Citation: LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu. Fabrication of Al₂O₃ Nanoparticles by Cathodic Plasma Electrolysis[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3106-3112. doi: 10.3866/PKU.WHXB20101114 shu

Fabrication of Al₂O₃ Nanoparticles by Cathodic Plasma Electrolysis

1.
Key Laboratory for Physics and Chemistry of Nanodevices, Ministry of Education, Department of Electronics, Peking University, Beijing 100871, P. R. China

Received Date: 24 May 2010
Available Online: 21 September 2010
Fund Project: 国家自然科学基金(60971002) (60971002)国家基础研究重大项目计划(973)(2006CB932402)资助 (973)(2006CB932402)

We used aluminum as the cathodic material and an aqueous solution of 3 mol·L^-1 NH₄NO₃ as the electrolyte in our work. Al₂O₃ nanoparticles were fabricated using asymmetrical electrodes during cathodic plasma electrolysis. The morphology and structure of the particles were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray energy dispersion (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). We identified cubic Al₂O₃ as the main component. The changes in current and optical emission phenomena during the cathodic plasma electrolysis were also studied. Based on the experimental results, we discuss the mechanisms responsible for particle formation.
- Cathodic plasma electrolysis,
- Al₂O₃ nanoparticle,
- Cathodic ablation,
- Solution oxidation,
- Microscopic characterization
1. [1]
  
  1. Shi, Z. J.; Lian, Y. F.; Zhou, X. H.; Gu, Z. N.; Zhang, Y. G.; Iijima, S.; Zhou, L. X.; Yue, K. T.; Zhang, S. L. Carbon, 1999, 37: 1449
2. [2]
  2. Cao, Z.; Walsh, J. L.; Kong, M. G. Appl. Phys. Lett., 2009, 94: 021501
3. [3]
  3. Akiyama, H.; Zettsu, N.; Yamamura, K. Thin Solid Films, 2010, 13: 3551
4. [4]
  4. Furusho, H.; Kitano, K.; Hamaguchi, S.; Nagasaki, Y. Chem. Mater., 2009, 21: 3526
5. [5]
  5. Guan, Y. J.; Xia, Y. Advances in Mechanics, 2004, 34: 237 [关永军,夏原.力学进展, 2004, 34: 237]
6. [6]
  6. Yang, X. Z.; He, Y. D.; Wang, D. R.; Gao, W. Science Bulletin, 2002, 47: 525 [杨晓战,何业东,王德仁,高唯. 科学通报, 2002, 47: 525]
7. [7]
  7. Tokushige, M.; Nishikiori, T.; Ito, Y. J. Appl. Electrochem., 2009, 39: 1665
8. [8]
  8. Aliofkhazraei, M.; Hassanzadeh-Tabrizi, S. A.; Rouhaghdam, A. S.; Heydarzadeh, A. Ceram. Int., 2009, 35: 2053
9. [9]
  9. Aliofkhazraei, M.; Rouhaghdam, A. S.; Heydarzadeh, A.; Elmkhah, H. Mater. Chem. Phys., 2009, 113: 607
10. [10]
  10. Paulmier, T.; Bell, J. M.; Fredericks, P. M. Thin Solid Films, 2007, 515: 2926
11. [11]
  11. Paulmier, T.; Bell, J. M.; Fredericks, P. M. J. Mater. Process. Technol., 2008, 208: 117
12. [12]
  12. Richmonds, C.; Sankaran, R. M. Appl. Phys. Lett., 2008, 93: 131501
13. [13]
  13. Toriyabe, Y.; Watanabe, S.; Yatsu, S.; Shibayama, T.; Mizuno, T. Appl. Phys. Lett., 2007, 91: 041501
14. [14]
  14. Azumi, K.; Kanada, A.; Seo, M.; Mizuno, T. Electrochimica Acta, 2007, 52: 4463
15. [15]
  15. Mizuno, T.; Akimoto, T.; Azumi, K.; Ohmort, T.; Aoki, Y.; Takahashi, A. Jpn. J. Appl. Phys., 2005, 44: 396
16. [16]
  16. Yan, Z. C.; Chen, L.; Wang, H. L. Acta Phys. -Chim. Sin., 2007, 23: 835 [严宗诚, 陈砺, 王红林.物理化学学报, 2007, 23: 835]
17. [17]
  17. Pearse, P. W. B.; Gaydon, A. G. The identification of molecular spectra. 2nd ed. London: Chapman&Hall Ltd., 1950: 51-265
1. [1]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
2. [2]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
3. [3]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
6. [6]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
8. [8]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
9. [9]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
10. [10]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
13. [13]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
14. [14]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
15. [15]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
16. [16]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
19. [19]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(1306)
Abstract views(2452)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Al2O3 Nanoparticles by Cathodic Plasma Electrolysis

Metrics

通讯作者: 陈斌, bchen63@163.com

Fabrication of Al₂O₃ Nanoparticles by Cathodic Plasma Electrolysis