Citation: ZHENG Hai-Ying, XIE Guan-Qun, WANG Xiao-Xia, JIN Ling-Yun, LUO Meng-Fei. Selective Hydrogenation of Crotonaldehyde over ZrO₂-Supported Pt Catalysts[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3273-3277. doi: 10.3866/PKU.WHXB20101216 shu

Selective Hydrogenation of Crotonaldehyde over ZrO₂-Supported Pt Catalysts

1.
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 16 July 2010
Available Online: 4 November 2010
Fund Project: 浙江省自然科学基金(Y4100300)资助项目 (Y4100300)

Pt catalysts supported on high specific surface area ZrO₂ were prepared by the impregnation method and applied to the hydrogenation of crotonaldehyde in the gas phase at atmospheric pressure. The effects of Pt loading and reduction temperature on the catalytic properties of the Pt/ZrO₂ catalysts were investigated. It was found that the 3Pt/ZrO₂ catalyst with a mass fraction of 3% Pt and at a reduction temperature of 500 °C exhibited favorable catalytic performance for the selective hydrogenation of crotonaldehyde. The selectivity for crotyl alcohol reached 55% at 27% crotonaldehyde conversion. The catalysts were characterized by X-ray powder diffraction (XRD), CO chemisorption, and NH₃ temperature programmed desorption (NH₃-TPD). The results indicated that the catalytic performance depended on the strong Lewis acidic sites on the catalyst surface and a proper Pt particle size of ca 8 nm for the selective hydrogenation of crotonaldehyde to crotyl alcohol.
- Hydrogenation,
- Pt/ZrO₂ Catalyst,
- High specific surface area ZrO₂,
- Crotyl alcohol,
- Lewis acid,
- Particle size of Pt
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Selective Hydrogenation of Crotonaldehyde over ZrO2-Supported Pt Catalysts

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通讯作者: 陈斌, bchen63@163.com

Selective Hydrogenation of Crotonaldehyde over ZrO₂-Supported Pt Catalysts