Citation:
HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong. Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole[J]. Acta Physico-Chimica Sinica,
;2010, 26(11): 3073-3079.
doi:
10.3866/PKU.WHXB20101127
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Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to prepare novel nonlinear optical (NLO) side-chain fluorinated polyimides by the Mitsunobu reaction. Their structures were verified by Fourier transform infrared (FT-IR) spectra, UV-visible (UV-Vis) spectra, 1H nuclear magnetic resonance (1H NMR) spectra, and gel permeation chromatography (GPC). Thermal analysis results indicate that the side-chain polyimides have high glass transition temperatures (Tg) between 184 and 188℃ and thermal decomposition temperatures (Td) up to 322℃. The electro-optic coefficients (γ33) of the side-chain polyimides were measured by a simple reflection technique at 1550 nm. The fluorinated polyimide PI1 containing a benzothiazolylazoaniline chromophore possesses a high electro-optic coefficient of 15 pm·V-1.
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