Citation: SITU Yue, ZHOU Li-Zhuang, LAN Ren-Hua, XIA Zheng-Bin, CHEN Huan-Qin. Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3237-3242. doi: 10.3866/PKU.WHXB20101209 shu

Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 31 July 2010
Available Online: 29 October 2010
Fund Project: 国家中小型企业技术创新基金(08C26214402212) (08C26214402212)广州市中小企业技术创新基金(2008V41 C0021)资助 (2008V41 C0021)

Acrylic polymer emulsions were synthesized by semi-continuous seeded emulsion polymerization and the corresponding redispersible polymer powders were prepared by spray drying. Methacrylic acid (MAA) was used as the hydrophilic shell monomer. The influences of the amount of MAA on the average particle size of the original emulsion, the dispersion stability, zeta potential, and size distribution of the redispersion emulsion were investigated. The results show that with an increase in the amount of MAA, the particle size of original emulsion, the dispersion stability, and the zeta potential of the redispersion emulsion increased significantly. The size distribution of the redispersion emulsion with a high amount of MAA was unimodal and similar to the original emulsion indicating excellent water-redispersibility. Transmission electron microscopy (TEM) was used to characterize the internal microtopography of the redispersible polymer powder, and results showed that with a higher amount of MAA, millipores with larger pore sizes were present in the transection of the redispersible polymer powder. When polymer powders are redispersed in an aqueous phase, large micropores provide a more convenient channel for water permeation, which optimizes the redispersibility. The hairy structure and higher zeta potential endow the redispersion emulsion with excellent redispersion stability.
- Methacrylic acid,
- Redispersible polymer powder,
- Stability,
- Hollow polymer powder
1. [1]
  
  1. Klaus, M.; Karl, J. R.; Detlev, S.;Wolfgang, Z. Process for the preparation of a dispersible vinyl acetate/ ethylene polymer powder: US, 3883489
2. [2]
  [P]. 1975-05-13
3. [3]
  2. Hartmut, K.; Bernd, R.; Volker, K.; Andreas,W. Redispersible polymer powders: US, 6451900
4. [4]
  [P]. 2000-09-17
5. [5]
  3. Josef,W.; Alfred, K. Redispersible polymer powders, method for their preparation and applications: US, 5895802
6. [6]
  [P].1999-03-20
7. [7]
  4. Tadashi, I.; Yoshio, K.; Futoshi, H.; Katsunari, M. Redispersible polymer and production process thereof: US, 6090892
8. [8]
  [P]. 2000-07-18
9. [9]
  5. Joachim, S.; Otmar, K. Cem. Concr. Res., 2001, 31(3): 357
10. [10]
  6. Redispersion powder composition with binding acceleration effect: US, 0037925
11. [11]
  [P]. 2007-02-15
12. [12]
  7. Afridi, M. U. K.; Ohama, Y.; Demura, K.; Iqbal, M. Z. Cem. Concr. Res., 2003, 33: 1715
13. [13]
  8. Louis, A. K.; James,W. J.; Daniel, M. High Tg polymer and redispersible powder for use in hydraulic Portland cement mortar and concrete: US, 5576378
14. [14]
  [P]. 1996-11-19
15. [15]
  9. Weitzel, H.Water-redispersible polymer powders for building adhesive compositions: US, 6890975
16. [16]
  [P]. 2005-05-10
17. [17]
  10. Jing, X. J.; Li,W. J.; Yan, J. M.; Yang, Z. K. Journal of Taiyuan University of Technology, 2007, 38(2): 139
18. [18]
  [荆秀娟, 李万捷, 闫济民, 杨志康. 太原理工大学学报, 2007, 38(2): 139]
19. [19]
  11. Saija, L. M.; Uminski, M. J. Appl. Polym. Sci., 1999, 71(11): 1781
20. [20]
  12. Joachim, P.; Ines, P.; Hans-Jürgen, D.; Heinrich, S.; Bernd, R. Preparation of readily water-redispersible and water-wettable polymer powders: US, 6872773
21. [21]
  [P]. 2005-04-29
22. [22]
  13. Zhang, X. Y.; Jiang, Y. L.; Xie, D. L.; Chen, H. Q. Journal of Building Materials, 2009, 12(6): 689
23. [23]
  [张心亚, 江煜灵, 谢德龙, 陈焕钦. 建筑材料学报, 2009, 12(6): 689]
24. [24]
  14. Lin, J. D.; Chen, H. Q. Journal of South China University of Technology: Natural Science Edition, 2006, 34(8): 41
25. [25]
  [林劲冬, 陈焕钦. 华南理工大学学报: 自然科学版, 2006, 34(8): 41]
26. [26]
  15. Ines, P.; Joachim, P.; Oliver, R.; Heinrich, S. Method for producing polymer powders that can be easily redispersed in water: US, 0167539
27. [27]
  [P]. 2007-07-19
28. [28]
  16. Xie, D. L.; Zhang, X. Y.; Yang, B.; Chen, H. Q. Journal of South China University of Technology: Natural Science Edition, 2007, 35(7): 88
29. [29]
  [谢德龙, 张心亚, 杨波, 陈焕钦. 华南理工大学学报: 自然科学版, 2007, 35(7): 88]
30. [30]
  17. Chen, S.W.; Jiang, Y. B.; Sun, J. Z.; Zhao, Q.; Zhou, Q. Y. Journal of Chemical Engineering of Chinese Universities, 2009, 23(4): 644
31. [31]
  [陈松炜, 江永波, 孙建中, 赵骞, 周其云. 高校化学工程学报, 2009, 23(4): 644]
32. [32]
  18. Anna, M.; Renate, R.; Christian, T.; Katharina, L. Langmuir, 2007, 23, 5367
33. [33]
  19. Gallardo, V.; Morales, M. E.; Ruiz, M. A.; Delgado, A. V. Eur. J. Pharm. Sci., 2005, 26, 170
34. [34]
  20. Yu, L.;Yao, J.; Fu, Z.W.Acta Phys. -Chim. Sin., 2007,23(6):945
35. [35]
  [余乐, 姚佳, 傅正文. 物理化学学报, 2007, 23(6): 945]
36. [36]
  21. Günther, L.; Peukert,W. Part. Part. Syst. Char., 2002, 19(5): 312
37. [37]
  22. Günther, L.; Peukert,W. Colloids Surf. A, 2003, 225(1-3): 49
38. [38]
  23. Pei, Y. B.; Zhang, X. Y.; Xie, D. L.; Chen, H. Q. Journal of Chemical Engineering of Chinese Universities, 2009, 23(6): 1038
39. [39]
  [裴勇兵, 张心亚, 谢德龙, 陈焕钦. 高校化学工程学报, 2009, 23(6): 1038]
40. [40]
  24. Sun, R. X.; Lu, Y. P.; Chen, K. Z. Mater. Sci. Eng. C, 2009, 29: 1088
41. [41]
  25. Kim,T. K.;Yoon, J. J.; Lee, D. S.; Park,T. G. Biomat., 2006,27:152
1. [1]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
2. [2]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
5. [5]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
6. [6]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
7. [7]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
8. [8]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
11. [11]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
14. [14]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
15. [15]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
16. [16]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
17. [17]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
18. [18]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
19. [19]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
20. [20]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035

Get Citation

PDF

XML

Metrics

PDF Downloads(1326)
Abstract views(2669)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142