Citation: ZHANG Lei-Yong, HE Shui-Jian, CHEN Shui-Liang, GUO Qiao-Hui, HOU Hao-Qing. Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3181-3186. doi: 10.3866/PKU.WHXB20101135 shu

Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received Date: 4 June 2010
Available Online: 15 October 2010
Fund Project: 江西师范大学校创新基金(YJS2010059)资助项目 (YJS2010059)

Polyaniline/carbon nanofiber (PANI/CNF) composite materials were prepared by in situ polymerization. The functional group, composition, surface morphology, and specific surface area of composite materials were characterized by Fourier transform infrared (FT?IR) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Brunauer?Emmelt?Teller analysis. Cyclic voltammetry (CV) and galvanotactic charge?discharge methods were used to study the electrochemical properties of the PANI/ CNF composite materials. Results showed that the composite materials had a rough surface with a burry PANI structure that was uniformly distributed over the CNF. The composite materials, as electrodes, showed od reversibility in redox reactions. The specific capacitance of 44.4%(w) PANI/CNF was 587.1 F·g^-1, the specific energy was 66.1 Wh·kg^-1 at a current density of 100 mA·g^-1, and the specific power was 1014.2 W·kg^-1 at a current density of 800 mA·g^-1. Moreover, the specific capacitance of PANI/CNF only decreased by 28% after 1000 charge?discharge cycles. Therefore, the PANI/CNF composite material is an excellent material for use in supercapacitors because of its high electrical conductivity and large specific capacitance.
- Carbon nanofiber mat,
- Polyaniline,
- Electrochemical property,
- Specific capacitance,
- Composite material
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