Citation: YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei. Effect of Preparation Method on the Activity of CuO/CeO₂-ZrO₂ Catalysts for Low Temperature CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3278-3284. doi: 10.3866/PKU.WHXB20101210 shu

Effect of Preparation Method on the Activity of CuO/CeO₂-ZrO₂ Catalysts for Low Temperature CO Oxidation

1.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China

Received Date: 1 August 2010
Available Online: 29 October 2010
Fund Project: 上海市教委重点学科建设项目(J51503) (J51503)上海应用技术学院科学技术发展基金项目(KJ2008-01)资助 (KJ2008-01)

CuO/CeO₂-ZrO₂ catalysts were prepared by microwave heating decomposition (one-step approach) and by microwave heating treatment of co-precipitation followed by impregnation (two-step approach). The catalysts were characterized by X-ray diffraction (XRD), low temperature N2 adsorption/ desorption, and H₂-temperature-programmed reduction (H₂-TPR). The catalytic activities of the catalysts for low temperature CO oxidation were investigated using a microreactor-gas chromatograph. The results showed that the one-step approach was more beneficial to CuO dispersion on the catalyst surface because of a strong interaction between CuO and CeO₂-ZrO₂ and to the improved reducibility of CuO, which resulted in higher catalytic activity. We conclude that finely dispersed and small CuO particles strongly interact with CeO₂-ZrO₂ are responsible for the high catalytic activity toward CO oxidation and that large CuO particles that do not interact with CeO₂-ZrO₂ inhibit the catalytic activity.
- Catalytic activity,
- CuO/CeO₂-ZrO₂,
- CO oxidation,
- Microwave heating
1. [1]
  
  1. Liu, Y.; Meng, M.; Yao, J. S.; Zha, Y. Q. Acta Phys. -Chim. Sin., 2007, 23: 641
2. [2]
  [刘咏, 孟明, 姚金松, 査宇清. 物理化学学报, 2007, 23: 641]
3. [3]
  2. Yu, J.;Wu, G. S.; Mao, D. S.; Lu, G. Z. Acta Phys. -Chim. Sin., 2008, 24: 1751
4. [4]
  [俞俊, 吴贵升, 毛东森, 卢冠忠. 物理化学学报, 2008, 24: 1751]
5. [5]
  3. Zheng, X. C.;Wang, X. Y.; Yu, L. H.;Wang, S. R.;Wu, S. H. Prog. Chem., 2006, 18: 159
6. [6]
  [郑修成, 王向宇, 于丽华, 王淑荣, 吴世华. 化学进展, 2006, 18: 159]
7. [7]
  4. Liang, F. X.; Zhu, H. Q.; Qin, Z. F.;Wang, G. F.;Wang, J. G. Prog. Chem., 2008, 20: 1453
8. [8]
  [梁飞雪, 朱华青, 秦张峰, 王国富, 王建国. 化学进展, 2008, 20: 1453]
9. [9]
  5. Wang, S. P.; Zheng, X. C.;Wang, X. Y.;Wang, S. R.; Zhang, S. M.; Yu, L. H.; Huang,W. P.;Wu, S. H. Catal. Lett., 2005, 105: 163
10. [10]
  6. Wang, S. P.;Wang, X. Y.; Huang, J.; Zhang, S. M.;Wang, S. R.; Wu, S. H. Catal. Commun., 2007, 8: 231
11. [11]
  7. Wang, S. P.; Zhang, T. Y.; Su, Y.;Wang, S. R.; Zhang, S. M.; Zhu, B. L.;Wu, S. H. Catal. Lett., 2008, 121: 70
12. [12]
  8. Jiang, X. Y.; Zhou, R. X.; Chen, Y.; Lou, L. P.; Zheng, X. M. J. Zhejiang Univ.: Science Edition, 2001, 28: 653
13. [13]
  [蒋晓原, 周仁贤, 陈煜, 楼莉萍, 郑小明. 浙江大学学报: 理学版, 2001, 28: 653]
14. [14]
  9. Wang, S. P.;Wang, X. Y.; Zheng, X. C.;Wang, S. R.; Zhang, S. M.; Huang,W. P.;Wu, S. H. React. Kinet. Catal. Lett., 2006, 89: 37
15. [15]
  10. Luo, M. F.; Zheng, X. M. Acta Chem. Scand., 1998, 52: 1183
16. [17]
  [杨志强, 毛东森, 朱慧琳, 卢冠忠. 催化学报, 2009, 30: 997]
17. [18]
  12. Martinez-Arias, A.; Fernandez-Garcia, M.; Galvez, O.; Coronado, J. M.; Anderson, J. A.; Conesa, J. C.; Soria, J.; Munuera, G. J. Catal., 2000, 195: 207
18. [19]
  13. Chen, H. L.; Zhu, H. Y.;Wu, Y.; Gao, F.; Dong, L.; Zhu, J. J. J. Mol. Catal. A, 2006, 255: 254
19. [20]
  14. Zhu, J.; Zhang, L. L.; Deng, Y.; Liu, B.; Dong, L. H.; Gao, F.; Sun, K. Q.; Dong, L.; Chen, Y. Appl. Catal. B, 2010, 96: 449
20. [21]
  15. Hong, Q. H.; Song, Y. P.; Jia, A. P.; Pu, Z. Y.; Luo, M. F. J. Mol. Catal. (China), 2008, 22: 429
21. [22]
  [洪庆红, 宋宇鹏, 贾爱平, 普志英, 罗孟飞. 分子催化, 2008, 22: 429]
22. [23]
  16. Wang, E. G.; Chen, S. Y. J. Chin. Rare Earth Soc., 2001, 19: 17
23. [24]
  [王恩过, 陈诵英. 中国稀土学报, 2001, 19: 17]
24. [25]
  17. Wang, E. G.; Chen, S. Y. J. Rare Earths, 2002, 20: 533
25. [26]
  18. Wang, J. P.;Wang, E. G.; Chen, S. Y. Coal Conv., 2000, 23: 88
26. [27]
  [王建平, 王恩过, 陈诵英. 煤炭转化, 2000, 23: 88]
27. [28]
  19. Cao, J. L.;Wang, Y.; Zhang, T. Y.;Wu, S. H.; Yuan, Z. Y. Appl. Catal. B, 2008, 78: 120
28. [29]
  20. Yang, Z. Q.; Mao, D. S.; Zhu, H. L.; Lu, G. Z. Chin. J. Inorg. Chem., 2009, 25: 812
29. [30]
  [杨志强, 毛东森, 朱慧琳, 卢冠忠. 无机化学学报, 2009, 25: 812]
30. [31]
  21. Cai, C.; Xue, P. J. Ningxia Univ.: Natural Science Edition, 2005, 26: 345
31. [32]
  [蔡超, 薛屏. 宁夏大学学报: 自然科学版, 2005, 26: 345]
32. [33]
  22. Wang, J. Q.; Shen, M. Q.;Wang, J.;Wang,W. L.; Jia, L.W. Acta Phys. -Chim. Sin., 2010, 26: 2249
33. [34]
  [王建强, 沈美庆, 王军, 王务林, 贾莉伟. 物理化学学报, 2010, 26: 2249]
34. [35]
  23. Ma, L.; Luo, M. F.; Chen, S. Y. Appl. Catal. A, 2003, 242: 151
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Preparation Method on the Activity of CuO/CeO2-ZrO2 Catalysts for Low Temperature CO Oxidation

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通讯作者: 陈斌, bchen63@163.com

Effect of Preparation Method on the Activity of CuO/CeO₂-ZrO₂ Catalysts for Low Temperature CO Oxidation