Citation: WU Xin-Zhou, PEI Mei-Shan, WANG Lu-Yan, LI Xiao-Nan, TAO Xu-Tang. Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3095-3100. doi: 10.3866/PKU.WHXB20101132 shu

Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures

1.
1. Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China;
2. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China

Received Date: 21 April 2010
Available Online: 14 October 2010
Fund Project: 国家自然科学基金(50872042, 51003040) (50872042, 51003040) 晶体材料国家重点实验室(山东大学)开放课题(KF0802) (山东大学)开放课题(KF0802)山东省博士后创新项目专项资金 (200703075)资助 (200703075)

Silver tangled nanowires and dendritic structures were readily synthesized in high yield by reducing silver nitrate with different concentrations of ascorbic acid in a polyacrylamide (PAM) aqueous solution at mild conditions (normal temperature and pressure). The structures obtained all have tangled morphology, which is different from the silver nanowires reported previously. The structures of the obtained sliver structures were investigated using transmission electron microscopy (TEM), scanning electron microscopy (SEM), Raman spectroscopy, and UV-Vis spectroscopy. PAM plays a key role in the formation of these anisotropic nanostructures as the capping agent and as a soft template. During the initial stage, silver nuclei are formed and PAM molecules simultaneously adsorb on their surfaces. Then, small silver particles will collide with each other along the polymer chains leading to the formation of tangled structures. Additionally, a too high concentration of ascorbic acid is unfavorable for the growth of tangled silver nanowires, and dendritic structures are formed. The surface-enhanced Raman scattering (SERS) activity was investigated using p-aminothiophenol (PATP) as a probe molecule. The silver tangled nanowires and dendritic structures show efficient surface enhanced Raman scattering property.
- Silver,
- Tangled,
- Nanowire,
- Dendritic,
- Surface-enhanced Raman scattering
1. [1]
  
  1. Yao, H.; Liu, J.; Duan, J. L.; Hou, M. D.; Sun, Y. M.; Mo, D.; Chen, Y. F.; Xue, Z. H. Acta Phys. -Chim. Sin., 2007, 23: 489
2. [2]
  [姚会军, 刘杰, 段敬来, 侯明东, 孙友梅, 莫丹, 陈艳峰, 薛智浩. 物理化学学报, 2007, 23: 489]
3. [3]
  2. Fu, X.; Zou, H.; Zhou, L.; Zhou, Z.; Yu, X.; Hao, Z. Acta Phys. -Chim. Sin., 2008, 24: 781
4. [4]
  [付小锋, 邹化民, 周利, 周张凯, 喻学峰, 郝中华. 物理化学学报, 2008, 24: 781]
5. [5]
  3. Chi, G.; Yao, S.; Fan, J.; Zhang, W.; Wang, H. Acta Phys. -Chim. Sin., 2002, 18: 532
6. [6]
  [迟广俊, 姚素薇, 范君, 张卫国, 王宏智. 物理化学学报, 2002, 18: 532]
7. [7]
  4. Xia, Y.; Yang, P.; Sun, Y.; Wu, Y.; Mayers, B.; Gates, B.; Yin, Y.; Kim, F.; Yan, H. Adv. Mater., 2003, 15: 353
8. [8]
  5. Sarkar, R.; Kumbhakar, P.; Mitra, A. K.; Ganeev, R. A. Current Appl. Phys., 2010, 10: 853
9. [9]
  6. Kostowskyj, M. A.; Gilliama, R. J.; Kirkb, D. W.; Thorpe, S. J. Int. J. Hydrog. Energy, 2008, 33: 5773
10. [10]
  7. Gao, Y.; Jiang, P.; Liu, D. F.; Yuan, H. J.; Yan, X. Q.; Zhou, Z. P.; Wang, J. X.; Song, L.; Liu, L. F.; Zhou, W. Y.; Wang, G.; Wang, C. Y.; Xie, S. S. Chem. Phys. Lett., 2003, 380: 146
11. [11]
  8. Jiang, Z. Y.; Xie, Z. X.; Zhang, S. H.; Xie, S. Y.; Huang, R. B.; Zheng, L. S. Chem. Phys. Lett., 2003, 374: 645
12. [12]
  9. Chen, C.; Wang, L.; Yu, H.; Jiang, G.; Yang, Q.; Zhou, J.; Xiang W.; Zhang, J. Mater. Chem. Phys., 2008, 107: 13
13. [13]
  10. Tae Young Kim; Kim, W. J.; Hong, S. H.; Kim, J. E.; Suh, K. S. Angew. Chem. Int. Edit., 2009, 48: 3806
14. [14]
  11. Sanders, A. W.; Routenberg, D. A.; Wiley, B. J.; Xia, Y.; Dufresne, E. R.; Reed, M. A. Nano Lett., 2006, 6: 1822
15. [15]
  12. Kang, T.; Yoon, I.; Jeon, K. S.; Choi, W.; Lee, Y.; Seo, K.; Yoo, Y.; Park, Q. H.; Ihee, H.; Suh, Y. D.; Kim, B. J. Phys. Chem. C, 2009, 113: 7492
16. [16]
  13. Tanga, X.; Tsuji, M.; Jiang, P.; Nishio, M.; Jang, S. M.; Yoon, S. H. Colloids and Surfaces A, 2009, 338: 36
17. [17]
  14. Mondal, B.; Majumdar, D.; Saha, S. K. J. Mater. Res., 2010, 25: 383
18. [18]
  15. Krigbaum, W. R.; Geyme, D. O. J. Am. Chem. Soc., 1959, 81: 1859
19. [19]
  16. Ye, W.; Shen, C.; Tian, J.; Wang, C.; Hui, C.; Gao, H. Solid State Sci., 2009, 11: 1088.
20. [20]
  17. Chen, J.; Wiley, B. J.; Xia, Y. Langmuir, 2007, 23: 4120
21. [21]
  18. Caswell, K. K.; Bender, C. M.; Murphy, C. J. Nano Lett., 2003, 3: 667
22. [22]
  19. Mdluli, P. S.; Revaprasadu, N. Mater. Lett., 2009, 63: 447
23. [23]
  20. Brennan, M. E.; Whelan, A. M.; Kelly, J. M.; Blau, W. J. Synth. Met., 2005, 154: 205
24. [24]
  21. Gao, Y.; Jiang, P.; Song, L.; Liu, L.; Yan, X.; Zhou, Z.; Liu, D.; Wang, J.; Yuan, H.; Zhang, Z.; Zhao, X.; Dou, X.; Zhou, W.; Wang, G.; Xie, S. J. Phys. D-Appl. Phys., 2005, 38: 1061
25. [25]
  22. Sun, Y.; Yin, Y.; Mayers, B. T.; Herricks, T.; Xia, Y. Chem. Mater., 2002, 14: 4736
26. [26]
  23. Zhang, J.; Liu, K.; Dai, Z.; Feng, Y.; Bao, J.; Mo, X. Mater. Chem. Phys., 2006, 100: 313
27. [27]
  24. Zou, X.; Ying, E.; Dong, S. J. Colloid Interface Sci., 2007, 306: 307
28. [28]
  25. Wu, D. Y.; Liu, X. M.; Huang, Y. F.; Ren, B.; Xu, X.; Tian, Z. Q. J. Phys. Chem. B, 2009, 113: 18212
29. [29]
  26. Jana, N. R.; Pal, T. Adv. Mater., 2007, 19: 1761
30. [30]
  27. Wang, Y.; Camar , P. H. C.; Skrabalak, S. E.; Gu, H.; Xia, Y. Langmuir, 2008, 24: 12042
1. [1]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
2. [2]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
3. [3]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
4. [4]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
5. [5]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
6. [6]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
7. [7]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
8. [8]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
9. [9]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
10. [10]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
11. [11]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
12. [12]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
13. [13]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
14. [14]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
15. [15]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
16. [16]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
17. [17]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
18. [18]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
19. [19]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
20. [20]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055

Get Citation

PDF

XML

Metrics

PDF Downloads(1633)
Abstract views(3066)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142