Citation: ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen. Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3169-3174. doi: 10.3866/PKU.WHXB20101203 shu

Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior

1.
1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;
2. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
3. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China

Received Date: 1 July 2010
Available Online: 25 October 2010
Fund Project: 国家重点基础研究发展计划项目(973) (2007CB209703) (973) (2007CB209703)国家自然科学基金(20633040, 20873064)资助 (20633040, 20873064)

Zinc acetate/polyacrylonitrile nanofibers were prepared by an electrospinning method. The as-prepared nanofibers were carbonized under ar n and washed with acid to obtain porous carbon nanofibers. The surface morphology and microstructure of the porous carbon nanofibers were examined by scanning electron microscopy and X-ray diffraction. The surface area was found to be 413 m²·g^-1 by the Brunauer-Emmett-Teller (BET) method. The electrochemical performance of the electrodes was characterized by cyclic voltammetry and by chronopotentiogram tests. The results showed that the specific capacitance of the as-repapered carbon porous nanofiber electrode was 275 F·g^-1 under 1 A·g^-1, which is 162% higher than that of the carbon nanofibers without a porous structure.
- Supercapacitor,
- Electrospinning,
- Porous carbon nanofiber
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