Citation: ZHAN Yong- ng, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin. Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3113-3119. doi: 10.3866/PKU.WHXB20101119 shu

Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals

1.
1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Received Date: 9 July 2010
Available Online: 24 September 2010
Fund Project: 科技支撑计划重点课题(2006BAE02B05) (2006BAE02B05)国家重点基础研究发展规划项目(973) (2005CB221406)资助 (973) (2005CB221406)

We synthesized novel α-Fe₂O₃ nanocrystals (NFO-1) with single crystalline structure. In our synthetic strategy, the morphology and structure can be controlled simultaneously by the choice of inorganic salt (IS) and organic template (OT) in the extremely low precursor concentration reaction system. The evaporation-induced self-assembly (EISA) method was used to accelerate the reaction and to recover the synthesized α-Fe₂O₃ with high yields while preserving its favorable shape and structure. The morphologies and structures of the obtained α-Fe₂O₃ nanocrystals greatly influence their surface functionalization capability. The chemical interaction between NFO-1 and the surface functionalization agent (dopamine) was obviously enhanced because of its special spindle-likemorphology. The synthesis method described in this paper is suitable for the synthesis of other transition metal oxide single nanocrystals as well and we expect that this new route will be useful for the synthesis of novel nanomaterials.
- α-Fe₂O₃ nanocrystal,
- Template-direction,
- Evaporation-induced self-assembly,
- Surface functionalization
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Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe₂O₃ Nanocrystals