Citation: ZHOU Xiao-Ling, HUANG Rui-An, WU Zhao-Cong, YANG Bin, DAI Yong-Nian. Synthesis and Electrochemical Properties of High-Rate Spinel Li₄Ti₅O_l2/TiN Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3187-3192. doi: 10.3866/PKU.WHXB20101212 shu

Synthesis and Electrochemical Properties of High-Rate Spinel Li₄Ti₅O_l2/TiN Anode Material for Lithium-Ion Batteries

1.
National Engineering Laboratory for Vacuum Metallurgy, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, P. R. China

Received Date: 25 June 2010
Available Online: 2 November 2010
Fund Project: 云南省自然科学基金(2009CD024)资助项目 (2009CD024)

Spinel Li₄Ti₅O_l2/TiN was successfully prepared by sol-gel processing using acetylacetone (ACAC) as a chelating ligand and polyethylene glycol (PEG) as a dispersant. The effect of the TiN film on the electrochemical properties of spinel Li₄Ti₅O_l2 for lithium-ion batteries was studied. The Li₄Ti₅O_l2/TiN was analyzed by X-ray photoelectron spectroscopy (XPS). X-ray diffraction (XRD) patterns and scanning electron microscope (SEM) images showed that this anode material with the TiN film was pure spinel Li₄Ti₅O_l2 and was of sub-micron size. The initial specific discharge capacity of the Li₄Ti₅O_l2/TiN is 173.0 mAh·g^-1. When tested at a rate of 0.2C, 1C, 2C, and 5C, it still retained a discharge capacity of 170.6, 147.6, 135.6, and 111.0 mAh·g^-1, respectively, after 10 cycles, indicating that Li₄Ti₅O_l2/TiN had better high-rate performance than that without the TiN film. The positive effect of the TiN film on lithium-ion batteries was also demonstrated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS).
- Lithium-ion battery,
- Spinel Li₄Ti₅O_l2,
- TiN film,
- Anode material,
- Sol-gel processing,
- Polyethylene glycol
1. [1]
  
  1. Zaghib, K.; Simoneau, M.; Armand, M.; Gauthier, M. J. Power Sources, 1999, 81-82: 300
2. [2]
  2. Yu, Y.; Shui, J. L.; Chen, C. H. Solid State Commun., 2005, 135: 485
3. [3]
  3. Nikonov, A. V.; Kelder, E. M.; Schoonman, J.; Ivanov, V. V.; Pivkin, N.M. Solid State Ionics, 2006, 177: 2779
4. [4]
  4. Kitaura, H.; Hayashi, A.; Tadanaga, K.; Tatsumisa , M. J. Power Sources, 2009, 189:145
5. [5]
  5. Colobow, K. M.; Dahn, J. R.; Haering, R. R. J. Power Sources, 1989, 26: 397.
6. [6]
  6. Wu, Y. P.;Wan, C. R.; Jiang, C. Y. Rechargeable lithium-ion battery. Beijing: Chemical Industry Press, 2002:126
7. [7]
  [吴宇平, 万春荣, 姜长印. 锂离子二次电池. 北京: 化学工业出版社, 2002: 126]
8. [8]
  7. Jansen, A. N.; Kahaian, A. J.; Kepler, K. D.; Nelson, P. A.; Amine, K.; Dees, D.W.; Vissers, D. R.; Thackeray, M. M. J. Power Sources, 1999, 81-82: 902
9. [9]
  8. Dominko, R.; Gaberscek, M.; Bele, M.; Mihailovic, D.; Jamnik, J. J. Eur. Ceram. Soc., 2007, 27: 909
10. [10]
  9. Gao, J.; Ying, J. R.; Jiang, C. Y.;Wan, C. R. J. Power Sources, 2007, 166: 255
11. [11]
  10. Yang, L.X.; Gao, L. J. J. Alloy. Compd., 2009, doi:10.1016/j.jallcom.2009.05.151
12. [12]
  11. Ye,J.Y.; Zhao, X. B.; Yu; H. M.; Zhu; T. J. Function Materials, 2007, 38: 1423
13. [13]
  [叶静雅, 赵新兵, 余鸿明, 朱铁军. 功能材料, 2007, 38 : 1423]
14. [14]
  12. Huang, S. H.;Wen, Z. Y.; Zhang, J. C.; Gu, Z. H.; Xu, X. H. Solid State Ionics, 2006, 177: 851
15. [15]
  13. Hao,Y. J.; Lai, Q. Y.; Chen, Y. D.; Lu, J.Z.; Ji, X. Y. J. Alloy. Compd., 2008, 462: 404
16. [16]
  14. Xiong, L. Z.; He, Z. Q.;Yin, Z. L.; Chen, Q.Y.The Chinese Journal of Nonferrous Metals, 2008, 18: 310
17. [17]
  [熊利芝, 何则强, 尹周澜, 陈启元. 中国有色金属学报, 2008, 18 : 310]
18. [18]
  15. Huang, S. H.;Wen, Z. Y.; Lin, B.; Han, J. D.; Xu, X. G. J. Alloy. Compd., 2008, 457: 400
19. [19]
  16. Yu, H. Y.; Zhang, X. F.; Jalbout, A. F.; Yan, X. D.; Pan, X. M.; Xie, H. M.;Wang, R. S. Electrochimica Acta, 2008, 53: 4200
20. [20]
  17. Zhao, H. L.; Yue, L.; Zhu, Z. M.; Jiu, L.; Tian, Z. H.;Wang, R. L. Electrochimica Acta, 2008, 53: 7079
21. [21]
  18. Li, X.; Qu, M. Z.; Yu, Z. L. J. Alloy. Compd., 2008, doi:10.1016/ j.jallcom.2009.07.176
22. [22]
  19. Huang, S. H.;Wen, Z. Y.; Gu, Z. H.; Zhu, X. J. J. Electrochimica Acta, 2005, 50: 4057
23. [23]
  20. Huang, S. H.;Wen, Z. Y.; Zhu, X. J.; Lin, Z. X. J. Power Sources, 2007, 165: 408
24. [24]
  21. Mo,W.; Deng, G. Z.; Luo, F. C. Titanium metallurgy. Beijing: Metallurgical Industry Press.1998: 97-99
25. [25]
  [莫畏, 邓国珠, 罗方承. 钛冶金. 北京: 冶金工业出版社, 1998: 97-99]
26. [26]
  22. Jiang, C. H.; Ichihara, M.; Honma, I.; Zhou, H. S. Electrochimica Acta, 2007, 52: 6470
1. [1]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
2. [2]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
3. [3]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
6. [6]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
7. [7]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
8. [8]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
9. [9]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
10. [10]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082
11. [11]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
12. [12]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
13. [13]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
14. [14]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
15. [15]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
18. [18]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . Nucleation Regulation and Mechanism of Precursors for Nickel Cobalt Manganese-based Cathode Materials in Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100009-0. doi: 10.3866/PKU.WHXB202404042
19. [19]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
20. [20]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051

Get Citation

PDF

XML

Metrics

PDF Downloads(2533)
Abstract views(3333)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Properties of High-Rate Spinel Li4Ti5Ol2/TiN Anode Material for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Properties of High-Rate Spinel Li₄Ti₅O_l2/TiN Anode Material for Lithium-Ion Batteries