Citation: SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao. Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3023-3029. doi: 10.3866/PKU.WHXB20101109 shu

Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16

1.
Institute of Industrial Ecology and Environment, Zhejiang University, Hangzhou 310028, P. R. China

Received Date: 27 June 2010
Available Online: 15 September 2010
Fund Project: 国家自然科学基金(20976159)资助项目 (20976159)

Novel CO₂ adsorbents for CO₂ removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesoporous silica using a post-synthetic impregnation method. The properties of the mesoporous materials before and after surface modification were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), and N₂ adsorption-desorption. We confirmed that TEPA was loaded onto the surface of the channels in the mesoporous materials. The surface area, pore size, and pore volume of TEPA-loaded SBA-16 decreased with an increase in TEPA loading while its fundamental pore structure was unchanged. The dynamic adsorption of CO₂ onto TEPA-loaded SBA-16 as well as its regeneration property was studied in a packed column. The total adsorption capacity and breakthrough capacity increased when the amount of loaded TEPA increased from 10% to 30% (w). The sample impregnated with 30% TEPA showed the highest breakthrough capacity and total adsorption capacity of about 0.625 and 0.973 mmol·g^-1 at 60℃, respectively. From 60℃ to 80℃, the CO₂ dynamic adsorption behavior of TEPA-loaded SBA-16 was stable. The total adsorption capacity of CO₂ on TEPA-loaded SBA-16 dropped slightly (6.45%) after 20 adsorption-desorption regeneration cycles. Their CO₂ adsorption behavior was also investigated using the deactivation model, which showed an excellent predictive capability for the breakthrough curves.
- SBA-16,
- Dynamic,
- Breakthrough curve,
- Deactivation model,
- CO₂ adsorption
1. [1]
  
  1. Idem, R.; Tontiwachwuthikul, P. Ind. Eng. Chem. Res., 2006, 45: 2413
2. [2]
  2. Yang, H. Q.; Xu, Z. H.; Fan, M. H.; Fan, M. H.; Gupta, R.; Slimane, R. B.; Bland, A. E.; Wright, I. J. Environ. Sci., 2008, 20: 14
3. [3]
  3. Aaron, D.; Tsouris, C. Separ. Sci. Technol., 2005, 40: 321
4. [4]
  4. Oyenekan, B. A.; Rochelle, G. T. AICHE J., 2007, 53: 3144
5. [5]
  5. Veawab, A.; Tontiwachwuthikul, P.; Chakma, A. Ind. Eng. Chem. Res., 1999, 38: 3917
6. [6]
  6. Katoh, M.; Yoshikawa, T.; Tomonari, T.; Katayama, K.; Tomida, T. J. Colloid Interface Sci., 2000, 226: 145
7. [7]
  7. Li, P. Y.; Zhang, S. J.; Chen, S. X.; Zhang, Q. K.; Pan, J. J.; Ge, B. Q. J. Appl. Polym. Sci., 2008, 108: 3851
8. [8]
  8. Lee, J. S.; Kim, J. H.; Kim, J. T.; Suh, J. W.; Lee, J. M.; Lee, C. H. J. Chem. Eng. Data, 2002, 47: 1237
9. [9]
  9. Siriwardane, R. V.; Shen, M. S.; Fisher, E. P.; Poston, J. A. Energy Fuels, 2001, 15: 279
10. [10]
  10. Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mat., 2008, 113: 31
11. [11]
  11. Wei, J.W.; Shi, J. J.; Pan, H.; Zhao,W.; Ye, Q.; Shi, Y.Microporous Mesoporous Mat., 2008, 116: 394
12. [12]
  12. Choi, S.; Drese, J. H.; Jones, C. W. ChemSusChem, 2009, 2: 796
13. [13]
  13. Li, L.; Yuan,W. H.; Wei, C. H. Chem. Ind. Eng. Prog., 2006, 25: 918 [李莉, 袁文辉,韦朝海.化工进展, 2006, 25: 918]
14. [14]
  14. Xu, X. C.; Song, C. S.; Andresen, J. M.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Microporous Mesoporous Mat., 2003, 62: 29
15. [15]
  15. Wang, L. F.; Ma, L.; Wang, A. Q.; Liu, Q.; Zhang, T. Chin. J. Catal., 2007, 28: 805 [王林芳,马磊,王爱琴,刘茜,张涛. 催化学报, 2007, 28: 805]
16. [16]
  16. Zhao, H. L.; Hu, J.; Wang, J. J.; Zhou, L. H.; Liu, H. L. Acta Phys. - Chim. Sin., 2007, 23: 801 [赵会玲,胡军, 汪建军,周丽绘,刘洪来.物理化学学报, 2007, 23: 801]
17. [17]
  17. Kim, S. N.; Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mat., 2008, 115: 497
18. [18]
  18. Knofel, C.; Descarpentries, J.; Benzaouia, A.; Zelenak, V.; Mornet, S.; Llewellyn, P. L.; Hornebecq, V. Microporous Mesoporous Mat., 2007, 99: 79
19. [19]
  19. Yue, M. B.; Sun, L. B.; Cao, Y.; Wang, Y.; Wang, Z. J.; Zhu, J. H. Chem. Eur. J., 2008, 14: 3442
20. [20]
  20. Kim, T. W.; Ryoo, R.; Kruk, M.; Gierszal, K. P.; Jaroniec, M.; Kamiya, S.; Terasak, O. J. Phys. Chem. B, 2004, 108: 11480
21. [21]
  21. Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc., 1998, 120: 6024
22. [22]
  22. Kleitz, F.; Czuryszkiewicz, T.; Solovyov, L. A.; Lindn, M. Chem. Mater., 2006, 18: 5070
23. [23]
  23. Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Energy Fuels, 2001, 15: 250
24. [24]
  24. Kim, T. W.; Ryoo, R.; Kruk, M.; Gierszal, K. P.; Jaroniec, M.; Kamiya, S.; Terasaki, O. J. Phys. Chem. B, 2004, 108: 11480
25. [25]
  25. Yasyerli, S.; Dogu, G.; Ar, I.; Dogu, T. Ind. Eng. Chem. Res., 2001, 40: 5206
26. [26]
  26. Kopac, T.; Kocabas, S. Chem. Eng. Commun., 2003, 190: 1041
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16

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通讯作者: 陈斌, bchen63@163.com

Dynamic Performance of CO₂ Adsorption with Amine-Modified SBA-16