Citation: ZHAN Yong- ng, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin. Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3113-3119. doi: 10.3866/PKU.WHXB20101119 shu

Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals

1.
1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Received Date: 9 July 2010
Available Online: 24 September 2010
Fund Project: 科技支撑计划重点课题(2006BAE02B05) (2006BAE02B05)国家重点基础研究发展规划项目(973) (2005CB221406)资助 (973) (2005CB221406)

We synthesized novel α-Fe₂O₃ nanocrystals (NFO-1) with single crystalline structure. In our synthetic strategy, the morphology and structure can be controlled simultaneously by the choice of inorganic salt (IS) and organic template (OT) in the extremely low precursor concentration reaction system. The evaporation-induced self-assembly (EISA) method was used to accelerate the reaction and to recover the synthesized α-Fe₂O₃ with high yields while preserving its favorable shape and structure. The morphologies and structures of the obtained α-Fe₂O₃ nanocrystals greatly influence their surface functionalization capability. The chemical interaction between NFO-1 and the surface functionalization agent (dopamine) was obviously enhanced because of its special spindle-likemorphology. The synthesis method described in this paper is suitable for the synthesis of other transition metal oxide single nanocrystals as well and we expect that this new route will be useful for the synthesis of novel nanomaterials.
- α-Fe₂O₃ nanocrystal,
- Template-direction,
- Evaporation-induced self-assembly,
- Surface functionalization
1. [1]
  
  1. Lin, Y.;Wu, S.; Hung, Y.; Chou, Y.; Chang, C.; Lin, M.; Tsai, C.; Mou, C. Chem. Mater., 2006, 18: 5170
2. [2]
  2. Yada, M.; Ohya, M.; Machida, M.; Kijima, T. Langmuir, 2000, 16: 4752
3. [3]
  3. Nelson, P.; Elliott, J. M.; Attard, G. S.; Owen, J. R. Chem. Mater., 2002, 14: 524
4. [4]
  4. Teng, X.; Han, W.; Ku, W.; Hücker, M. Angew. Chem. Int. Edit., 2008, 47: 2055
5. [5]
  5. Srivastava, D. N.; Perkas, N.; Gedanken, A.; Felner, I. J. Phys. Chem. B, 2002, 106: 1878
6. [6]
  6. Jiao, F.; Bruce, P. G. Angew. Chem. Int. Edit., 2004, 43: 5958
7. [7]
  7. Jiao, F.; Jumas, J. C.; Womes, M.; Chadwick, A. V.; Harrison, A.; Bruce, P. G. J. Am. Chem. Soc., 2006, 128: 12905
8. [8]
  8. Epling,W. S.; Hoflund, G. B.; Weaver, J. F.; Tsubota, S.; Haruta, M. J. Phys. Chem., 1996, 100: 9929
9. [9]
  9. Pickard, J. M.; Jones, E. G. Energy&Fuels, 1997, 11: 1232
10. [10]
  10. Lai, J.; Shafi, K. V. P. M.; Loos, K.; Ulman, A.; Lee, Y.; Vogt, T.; Estournès, C. J. Am. Chem. Soc., 2003, 125: 11470
11. [11]
  11. Wu, C.; Yin, P.; Zhu, X.; Ouyang, C.; Xie, Y. J. Phys. Chem. B, 2006, 110: 17806
12. [12]
  12. Tang, B.; Wang, G.; Zhuo, L.; Ge, J.; Cui, L. Inorg. Chem., 2006, 45: 5196
13. [13]
  13. Yamada, K.; Mukaihata, N.; Kawahara, T.; Tada, H. Langmuir, 2007, 23: 8593
14. [14]
  14. Zhong, Z.; Ho, J.; Teo, J.; Shen, S.; Gedanken, A. Chem. Mater., 2007, 19: 4776
15. [15]
  15. Han, L.; Shan, Z.; Chen, D.; Yu, X.; Yang, P.; Tu, B.; Zhao, D. J. Colloid Interface Sci., 2008, 318: 315
16. [16]
  16. Kenning, G. G.; Rodriguez, R.; Zotev, V. S.; Moslemi, A.; Wilson, S.; Hawel, L.; Byus, C.; Kovach, J. S. Rev. Sci. Instrum., 2005, 76: 014303
17. [17]
  17. Perez, J. M.; Simeone, F. J.; Saeki, Y.; Josephson, L.; Weissleder, R. J. Am. Chem. Soc., 2003, 125: 10192
18. [18]
  18. Shultz, M. D.; Reveles, J. U.; Khanna, S. N.; Carpenter, E. E. J. Am. Chem. Soc., 2007, 129: 2482
19. [19]
  19. Rockenberger, J.; Scher, E. C.; Alivisatos, A. P. J. Am. Chem. Soc.,1999, 121: 11595
20. [20]
  20. Woo, K.; Lee, H. J.; Ahn, J. P.; Park, Y. S. Adv. Mater., 2003, 15: 1761
21. [21]
  21. Wang, X.; Zhuang, J.; Peng, Q.; Li, Y. Nature, 2005, 437: 121
22. [22]
  22. Deng, H.; Li, X.; Peng, Q.; Wang, X.; Chen, J.; Li, Y. Angew. Chem. Int. Edit., 2005, 44: 2782
23. [23]
  23. Vayssieres, L.; Sathe, C.; Butorin, S. M.; Shuh, D. K.; Nordgren, J.; Guo, J. Adv. Mater., 2005, 17: 2320
24. [24]
  24. Jia, C.; Sun, L.; Yan, Z.; You, L.; Luo, F.; Han, X.; Pang, Y.; Zhang, Z.; Yan, C. Angew. Chem. Int. Edit., 2005, 44: 4328
25. [25]
  25. Sun, S.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.; Wang, S.; Li, G. J. Am. Chem. Soc., 2004, 126: 273
26. [26]
  26. Jia, C.; Sun, L.; Luo, F.; Han, X.; Heyderman, L.; Yan, Z.; Yan, C.; Zheng, K.; Zhang, Z.; Takano, M.; Hayashi, N.; Eltschka, M.; Kläui, M.; Rüdiger, U.; Kasama, T.; Cervera- ntard, L.; Dunin- Borkowski, R. E.; Tzvetkov, G.; Raabe, J. J. Am. Chem. Soc., 2008, 130: 16968
27. [27]
  27. Lu, Y.; Fan, H.; Stump, A.; Ward, T. L.; Rieker, T.; Brinker, C. J. Nature, 1999, 398: 223
28. [28]
  28. Wu, Y.; Cheng, G.; Katsov, K.; Sides, S. W.; Wang, J.; Tang, J.; Fredrickson, G. H.; Moskovits, M.; Stucky, G. D. Nature Mater., 2004, 3: 816
29. [29]
  29. Che, S.; Liu, Z.; Ohsuna, T.; Sakamoto, K.; Terasaki, O.; Tatsumi, T. Nature, 2004, 429: 281
30. [30]
  30. Koganti, V. R.; Dunphy, D.; wrishankar, V.; McGehee, M. D.; Li, X.; Wang, J.; Rankin, S. E. Nano Lett., 2006, 6: 2567
31. [31]
  31. Zhang, A.; Zhang, Y.; Xing, N.; Hou, K.; Guo, X. Chem. Mater., 2009, 21: 4122
32. [32]
  32. Bieniecki, A.;Wilk, K. A.; Gapi俳ski, K. J. Phys. Chem. B, 1997, 101: 871
33. [33]
  33. Zhang, Y.; Raman, N.; Bailey, J. K.; Brinker, C. J.; Crooks, R. M. J. Phys. Chem., 1992, 96: 9098
34. [34]
  34. Yang, P.; Zhao, D.; Mar lese, D. I.; Chmelka, B. F.; Stucky, G. D. Nature, 1998, 396: 152
35. [35]
  35. Brinker, C. J.; Lu, Y.; Sellinger, A.; Fan, H. Adv. Mater., 1999, 11: 579
36. [36]
  36. Yang, P.; Zhao, D.; Mar lese, D. I.; Chmelka, B. F.; Stucky, G. D. Chem. Mater., 1999, 11: 2813
37. [37]
  37. Alberius, P. C. A.; Frindell, K. L.; Hayward, R. C.; Kramer, E. J.; Stucky, G. D.; Chmelka, B. F. Chem. Mater., 2002, 14: 3284
38. [38]
  38. Bartl, M. H.; Puls, S. P.; Tang, J.; Lichtenegger, H. C.; Stucky, G. D. Angew. Chem., Int. Edit., 2004, 43: 3037
39. [39]
  39. Jiang, X.; Brinker, C. J. J. Am. Chem. Soc., 2006, 128: 4512
40. [40]
  40. Pang, J.; Xiong, S.; Jaeckel, F.; Sun, Z.; Dunphy, D.; Brinker, C. J. J. Am. Chem. Soc., 2008, 130: 3284
41. [41]
  41. Zhan, Y.; Cai, B.; Wang, B.; Huang, X.; Zhang, P.; Li, L.; Wu, Z.; Yin, Z.; Chen, Q. J. Mater. Chem., 2008, 18: 5967
42. [42]
  42. Li, Y.; Ge, X.; Zhang, Z.; Ye, Q. Chem. Mater., 2002, 14: 1048
43. [43]
  43. Brezesinski, T.; Groenewolt, M.; Antonietti, M.; Smarsly, B. Angew. Chem., Int. Edit., 2006, 45: 781
44. [44]
  44. Li, S.; Zhang, H.; Wu, J.; Ma, X.; Yang, D. Cryst. Growth Des., 2006, 6: 351
45. [45]
  45. Chen, M.; Liu, J.; Sun, S. J. Am. Chem. Soc., 2004, 126: 1950
46. [46]
  46. Cao, M.; Liu, T.; Gao, S.; Sun, G.; Wu, X.; Hu, C.; Wang, Z. Angew. Chem. Int. Edit., 2005, 44: 4197
47. [47]
  47. Cao, H.; Wang, G.; Zhang, L.; Liang, Y.; Zhang, S.; Zhang, X. ChemPhyChem, 2006, 7: 1897
48. [48]
  48. Zhang, P.; Zhan, Y.; Cai, B.; Hao, C.; Wang, J.; Liu, C.; Meng, Z.; Yin, Z.; Chen, Q. Nano Res., 2010, 3: 235
49. [49]
  49. Xu, C.; Xu, K.; Gu, H.; Zheng, R.; Liu, H.; Zhang, X.; Guo, Z.; Xu, B. J. Am. Chem. Soc., 2004, 126: 9938
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
3. [3]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
4. [4]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
5. [5]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
6. [6]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
7. [7]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
8. [8]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
9. [9]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
10. [10]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
11. [11]
  Qiying Xia , Guokui Liu , Yunzhi Li , Yaoyao Wei , Xia Leng , Guangli Zhou , Aixiang Wang , Congcong Mi , Dengxue Ma . Construction and Practice of “Teaching-Learning-Assessment Integration” Model Based on Outcome Orientation: Taking “Structural Chemistry” as an Example. University Chemistry, 2024, 39(10): 361-368. doi: 10.3866/PKU.DXHX202311007
12. [12]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
13. [13]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
14. [14]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
15. [15]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
16. [16]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
17. [17]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
18. [18]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069

Get Citation

PDF

XML

Metrics

PDF Downloads(1290)
Abstract views(2500)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe2O3 Nanocrystals

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals