Citation:
WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua. Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt[J]. Acta Physico-Chimica Sinica,
;2010, 26(11): 2951-2956.
doi:
10.3866/PKU.WHXB20101107
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A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composite electrode was prepared by constant-potential electropolymerization using AQS as a counter-ion. Cyclic voltammetry (CV), galvanostatic charge-discharge, and electrochemical impedance spectroscopy (EIS) were used to evaluate its capacitance performance. Experimental results show that the AQS dopant results in an improved specific capacitance, increased long-cycle stability, and a wide working potential range compared to that of using ClO-4 as the dopant. The PPy/AQS composite electrode has a specific capacitance of 491 F·g-1 at a CV scan rate of 50 mV·s-1 within a potential range of -0.6 to 0.6 V in 1 mol·L-1 KCl, which is 1.5 times more than that with a PPy/ClO-4 composite electrode. The improvement in capacitance should be attributed to the od redox performance of AQS and the porous submicron/ nanosized structure of the resulting composite film.
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