Citation: LI Ying-Pin, HAO Yan-Zhong. Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3365-3368. doi: 10.3866/PKU.WHXB20101205 shu

Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution

1.
College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Received Date: 18 June 2010
Available Online: 26 October 2010
Fund Project: 河北科技大学博士科研启动基金(QD200959) (QD200959) 河北省自然科学基金(B2010000856) (B2010000856)国家自然科学基金(20573031)资助项目 (20573031)

Permanganic potassium was reduced by malic acid under hydrothermal conditions without a template or additives and olive-shaped MnCO₃ particles were obtained. After the MnCO₃ precursor was calcined at 600 °C for 3 h, Mn₂O₃ was obtained and the olive-shape morphology was maintained. The products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and thermogravimetry-differential thermal analysis (TG-DTA). The effect of hydrothermal reaction time on the morphology of the products was studied. A MnCO₃ precursor with hollow olive morphology and thick wall was obtained when the reaction time was 2 h. When the reaction time was increased to 6 h, the wall of the hollow olive-shaped particles became thinner. When the reaction time was increased to 24 h the wall thickness of the MnCO₃ precursor with the hollow olive morphology was about 30 nm. Because of the Ostwald-Ripening effect, the morphology of the MnCO₃ precursor gradually evolved from thick-wall hollow olive to thin-wall hollow olive by increasing the reaction time.
- Hydrothermal synthesis,
- Mn₂O₃,
- Hollow,
- Olive
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Mn2O3 with a Hollow Olive Shape and Its Morphology Evolution

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution