Citation: HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong. Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3073-3079. doi: 10.3866/PKU.WHXB20101127 shu

Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole

  • Received Date: 20 May 2010
    Available Online: 9 October 2010

    Fund Project: 国家自然科学基金(60977038, 50873026, 60910187) (60977038, 50873026, 60910187)江苏省科技支撑计划(BE2008129)资助 (BE2008129)

  • Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to prepare novel nonlinear optical (NLO) side-chain fluorinated polyimides by the Mitsunobu reaction. Their structures were verified by Fourier transform infrared (FT-IR) spectra, UV-visible (UV-Vis) spectra, 1H nuclear magnetic resonance (1H NMR) spectra, and gel permeation chromatography (GPC). Thermal analysis results indicate that the side-chain polyimides have high glass transition temperatures (Tg) between 184 and 188℃ and thermal decomposition temperatures (Td) up to 322℃. The electro-optic coefficients (γ33) of the side-chain polyimides were measured by a simple reflection technique at 1550 nm. The fluorinated polyimide PI1 containing a benzothiazolylazoaniline chromophore possesses a high electro-optic coefficient of 15 pm·V-1.

     

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