Citation: ZHANG Lei-Yong, HE Shui-Jian, CHEN Shui-Liang, GUO Qiao-Hui, HOU Hao-Qing. Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3181-3186. doi: 10.3866/PKU.WHXB20101135 shu

Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Received Date: 4 June 2010
Available Online: 15 October 2010
Fund Project: 江西师范大学校创新基金(YJS2010059)资助项目 (YJS2010059)

Polyaniline/carbon nanofiber (PANI/CNF) composite materials were prepared by in situ polymerization. The functional group, composition, surface morphology, and specific surface area of composite materials were characterized by Fourier transform infrared (FT?IR) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Brunauer?Emmelt?Teller analysis. Cyclic voltammetry (CV) and galvanotactic charge?discharge methods were used to study the electrochemical properties of the PANI/ CNF composite materials. Results showed that the composite materials had a rough surface with a burry PANI structure that was uniformly distributed over the CNF. The composite materials, as electrodes, showed od reversibility in redox reactions. The specific capacitance of 44.4%(w) PANI/CNF was 587.1 F·g^-1, the specific energy was 66.1 Wh·kg^-1 at a current density of 100 mA·g^-1, and the specific power was 1014.2 W·kg^-1 at a current density of 800 mA·g^-1. Moreover, the specific capacitance of PANI/CNF only decreased by 28% after 1000 charge?discharge cycles. Therefore, the PANI/CNF composite material is an excellent material for use in supercapacitors because of its high electrical conductivity and large specific capacitance.
- Carbon nanofiber mat,
- Polyaniline,
- Electrochemical property,
- Specific capacitance,
- Composite material
1. [1]
  
  1. Hou, H. Q.; Reneker, D. H. Adv. Mater., 2004, 16: 69
2. [2]
  2. Niu, C.; Sichel, E.; Hoch, R.; Moy, D.; Tennent, H. Appl. Phys. Lett., 1997, 70: 1480
3. [3]
  3. Guo, Q. H.; Zhou, X. P.; Li, X. Y.; Chen, S. L.; Agarwal, S.; Andreas, G.; Hou, H. Q. J. Mater. Chem., 2009, 19: 2810
4. [4]
  4. Dong, J, H.; The frontiers and development of macromolecule science (II). Beijing: Science Press, 2009: 624. [董建华. 高分子科学前沿与进展(II). 北京: 科学出版社, 2009, 624]
5. [5]
  5. Hou, H. Q.; Zeng, J.; Reuning, A.; Schaper, A.;Wendorff, J. H.; Greiner, A. Macromolecules, 2002, 35: 2429
6. [6]
  6. Jang, J.; Bae, J.; Choi, M.; Yoon, S. H. Carbon, 2005, 43: 2730
7. [7]
  7. Zhou, Y. K.; He, B. L.; Zhou,W. J.; Huang, J.; Li, X. H.;Wu, B.; Li, H. L. Electrochim. Acta, 2004, 49: 257
8. [8]
  8. Jiang, Q.; Zhang, Q.; Du, B.; Zhao, X. F.; Zhao, Y. Acta Phys. ? Chim. Sin., 2008, 24: 1719. [江奇, 张倩, 杜冰, 赵晓峰, 赵勇. 物理化学学报, 2008, 24: 1719]
9. [9]
  9. Lu, H. Preparation and electrochemical capacitive characteristic of polyaniline nanofiber by interfacial polymerization[D]. Changsha: Central South University, 2007. [卢海. 聚苯胺纳米纤维的界面聚合法制备及电化学电容特性研究[D]. 长沙: 中南大学, 2007]
10. [10]
  10. Andrews, R.; Jacques, D.; Rao, A. M.; Rantell, T.; Derbushire, F. Appl. Phys. Lett., 1999, 75: 1329
11. [11]
  11. Chen, R. J.; Franklin, N. R.; Kong, J.; Cao, J.; Tombler, T. W.; Zhang, Y. G. Appl. Phys. Lett., 2001, 79: 2258
12. [12]
  12. Gupta, V.; Miura, N. J. Power Sources, 2006, 157: 616
13. [13]
  13. Wang, Q. L.; Li, J. L.; Gao, F.; Li,W. S.;Wu, K, Z.;Wang, X. D. New Carbon Mater., 2008, 23: 275
14. [14]
  14. Zhang, Q. C.; Song, H. H.; Chen, X. H.; Meng, Q. H.; Pang, Z. Z. Chinese Journal of Power Sources, 2007, 32: 109. [张钦仓, 宋怀河, 陈晓红, 孟庆函, 庞自钊. 电源技术, 2007, 32: 109]
15. [15]
  15. Jang, J.; Lim, B. Angew. Chem.-Int. Edit., 2003, 42: 5600
16. [16]
  16. Lai, C. L. Preparation and application of carbon nanofibers[D]. Nanchang: Jiangxi Normal University, 2007. [赖垂林. 碳纳米纤维的制备及应用[D]. 南昌: 江西师范大学, 2007]
17. [17]
  17. Zhou, J. H.; Sui, Z. J.; Zhu, J.; Ping, L.; Chen, D.; Dai,Y. C.;Yuan,W. K. Carbon, 2007, 45: 785
18. [18]
  18. Wang, Y.W. Preparation and the study of properties of polyaniline/ Ag composite materials[D]. Changsha: Central South University [王炎伟. 聚苯胺/银纳米复合材料的制备及性能研究[D]. 长沙: 中南大学, 2009]
19. [19]
  19. Tang, J. S.; Jing, X. B.;Wang, B. C.;Wang, F. S. Synth. Met., 1988, 24: 231
20. [20]
  20. Cong,W. B.; Huang, Z. L.; Zhang, B. H. Electronic Components and Materials, 2007, 26: 65. [丛文博, 黄震雷, 张宝宏. 电子元件与材料, 2007, 26: 65]
21. [21]
  21. Dong, S. J.; Che, G. L.; Xie,Y.W. Chemicallymodified electrodes. Revised edition. Beijing: Science Press, 2003: 620-634. [董绍俊, 车广礼, 谢远武. 化学修饰电极. 修订版. 北京: 科学出版社, 2003: 620-634]
22. [22]
  22. Yang, H. S.; Zhou, X.; Zhang, Q.W. Acta Phys. Chim. Sin., 2005,
23. [23]
  21: 414. [杨红生, 周啸, 张庆武. 物理化学学报, 2005, 21: 414]
24. [24]
  23. Rajendra, P. K.; Munichandraiah, N. J. Electrochem. Soc., 2002, 149: A1393
25. [25]
  24. Chen, J.; Huang, K. L.; Liu, S. Q. Chin. J. Inorg.Chem., 2008, 24: 621. [陈洁, 黄可龙, 刘素琴. 无机化学学报, 2008, 24: 621]
26. [26]
  25. Zang, Y.; Hao, X. G.;Wang, Z. D.; Zhang, Z. L.; Liu, S. B. Acta Phys. Chim. Sin., 2010, 26: 291. [臧洋, 郝晓刚, 王忠德, 张忠林, 刘世斌. 物理化学学报, 2010, 26: 291]
27. [27]
  26. Zhang, J.; Kong, L. B.;Wang, N.; Luo, Y. C.; Kang, L. Synth. Met., 2009, 159: 260
28. [28]
  27. Lü, X. M.;Wu, Q. F.; Mi, H. Y.; Zhang, X. G. Acta Phys, Chim. Sin., 2007, 23: 820. [吕新美, 吴全福, 米红宇, 张校刚. 物理化学学报, 2007, 23: 820
1. [1]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
2. [2]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
3. [3]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
4. [4]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
5. [5]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
8. [8]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
9. [9]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
14. [14]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
15. [15]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
16. [16]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
17. [17]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
18. [18]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
19. [19]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
20. [20]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

Get Citation

PDF

XML

Metrics

PDF Downloads(1962)
Abstract views(4135)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142