Citation: SITU Yue, ZHOU Li-Zhuang, LAN Ren-Hua, XIA Zheng-Bin, CHEN Huan-Qin. Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3237-3242. doi: 10.3866/PKU.WHXB20101209 shu

Influencing Mechanism of Methacrylic Acid on the Redispersion Properties of Redispersible Polymer Powders

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 31 July 2010
Available Online: 29 October 2010
Fund Project: 国家中小型企业技术创新基金(08C26214402212) (08C26214402212)广州市中小企业技术创新基金(2008V41 C0021)资助 (2008V41 C0021)

Acrylic polymer emulsions were synthesized by semi-continuous seeded emulsion polymerization and the corresponding redispersible polymer powders were prepared by spray drying. Methacrylic acid (MAA) was used as the hydrophilic shell monomer. The influences of the amount of MAA on the average particle size of the original emulsion, the dispersion stability, zeta potential, and size distribution of the redispersion emulsion were investigated. The results show that with an increase in the amount of MAA, the particle size of original emulsion, the dispersion stability, and the zeta potential of the redispersion emulsion increased significantly. The size distribution of the redispersion emulsion with a high amount of MAA was unimodal and similar to the original emulsion indicating excellent water-redispersibility. Transmission electron microscopy (TEM) was used to characterize the internal microtopography of the redispersible polymer powder, and results showed that with a higher amount of MAA, millipores with larger pore sizes were present in the transection of the redispersible polymer powder. When polymer powders are redispersed in an aqueous phase, large micropores provide a more convenient channel for water permeation, which optimizes the redispersibility. The hairy structure and higher zeta potential endow the redispersion emulsion with excellent redispersion stability.
- Methacrylic acid,
- Redispersible polymer powder,
- Stability,
- Hollow polymer powder
1. [1]
  
  1. Klaus, M.; Karl, J. R.; Detlev, S.;Wolfgang, Z. Process for the preparation of a dispersible vinyl acetate/ ethylene polymer powder: US, 3883489
2. [2]
  [P]. 1975-05-13
3. [3]
  2. Hartmut, K.; Bernd, R.; Volker, K.; Andreas,W. Redispersible polymer powders: US, 6451900
4. [4]
  [P]. 2000-09-17
5. [5]
  3. Josef,W.; Alfred, K. Redispersible polymer powders, method for their preparation and applications: US, 5895802
6. [6]
  [P].1999-03-20
7. [7]
  4. Tadashi, I.; Yoshio, K.; Futoshi, H.; Katsunari, M. Redispersible polymer and production process thereof: US, 6090892
8. [8]
  [P]. 2000-07-18
9. [9]
  5. Joachim, S.; Otmar, K. Cem. Concr. Res., 2001, 31(3): 357
10. [10]
  6. Redispersion powder composition with binding acceleration effect: US, 0037925
11. [11]
  [P]. 2007-02-15
12. [12]
  7. Afridi, M. U. K.; Ohama, Y.; Demura, K.; Iqbal, M. Z. Cem. Concr. Res., 2003, 33: 1715
13. [13]
  8. Louis, A. K.; James,W. J.; Daniel, M. High Tg polymer and redispersible powder for use in hydraulic Portland cement mortar and concrete: US, 5576378
14. [14]
  [P]. 1996-11-19
15. [15]
  9. Weitzel, H.Water-redispersible polymer powders for building adhesive compositions: US, 6890975
16. [16]
  [P]. 2005-05-10
17. [17]
  10. Jing, X. J.; Li,W. J.; Yan, J. M.; Yang, Z. K. Journal of Taiyuan University of Technology, 2007, 38(2): 139
18. [18]
  [荆秀娟, 李万捷, 闫济民, 杨志康. 太原理工大学学报, 2007, 38(2): 139]
19. [19]
  11. Saija, L. M.; Uminski, M. J. Appl. Polym. Sci., 1999, 71(11): 1781
20. [20]
  12. Joachim, P.; Ines, P.; Hans-Jürgen, D.; Heinrich, S.; Bernd, R. Preparation of readily water-redispersible and water-wettable polymer powders: US, 6872773
21. [21]
  [P]. 2005-04-29
22. [22]
  13. Zhang, X. Y.; Jiang, Y. L.; Xie, D. L.; Chen, H. Q. Journal of Building Materials, 2009, 12(6): 689
23. [23]
  [张心亚, 江煜灵, 谢德龙, 陈焕钦. 建筑材料学报, 2009, 12(6): 689]
24. [24]
  14. Lin, J. D.; Chen, H. Q. Journal of South China University of Technology: Natural Science Edition, 2006, 34(8): 41
25. [25]
  [林劲冬, 陈焕钦. 华南理工大学学报: 自然科学版, 2006, 34(8): 41]
26. [26]
  15. Ines, P.; Joachim, P.; Oliver, R.; Heinrich, S. Method for producing polymer powders that can be easily redispersed in water: US, 0167539
27. [27]
  [P]. 2007-07-19
28. [28]
  16. Xie, D. L.; Zhang, X. Y.; Yang, B.; Chen, H. Q. Journal of South China University of Technology: Natural Science Edition, 2007, 35(7): 88
29. [29]
  [谢德龙, 张心亚, 杨波, 陈焕钦. 华南理工大学学报: 自然科学版, 2007, 35(7): 88]
30. [30]
  17. Chen, S.W.; Jiang, Y. B.; Sun, J. Z.; Zhao, Q.; Zhou, Q. Y. Journal of Chemical Engineering of Chinese Universities, 2009, 23(4): 644
31. [31]
  [陈松炜, 江永波, 孙建中, 赵骞, 周其云. 高校化学工程学报, 2009, 23(4): 644]
32. [32]
  18. Anna, M.; Renate, R.; Christian, T.; Katharina, L. Langmuir, 2007, 23, 5367
33. [33]
  19. Gallardo, V.; Morales, M. E.; Ruiz, M. A.; Delgado, A. V. Eur. J. Pharm. Sci., 2005, 26, 170
34. [34]
  20. Yu, L.;Yao, J.; Fu, Z.W.Acta Phys. -Chim. Sin., 2007,23(6):945
35. [35]
  [余乐, 姚佳, 傅正文. 物理化学学报, 2007, 23(6): 945]
36. [36]
  21. Günther, L.; Peukert,W. Part. Part. Syst. Char., 2002, 19(5): 312
37. [37]
  22. Günther, L.; Peukert,W. Colloids Surf. A, 2003, 225(1-3): 49
38. [38]
  23. Pei, Y. B.; Zhang, X. Y.; Xie, D. L.; Chen, H. Q. Journal of Chemical Engineering of Chinese Universities, 2009, 23(6): 1038
39. [39]
  [裴勇兵, 张心亚, 谢德龙, 陈焕钦. 高校化学工程学报, 2009, 23(6): 1038]
40. [40]
  24. Sun, R. X.; Lu, Y. P.; Chen, K. Z. Mater. Sci. Eng. C, 2009, 29: 1088
41. [41]
  25. Kim,T. K.;Yoon, J. J.; Lee, D. S.; Park,T. G. Biomat., 2006,27:152
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