Citation: LI Ying-Pin, HAO Yan-Zhong. Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3365-3368. doi: 10.3866/PKU.WHXB20101205 shu

Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution

1.
College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Received Date: 18 June 2010
Available Online: 26 October 2010
Fund Project: 河北科技大学博士科研启动基金(QD200959) (QD200959) 河北省自然科学基金(B2010000856) (B2010000856)国家自然科学基金(20573031)资助项目 (20573031)

Permanganic potassium was reduced by malic acid under hydrothermal conditions without a template or additives and olive-shaped MnCO₃ particles were obtained. After the MnCO₃ precursor was calcined at 600 °C for 3 h, Mn₂O₃ was obtained and the olive-shape morphology was maintained. The products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and thermogravimetry-differential thermal analysis (TG-DTA). The effect of hydrothermal reaction time on the morphology of the products was studied. A MnCO₃ precursor with hollow olive morphology and thick wall was obtained when the reaction time was 2 h. When the reaction time was increased to 6 h, the wall of the hollow olive-shaped particles became thinner. When the reaction time was increased to 24 h the wall thickness of the MnCO₃ precursor with the hollow olive morphology was about 30 nm. Because of the Ostwald-Ripening effect, the morphology of the MnCO₃ precursor gradually evolved from thick-wall hollow olive to thin-wall hollow olive by increasing the reaction time.
- Hydrothermal synthesis,
- Mn₂O₃,
- Hollow,
- Olive
1. [1]
  
  1. Masoud, S. N.; Fatemeh, M.; Fatemeh, D.; Kamal, S. J. Appl. urf. Sci., 2009, 256: 1476
2. [2]
  2. Chen, Y. C.; Zhang, Y. G.; Yao, Q. Z.; Zhou, G. T.; Fu, S. Q.; Fan, H. J. Solid State Chem., 2007, 180: 1218
3. [3]
  3. Yang, L. X.; Zhu, Y. J.; Tong, H.;Wang,W.W. J. Ultrason. onochem., 2007, 14: 259
4. [4]
  4. Yang, Z. H.; Zhang,W. X.;Wang, Q.; Song, X. M.; Qian, Y. T. Chem. Phys. Lett., 2006, 418: 46
5. [5]
  5. Navin, C.; Sanjeev, B.; Meenakshi, S.; Deepti, P. Mater. Lett., 2007, 61: 3728
6. [6]
  6. Baldi, M.; Escribano, V. S.; Amores, J. M. G. Appl. Catal. B, 1998, 17: L175
7. [7]
  7. Zhang, H. M.; Teraoka, Y.; Yamazoe, N. Catal. Today, 1989, 6: 155
8. [8]
  8. Nakamura, T.; Kajiyama, A. Solid State Ionics, 1999, 124: 45
9. [9]
  9. Wang, L. C.; He, L.; Liu, Y. M.; Cao ,Y.; He, H. Y.; Fan, K. N.; huang, J. H. J. Catal., 2009, 264: 145
10. [10]
  10. Jeong,W. T.; Joojh, L. J. Alloy. Compd., 2003. , 358: 294
11. [11]
  11. Xia, Y. Y.; Yoshio, M. J. Power Sources, 1995. , 57: 125
12. [12]
  12. Chen, Z.; Zhang, S. J. Cryst. Growth, 1997, 180: 280
13. [13]
  13. Yuan, Z. Y.; Ren, T. Z.; Du, G. H. Chem. Phys. Lett., 2004, 389: 83
14. [14]
  14. Liu, Y.; Zhao, X.; Pan, Y.; Zhao, J. Z.;Wang, Z. C. Acta hys. -Chim. Sin., 2009, 25: 1467. [刘莹, 赵旭, 潘琰, 敬哲, 王子忱. 物理化学学报, 2009, 25: 1467]
15. [15]
  15. Liu, X. L.; Xu, H. Y.; Meng, X. P.; Li, M.; Cui, D. L.; Song, Y. J.; ai, J. Q.; Li, M. S. Acta Phys. -Chim. Sin., 2004, 20: 608. [刘秀 , 徐红燕, 孟宪平, 李梅, 崔得良, 宋云京, 白见强, 李木森. 理化学学报, 2004, 20: 608]
16. [16]
  16. Liu, Y. P.; Qian, Y. T; Zhang, Y. H. Mater. Lett., 1996, 28: 357
17. [17]
  17. Shao, C. L.; Guan, H. Y.; Liu, Y. C. J. Solid State Chem., 2004, 177: 2628
18. [18]
  18. Cao, J.; Zhu, Y. C.; Bao, K. Y.; Shi, L.; Liu, S. Z; Qian, Y. T. J. Phys. Chem. C, 2009, 113: 17755
19. [19]
  19. Liu, B.; Zeng, H. Small, 2005, 1: 566
20. [20]
  20. Li, Y. P.; Zhou, X. Q.; Zhou, H. J.; Shen, Z. R.; Chen, T. H. Chem. J. Chin. Univ., 2007, 28(7): 1223. [李英品, 周晓荃, 周慧静, 铸睿, 陈铁红. 高等学校化学学报, 2007, 28(7):1223]
1. [1]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
2. [2]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
3. [3]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
4. [4]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
5. [5]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
6. [6]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
7. [7]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
8. [8]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
11. [11]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
14. [14]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
15. [15]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
16. [16]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
17. [17]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
18. [18]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
19. [19]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
20. [20]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

Get Citation

PDF

XML

Metrics

PDF Downloads(1650)
Abstract views(2376)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Mn2O3 with a Hollow Olive Shape and Its Morphology Evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Mn₂O₃ with a Hollow Olive Shape and Its Morphology Evolution