Citation: CHEN Tian, WANG Tao, WANG Dao-Jun, ZHAO Jian-Qing, DING Xiao-Chun, WU Shi-Chao, XUE Hai-Rong, HE Jian-Ping. Selective Adsorption Behavior of Cu(II) and Cr(VI) Heavy Metal Ions by Functionalized Ordered Mesoporous Carbon[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3249-3256. doi: 10.3866/PKU.WHXB20101134 shu

Selective Adsorption Behavior of Cu(II) and Cr(VI) Heavy Metal Ions by Functionalized Ordered Mesoporous Carbon

1.
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 12 July 2010
Available Online: 14 October 2010
Fund Project: 国家自然科学基金(50871053)资助项目 (50871053)

An ordered mesoporous carbon -silica nanocomposite was synthesized by the evaporation - induced triconstituent co ?assembly method, wherein a soluble resol polymer was used as an organic precursor, tetraethoxysilane was used as an inorganic precursor, and the triblock copolymer F127 was used as the template. After the removal of silica with HF, ordered mesoporous pure carbon (OMC) was obtained. X-ray diffraction (XRD), N₂ adsorption -desorption isotherms (BET), and transmission electron microscopy (TEM) showed that the OMC product had a highly ordered structure with a large pore size of 6.4 nm, a pore volume of 2.13 cm³·g^-1, and a high surface area of 1330 m²·g^-1. The OMC was subsequently functionalized with ethylenediamine by treatment with nitric acid and thionyl chloride to obtain a functionalized ordered mesoporous carbon (C-NH₂(m)), m is the mass (g) of the added ethylenediamine. Fourier transform infrared (FTIR) spectroscopy showed that the amino group was successfully grafted onto the surface of the OMC. TEM images showed that C-NH₂(m) had a highly ordered mesoporous structure. OMC and C?NH₂(m) were used as adsorbents for the selective adsorption of Cu(II) and Cr(VI) ions from the aqueous solution. C?NH2(9.0) had a higher adsorption capacity for Cu(II) of 495.05 mg·g^-1 versus 213.33 mg·g^-1 for the OMC and a lower adsorption capacity for Cr(VI) of 68.21 mg·g^-1 versus 241.55 mg·g^-1 for the OMC, indicating its significantly favorable potential for the selective adsorption of Cu(II).
- Ordered mesoporous carbon,
- Amino ? functionalized grafting,
- Selective adsorption,
- Cu(II),
- Cr(VI)
1. [1]
  
  1. Feng, X.; Fryxell, G. E.;Wang, L. Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science, 1997, 276: 923
2. [2]
  2. Mercier, L.; Pinnavaia, T. J. Environ. Sci. Technol., 1998, 32: 2749
3. [3]
  3. Lee, J.; Yoon, S.; Hyeon, T.; Oh, S. M.; Kim, K. B. Chem. Commun., 1999: 2177
4. [4]
  4. Hartmann, M.; Vinu, A.; Chandrasekar, G. Chem. Mater., 2005, 17: 829
5. [5]
  5. Darmstadt, H.; Roy, C.; Kaliaguine, S.; Choi, S. J.; Ryoo, R. Carbon, 2002, 40: 2673
6. [6]
  6. Lu, A. H.; Li,W. C.; Schmidt,W.; Schüth, F. Microporous Mesoporous Mat., 2005, 80: 117
7. [7]
  7. Han, S.; Kim, M.; Hyeon, T. Carbon, 2003, 41: 1525
8. [8]
  8. Lee, J.; Han, S.; Hyeon, T. J. Mater. Chem., 2004, 14: 478
9. [9]
  9. Vinu, A.; Hossain, K. Z.; Kumar, G. S. Carbon, 2006, 44: 530
10. [10]
  10. Wan, Y.; Yang, H. F.; Zhao, D. Y. Acc. Chem. Res., 2006, 39: 423
11. [11]
  11. Tanaka, S.; Nishiyama, N.; Egashira, Y.; Ueyama, K. Chem. Commun., 2005: 2125
12. [12]
  12. Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Edit., 2005, 44: 7053
13. [13]
  13. Liang, C. D.; Dai, S. J. Am. Chem. Soc., 2006, 128: 5316
14. [14]
  14. Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Cheng, L.; Feng, D.; Wu, Z. X.; Chen, Z. X.;Wan, Y.; Stein, A.; Zhao, D. Y. Chem. Mater., 2006, 18: 4447
15. [15]
  15. Liu, R. L.; Shi, Y. F.;Wan, Y.; Meng, Y.; Zhang, F. Q.; Gu, D.; Chen, Z. X.; Tu, B.; Zhao, D. Y. J. Am. Chem. Soc., 2006, 128: 11652
16. [16]
  16. Wan, Y.; Shi, Y. F.; Zhao, D. Y. Chem. Commun., 2007: 897
17. [17]
  17. Wan, Y.; Shi, Y. F.; Zhao, D. Y. Chem. Mater., 2008, 20: 932
18. [18]
  18. Wan, Y.; Qian, X.; Jia, N. Q.;Wang, Z. Y.; Li, H. X.; Zhao, D. Y. Chem. Mater., 2007, 20: 1012
19. [19]
  19. Zhou, J. H.; He, J. P.;Wang, T.; Sun, D.; Zhao, G.W.; Chen, X.; Wang, D. J.; Di, Z. Y. J. Mater. Chem., 2008, 18: 5776
20. [20]
  20. Wang, T.; He, J. P.; Zhang, C. X.; Zhou, J. H.; Guo, Y. X.; Chen, X.; Di, Z. Y.; Sun, D.;Wang, D. J. Acta Phys. Chim. Sin., 2008, 24: 2314. [王涛, 何建平, 张传香, 周建华, 郭云霞, 陈秀, 狄志勇, 孙盾, 王道军. 物理化学学报, 2008, 24: 2314]
21. [21]
  21. Wang, T.; Zhou, J. H.;Wang, D. J.; Sun, D.; Di, Z. Y.; He, J. P. Acta Phys. Chim. Sin., 2009, 25: 2155. [王涛, 周建华, 王道军, 孙盾, 狄志勇, 何建平. 物理化学学报, 2009, 25: 2155]
22. [22]
  22. Sun, D.; He, J. P.; Zhou, J. H.;Wang, T.; Di, Z. Y.;Wang, D. J.; Ding, X. C. Acta Phys. Chim. Sin., 2010, 26: 385. [孙盾, 何建平, 周建华, 王涛, 狄志勇, 王道军, 丁晓春. 物理化学学报, 2010, 26: 385]
23. [23]
  23. Yang, J. P.; Zhai, Y. P.; Deng, Y. H.; Gu, D.; Li, Q.;Wu, Q. L.; Huang, Y.; Tu, B.; Zhao, D. Y. J. Colloid Interface Sci., 2010, 342: 579
24. [24]
  24. Wu, Z. X.;Webley, P. A.; Zhao, D. Y. Langmuir, 2010, 26: 10277
25. [25]
  25. Zhu, J. Z.; Yang, J.; Deng, B. L. New Carbon Materials, 2008, 23: 622. [祝建中, 杨嘉, Deng Baolin. 新型炭材料, 2008, 23: 622]
26. [26]
  26. Peng, H. Q.; Alemany, L. B.; Margrave, J. L.; Khabashesku, V. N. J. Am. Chem. Soc., 2003, 125: 15174
27. [27]
  27. Knocke,W. R.; Hemphill, L. H. Water Research, 1981, 15: 275
1. [1]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
2. [2]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
3. [3]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
4. [4]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
5. [5]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
6. [6]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
7. [7]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
8. [8]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
9. [9]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
10. [10]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
11. [11]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
12. [12]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
13. [13]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
14. [14]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
15. [15]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
16. [16]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
17. [17]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
18. [18]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
19. [19]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
20. [20]
  Zhongyan Cao , Shengnan Jin , Yuxia Wang , Yiyi Chen , Xianqiang Kong , Yuanqing Xu . Advances in Highly Selective Reactions Involving Phenol Derivatives as Aryl Radical Precursors. University Chemistry, 2025, 40(4): 245-252. doi: 10.12461/PKU.DXHX202405186

Get Citation

PDF

XML

Metrics

PDF Downloads(2432)
Abstract views(3302)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Selective Adsorption Behavior of Cu(II) and Cr(VI) Heavy Metal Ions by Functionalized Ordered Mesoporous Carbon

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com