} transitions of Tb³⁺, respectively. The main peak is at 543 nm. The excitation spectrum (monitored at an emission wavelength of 543 nm) consists of several bands, and the main peak is located at 380 nm. The effect of amount of Tb³⁺ doping content, the compensators (Li⁺, Na⁺, K⁺, or Cl^-), and the sensitizer activator Ce³⁺ on the emission intensity of the NaBaPOM₄:Tb³⁺ phosphor were also studied. The results show that the emission intensity can be controlled by the above factors, and the intensity can be enhanced by selecting the prime optimum conditions.
- Luminescent characteristics,
- NaBaPOM₄：Tb³⁺,
- Green phosphor
1. [1]
  
  1. Nakamura, S.; Fasol, G. The blue laser diode. Berlin: Springer-Verlag, 1997: 1
2. [2]
  2. Setlur, A. A.; Heward,W. J.; Gao, Y.; Srivastava, A. M.; Chandran, R. G.; Shankar, A. V. Chem. Mater., 2006, 18(14): 3314
3. [3]
  3. Li, P. L.; Yang, Z. P.;Wang, Z. J.; Xiong, Z. J.; Guo, Q. L. Acta Phys.-Chim. Sin., 2008, 24(1): 179
4. [4]
  [李盼来, 杨志平, 王志军, 熊志军, 郭庆林. 物理化学学报, 2008, 24(1): 179]
5. [5]
  4. Kuo, C. H.; Sheu, J. K.; Chang, S. J.; Su, Y. K.;Wu, L.W.; Tsai, J. M.; Liu, C. H.;Wu, R. K. Jpn. J. Appl. Phys., 2003, 42(4B): 2284
6. [6]
  5. Du, H.; Sun, J.; Xia, Z.; Sun, J. Appl. Phys. B, 2009, 96: 459
7. [7]
  6. Zhang, J. C.;Wang, Y. H.; Zhang, Z. Y.; Xie, P.; Li, H. H.; Jiang, Y. P. Chin. Phys. Lett., 2008, 25(4): 1453
8. [8]
  7. Liao, J. S.; Liu, B.; Lai, H. S. J. Lumin., 2009, 129: 668
9. [9]
  8. Li, P. L.; Pang, L. B.;Wang, Z. J.; Yang, Z. P.; Guo, Q. L.; Li, X. J. Alloy. Compd., 2009, 478: 813
10. [10]
  9. Tang, Y. S.; Hu, S. F.; Lin, C. C.; Bagkar, N. C.; Liu, R. S. Appl. Phys. Lett., 2007, 90: 151108-1
11. [11]
  10. Wu, Z. C.; Liu, J.; ng, M. L.; Su, Q. J. Electrochem. Soc., 2009, 156(3): H153
12. [12]
  11. Liao, J. S.; Qiu, B.;Wen, H. R.; Chen, J, L.; You,W. X. Mater. Res. Bull., 2009, 44: 1863
13. [13]
  12. Meng, Q. Y.; Chen, B. J.; Xu,W.; Zhao, X. X.; Yang, Y. M.; Di, W. H.;Wang, X. J. Spectroscopy and Spectral Analysis, 2009, 29 (1): 151
14. [14]
  [孟庆裕, 陈宝玖, 许武, 赵晓霞, 杨艳民, 狄卫华, 王晓君. 光谱学与光谱分析, 2009, 29(1): 151]
15. [15]
  13. Chen, Y.;Wang, J.; Zhang, X. G.; Zhang, G. G.; ng, M. L.; Su, Q. Sensors and Actuators B: Chemical, 2010, 148: 259
16. [16]
  14. Lu ,J.; Huang, Y. L.; Tao, Y.; Seo, H. J. J. Alloy. Compd., 2010, 500: 134
17. [17]
  15. Sun, L. D.; Qian, C.; Liao, C. S.;Wang, X. L.; Yan, C. H. Solid State Commun., 2001, 119: 393
18. [18]
  16. Li, X.; Yang, Z. P.; Guan, L.; Guo, J. X.;Wang, Y.; Guo, Q. L. J. Alloy. Compd., 2009, 478: 684
19. [19]
  17. Turos-Matysiak, R.; Gryk,W.; Grinberg, M.; Lin, Y. S.; Liu, R. S. Radiation Measurements, 2007, 42: 755
20. [20]
  18. Liu, X. R.;Wang, X. J.;Wang, Z. K. Phys. Rev. B, 1989, 39: 10633
1. [1]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
2. [2]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
3. [3]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
4. [4]
  Shuhao FENG , Feibing XIONG , Yaqing LIN , Han SU , Xu HAN . Preparation and luminescent properties of alkaline metal doped Cd₃Al₂Ge₃O₁₂: Pr³⁺ orange phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 284-296. doi: 10.11862/CJIC.20250171
5. [5]
  Nian LIU , Biao ZHENG , Kun WANG , Chunbao ZHENG , Qingyan HAN , Enjie HE , Saidong XUE . Synthesis and spectroscopic performance of double perovskite Li_0.5La_0.5MgSrWO₆∶Mn⁴⁺ phosphors for plant growth lighting. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 129-140. doi: 10.11862/CJIC.20250069
6. [6]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
7. [7]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
8. [8]
  Xiaokang JIANG , Junliang MA , Yan ZHAO , Feng GAO , Changli LIU , Xingshen ZHAO , Hengwei ZHOU . Preparation and luminescent properties of Sm³⁺-doped La₂MgZrO₆ phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 263-270. doi: 10.11862/CJIC.20250236
9. [9]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074
10. [10]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
11. [11]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
12. [12]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
13. [13]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
14. [14]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
15. [15]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
16. [16]
  Ruixin XU , Hongtuo LI , Chen SHI , Yanhong YAN . Factors influencing the spectral properties of composite luminescent materials SrTiO₃: Eu³⁺/SrAl₂O₄: Eu²⁺, Dy³⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2307-2316. doi: 10.11862/CJIC.20250055
17. [17]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
18. [18]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
19. [19]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
20. [20]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100021-0. doi: 10.3866/PKU.WHXB202311005

Get Citation

PDF

XML

Metrics

PDF Downloads(1125)
Abstract views(2779)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescent Characteristics of the NaBaPOM4:Tb3+ Green Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor