Citation: HOU Ling-Yun, YANG Jin, MA Xue-Song, LIU Wei. Effects of Species in Vitiation Air on Methane-Fueled Supersonic Combustion[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3150-3156. doi: 10.3866/PKU.WHXB20101204 shu

Effects of Species in Vitiation Air on Methane-Fueled Supersonic Combustion

1.
1. School of Aerospace, Tsinghua University, Beijing 100084, P. R. China;
2. Beijing Power Machinery Research Institute, Beijing 100074, P. R. China

Received Date: 10 May 2010
Available Online: 26 October 2010
Fund Project: 国家自然科学基金(50306011)资助项目 (50306011)

Based on a detailed chemical reaction mechanism, a reduced reaction mechanism with 18 species and 24 steps was used to simulate the supersonic combustion of methane. Heated air calculations showed that seven main vitiated species, i.e., H₂O, CO₂, O, OH, CO, H, and H₂, were present in ethanolfueled heated air. We analyzed the effects of these species on methane-fueled supersonic combustion using chemical kinetics and thermodynamics. H₂O inhibits the combustion process, decreases the combustion efficiency, and decreases the specific thrust. The relatively large molecular weight of CO₂ contributes to an increase in the mean molecular weight of the fuel gas, which is a negative factor in the mechanism of specific thrust. Free radicals O, OH, H can effectively promote the combustion process and thus increase the combustion efficiency. Intermediate products CO and H₂ increase the combustion efficiency, and this is a function of the additional fuel.
- Supersonic combustion,
- Chemical reaction mechanism,
- Vitiation air,
- Species
1. [1]
  
  1. Edelman, R. B.; Spadaccini, L. J. J. Spacecraft, 1969, 6(12): 1442
2. [2]
  2. Mattick, S. J.; Frankel, S. H. Numerical modeling of supersonic combustion_ validation and vitiation studies using FLUENT// 41st AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit. Tucson, Arizona, 2005: 10-13
3. [3]
  3. Tomioka, S.; Hiraiwa, T.; Kobayashi, K.; Izumikawa, M.; Kishida, T.; Yamasaki H. J. Propulsion Power, 2007, 23(4): 789
4. [4]
  4. Li,W. Q.; Song,W.Y. Journal of Air Force Engineering University, 2006, 5(7):10. [李卫强, 宋文艳. 空军工程大学学报, 2006, 5(7): 10]
5. [5]
  5. Liu,W. X.; He,W.; Li, H. B.; Li, X. Y.; Le, J. L. Chinese Science Bulletin, 2009, 54(8): 1317. [刘伟雄, 贺伟, 李宏斌, 李象远, 乐嘉陵. 科学通报, 2008, 53(8): 2257]
6. [6]
  6. Shao, J. X.; Tan, N. X.; Liu,W. X.; Li, X. Y. Acta Phys. -Chim. Sin., 2010, 26(2): 270. [邵菊香, 谈宁馨, 刘伟雄, 李象远. 物理化学学报, 2010, 26(2): 270]
7. [7]
  7. Liu, O. Z.; Cai, Y. H.; Hu, Y. L.; Liu, J. H.; Ling,W. H. Journal of Propulsion Technology, 2004, 25(5): 463. [刘欧子, 蔡元虎, 胡欲立, 刘敬华, 凌文辉. 推进技术, 2004, 25(5): 463]
8. [8]
  8. Peters, N.; Kee, R. J. Combust. Flame, 1987, 68: 17
9. [9]
  9. Tong, G.; Huang, Y.; Chen, Y. L. Journal of Fuel Chemistry and Technology, 2000, 28(1): 49. [董刚, 黄鹰, 陈义良. 燃料化学学报, 2000, 28(1): 49]
10. [10]
  10. Bowman, C. T.; Hanson, R. K.; Davidson, D. F.; Gardiner Jr.,W. C.; Lissianski, V.; Smith, G. P.; lden, D. M.; Frenklach, M.; ldenberg, M. 1994, http://www.me.berkeley.edu/gri_mech/
11. [11]
  11. Marinov, N. M. Int. J. Chem. Kinet., 1999, 31(3):183
12. [12]
  12. Davidenko, D. M.; Gökalp, I.; Dufour, E.; Magre, P. Systematic numerical study of the supersonic combustion in an experimental combustion chamber. 14th AIAA/AHI Space Planes and Hypersonic Systems and Technologies Conference, AIAA 2006-7913
1. [1]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
2. [2]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
3. [3]
  Jia Huo , Jia Li , Yongjun Li , Yuzhi Wang . Ideological and Political Design of Physical Chemistry Teaching: Chemical Potential of Any Component in an Ideal-Dilute Solution. University Chemistry, 2024, 39(2): 14-20. doi: 10.3866/PKU.DXHX202307075
4. [4]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
5. [5]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
6. [6]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
7. [7]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
8. [8]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
9. [9]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
10. [10]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
11. [11]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
12. [12]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
13. [13]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
14. [14]
  Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
15. [15]
  Houjin Li , Wenjian Lan . Name Reactions in University Organic Chemistry Laboratory. University Chemistry, 2024, 39(4): 268-279. doi: 10.3866/PKU.DXHX202310016
16. [16]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
17. [17]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
18. [18]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
19. [19]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
20. [20]
  Shuyong Zhang , Yaxian Zhu , Wenqing Zhang , Yuzhi Wang , Jing Lu . Ideological and Political Design of Combustion Heat Measurement Experiment: Determination of Heat Value of Agricultural and Forestry Wastes. University Chemistry, 2024, 39(2): 1-6. doi: 10.3866/PKU.DXHX202303026

Get Citation

PDF

XML

Metrics

PDF Downloads(1249)
Abstract views(3065)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142