Citation: ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong. Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 2982-2988. doi: 10.3866/PKU.WHXB20101105 shu

Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components

ZONG Hua ¹ ,
WANG Lei ² ,
FANG Hong-Bo ¹ ,
MAO Lei-Ting ¹ ,
WANG Yu-Hui ¹ ,
ZHANG Lu ^3, ,
ZHAO Sui ³ ,
YU Jia-Yong ³

1.
1. Shengli Engineering and Consulting Co., Ltd., Shengli Oilfield Company of SINOPEC, Dongying 257000, Shandong Province, P. R. China;
2. Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
3. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 27 June 2010
Available Online: 10 September 2010
Fund Project: 国家科技重大专项(2008ZX05011) (2008ZX05011)国家高技术研究发展计划项目(863) (2008AA092801)资助 (863) (2008AA092801)

The effect of hydrophobically modified polyacrylamide (HMPAM) on the dilational rheological properties of interfacial films containing acidic components or asphaltenes in petroleum crude oil was investigated by drop shape analysis method. The influence of surface-active component concentration on the dilational rheological behavior was investigated. Experimental results show that the dilational modulus is approximately 100 mN·m^-1 for a 1750 mg·L^-1 HMPAMsolution. This is due to the formation of an interfacial structure by a hydrophobic interaction among HMPAM molecules. As the interfacial film ages, the acidic component molecules adsorb onto the interface and form mixed complexes with the hydrophobic parts of the HMPAMmolecules. These interactions reduce the dilational modulus by a fast exchange process and the elasticity of the structure improves because of an enhanced hydrophobic interaction among the HMPAMmolecules. For asphaltenes, the nature of the interfacial film is controlled by both the structure of HMPAMand the interfacial complex formed by pure asphaltene molecules because of their relatively larger molecular sizes as well as their strong intermolecular interactions, which leads to a slight decrease in the dilational modulus compared with the pure HMPAMsystem.
- Hydrophobically modified polyacrylamide,
- Crude oil,
- Acidic component,
- Asphaltene,
- Interfacial dilational rheology
1. [1]
  
  1. Taylor, K. C.; Nasr-El-Din, H. A. J. Petrol. Sci. Eng., 1998, 19: 265
2. [2]
  2. Taylor, K. C.; Nasr-El-Din, H. A. Colloids Surf. A, 1998, 108: 49
3. [3]
  3. Shen, P. P.; Yu, J. Y. Fundamental study on extensively enhanced petroleumrecovery. Beijing: PetroleumIndustry Press, 2001: a38- 92; b133-159; c160-193 [沈平平, 俞稼镛.大幅度提高石油采收率的基础研究. 北京: 石油工业出版社, 2001: a38-92; b133-159; c160-193]
4. [4]
  4. Li, M. Y.; Wu, Z. L. Petroleumemulsion. Beijing: Science Press, 2009: 40-68 [李明远,吴肇亮.石油乳状液.北京: 科学出版社, 2009: 40-68]
5. [5]
  5. Liggieri, L.; Ferrari,M.;Mondelli, D.; Ravera, F. Faraday Discuss., 2005, 129: 125
6. [6]
  6. Zhu, Y. Y.; Xu, G. Y. Acta Phys. -Chim. Sin., 2009, 25: 191 [朱艳艳, 徐桂英.物理化学学报, 2009, 25: 191]
7. [7]
  7. Wang, Y. Y.; Zhang, L.; Sun, T. L. Zhao, S.; Yu, J. Y. Chem. J. Chin. Univ., 2003, 24: 2044 [王宜阳, 张路,孙涛垒,赵濉, 俞稼镛. 高等学校化学学报2003, 24: 2044]
8. [8]
  8. Hannisdal, A.; Orr, R.; Sjöblom, J. J. Dispersion Sci. Technol., 2007, 28: 361
9. [9]
  9. Dicharry, C.; Arla, D.; Sinquin, A.; Graciaa, A.; Bouriat, P. J. Colloid Interface Sci., 2006, 297: 785
10. [10]
  10. Aske, N.; Orr, R.; Sjöblom, J. J. Dispersion Sci. Technol., 2002, 23: 809
11. [11]
  11. Freer, E. M.; Radke, C. J. J. Adhes., 2004, 80: 481
12. [12]
  12. Bouriat, P.; ElKerri, N.; Graciaa, A.; Lachaise, J. Langmuir, 2004, 20: 7459
13. [13]
  13. Yang, X.; Verruto, V. J.; Kilpatrick, P. K. Energy Fuels, 2007, 21: 1343
14. [14]
  14. Sun, T. L.; Zhang, L.;Wang, Y. Y.; Zhao, S.; Yu, J. Y. Chem. J. Chin. Univ., 2003, 24: 2243 [孙涛垒,张路, 王宜阳,赵濉, 俞稼镛. 高等学校化学学报, 2003, 24: 2243]
15. [15]
  15. Sun, T. L.; Peng, B.; Xu, Z. M.; Zhang, L.; Zhao, S.; Li, M. Y.; Yu, J. Y. Acta Phys. -Chim. Sin., 2002, 18: 161 [孙涛垒,彭勃,许志明,张路,赵濉,李明远,俞稼镛.物理化学学报, 2002, 18: 161]
16. [16]
  16. Sun, T. L.; Zhang, L.;Wang, Y. Y.; Peng, B.; Zhao, S.; Li, M. Y.; Yu, J. Y. J. Dispersion Sci. Technol., 2003, 24: 699
17. [17]
  17. Sun, T. L.; Zhang, L.;Wang, Y. Y.; Zhao, S.; Peng, B.; Li, M. Y.; Yu, J. Y. J. Colloid Interface Sci., 2002, 255: 241
18. [18]
  18. Zhang, L.; Yan, F.; Wang, X. C.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Dispersion Sci. Technol., 2009, 30: 250
19. [19]
  19. Zhang, L.; Wang, X. C.; Yan, F.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Colloid Polym. Sci., 2008, 286: 1291
20. [20]
  20. Wang, D. X.; Luo, L.; Zhang, L.; Zhao, S.; Wang, L.; ng, Q. T.; Liao, L.; Chu, Y. P.; Yu, J. Y. J. Dispersion Sci. Technol., 2007, 28: 725
21. [21]
  21. Luo, L.; Wang, D. X.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Dispersion Sci. Technol., 2007, 28: 263
22. [22]
  22. Zhang, L.; Wang, X. C.; ng, Q. T.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin., 2007, 23: 1652 [张磊,王晓春,宫清涛,罗澜,张路,赵濉,俞稼镛.物理化学学报, 2007, 23: 1652]
23. [23]
  23. Li, X. L.; Zhang, L.; ng, Q. T.; Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin., 2010, 26: 631 [李秀兰, 张磊,宫清涛, 张路,赵濉,俞稼镛.物理化学学报, 2010, 26: 631]
24. [24]
  24. Lucassen, J.; van den Tempel, M. J. Colloid Interface Sci., 1972, 41: 491
25. [25]
  25. van den Tempel, M.; Lucassen-Reynders, E. H. Adv. Colloid Interface Sci., 1983, 18: 281
26. [26]
  26. Wang, Y. Y.; Dai, Y. H.; Zhang, L.; Luo, L.; Chu, Y. P.; Zhao, S.; Li, M. Y.; Wang, E. J.; Yu, J. Y. Macromolecules, 2004, 37: 2930
27. [27]
  27. Huang, Y. P.; Zhang, L.; Luo, L.; Zhao, S.; Yu, J. Y. J. Phys. Chem. B, 2007, 111: 5640
28. [28]
  28. Verruto, V. J.; Le, R. K.; Kilpatrick, P. K. J. Phys. Chem. B, 2009, 113: 13788
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