Citation: WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua. Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 2951-2956. doi: 10.3866/PKU.WHXB20101107 shu

Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt

1.
Key Laboratory of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 4 May 2010
Available Online: 13 September 2010
Fund Project: 国家自然科学基金(20803025) (20803025) 广东省自然科学基金(8451064101000891) (8451064101000891)华南理工大学中央高校基本科研业务经费专项资金(2009ZM0026) 资助项目 (2009ZM0026)

A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composite electrode was prepared by constant-potential electropolymerization using AQS as a counter-ion. Cyclic voltammetry (CV), galvanostatic charge-discharge, and electrochemical impedance spectroscopy (EIS) were used to evaluate its capacitance performance. Experimental results show that the AQS dopant results in an improved specific capacitance, increased long-cycle stability, and a wide working potential range compared to that of using ClO^-₄ as the dopant. The PPy/AQS composite electrode has a specific capacitance of 491 F·g^-1 at a CV scan rate of 50 mV·s^-1 within a potential range of -0.6 to 0.6 V in 1 mol·L^-1 KCl, which is 1.5 times more than that with a PPy/ClO^-₄ composite electrode. The improvement in capacitance should be attributed to the od redox performance of AQS and the porous submicron/ nanosized structure of the resulting composite film.
- Anthraquinone sulfonate,
- Polypyrrole,
- Electrochemical capacitor,
- Electropolymerization,
- Charge-discharge test
1. [1]
  
  1. Conway, B. E. Electrochemical supercapacitors: scientific fundamentals and technological applications. NewYork: Kluwer Academic, 1999: 183
2. [2]
  2. An, H. F.; Wang, X. Y.; Li, N.; Zheng, L. P.; Chen, Q. Q. Progress in Chemistry, 2009, 21(9): 1832 [安红芳,王先友, 李娜,郑丽萍, 陈权启.化学进展, 2009, 21(9): 1832]
3. [3]
  3. Winter, M.; Brodd, R. J. Chem. Rev., 2004, 104(10): 4245
4. [4]
  4. Song, R. Y.; Park, J. H.; Sivakkumar, S. R.; Kim, S. H.; Ko, J. M.; Park, D. Y.; Jo, S. M.; Kim, D. Y. J. Power Sources, 2007, 166(1): 297
5. [5]
  5. Sharma, R. K.; Rastogi, A. C.; Desu, S. B. Electrochim. Acta, 2008, 53(26): 7690
6. [6]
  6. Wang, J.; Xu, Y. L.; Chen, X.; Du, X. F.; Li, X. F. Acta Phys. - Chim. Sin., 2007, 23(3): 299 [王杰, 徐友龙,陈曦,杜显锋, 李喜飞.物理化学学报, 2007, 23(3): 299]
7. [7]
  7. Chen, H.; Chen, J. S.; Zhou, H. H.; Jiao, S. Q.; Chen, J. H.; Kuang, Y. F. Acta Phys. -Chim. Sin., 2004, 20(6): 593 [陈宏,陈劲松, 周海晖,焦树强,陈金华,旷亚非.物理化学学报, 2004, 20(6): 593]
8. [8]
  8. Kim, B. C.; Ko, J. M.; Wallace, G. G. J. Power Sources, 2008, 177 (2): 665
9. [9]
  9. Algharaibeh, Z.; Liu, X.; Pickup, P. G. J. Power Sources, 2009, 187(2): 640
10. [10]
  10. Groenendaal, L. B.; Jonas, F. F. Adv. Mater., 2000, 12: 481
11. [11]
  11. Weidlich, C.; Man ld, K. M.; Jüttner, K. Electrochim. Acta, 2005, 50(7-8): 1547
12. [12]
  12. Algharaibeh, Z.; Liu, X.; Pickup, P. G. J. Power Sources, 2009, 187(2): 640
13. [13]
  13. Kalinathan, K.; Des Roches, D. P.; Liu, X.; Pickup, P. G. J. Power Sources, 2008, 181(1): 182
14. [14]
  14. Seredych, M.; Hulicova-Jurcakova, D.; Lu, G. Q.; Bandosz, T. J. Carbon, 2008, 46(11): 1475
15. [15]
  15. Hepel, M. Electrochim. Acta, 1996, 41(1): 63
16. [16]
  16. Ingram, M. D.; Staesche, H.; Ryder, K. S. J. Power Sources, 2004, 129(1): 107
17. [17]
  17. Feng, C.; Chan, P. C. H.; Hsing, I. M. Electrochem. Commun., 2007, 9(1): 89
18. [18]
  18. Feng, C.; Ma, L.; Li, F.; Mai, H.; Lang, X.; Fan, S. Biosens. Bioelectron., 2010, 25: 1516
19. [19]
  19. Rubinger, C. P. L.; Martins, C. R.; De Paoli, M. A.; Rubinger, R. M. Sens. Actuators B, 2007, 123(1): 42
20. [20]
  20. Kumar, S. S.; Kumar, C. S.; Mathiyarasu, J.; Phani, K. L. Langmuir, 2007, 23(6): 3401
21. [21]
  21. Ahmed, S. M.; Nagaoka, T.; Ogra, K. Anal. Sci., 1998, 14(3): 535
22. [22]
  22. Li, H.; Wang, J.; Chu, Q.; Wang, Z.; Zhang, F.; Wang, S. J. Power Sources, 2009, 190(2): 578
23. [23]
  23. Kotz, R.; Carlen, M. Electrochim. Acta, 2000, 45(15-16): 2483
24. [24]
  24. Belanger, D.; Ren, X.; Davey, J.; Uribe, F.; ttesfeld, S. J. Electrochem. Soc., 2000, 147: 2923
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沈阳化工大学材料科学与工程学院沈阳 110142