Citation: WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng. Preparation and Characterization of One-Dimensional TiO₂ Nanowire Films on a Flexible Stainless Steel Substrate[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3087-3094. doi: 10.3866/PKU.WHXB20101103 shu

Preparation and Characterization of One-Dimensional TiO₂ Nanowire Films on a Flexible Stainless Steel Substrate

1.
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 15 April 2010
Available Online: 8 September 2010
Fund Project: 江苏省自然科学基金(BK2004129) (BK2004129)航空基金(04H5209) (04H5209)南京航空航天大学基本科研业务费专项科研项目助(NS2010153)资助 (NS2010153)

We synthesized a one dimensional (1D) TiO₂ nanowire with a large aspect ratio on non-Ti substrate in NaOH aqueous solution by the hydrothermal treatment of pure titanium films deposited by direct current magnetron sputtering on a flexible stainless steel substrate (50 μm). The samples were characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and photoelectro- chemical methods. Results show that the density and crystallinity of the titanium film as well as the binding strength between the Ti film and the stainless steel substrate increased with an increase in substrate temperature. The optimum hydrothermal temperature for the formation of the 1D TiO₂ nanowire was 130-150 ℃when the concentration of NaOH was kept at 10 mol·L^-1. TiO₂ nanowires with diameters of 10-30 nm and lengths of up to several microns grow in a crosswise manner and form a 3D network structure. Moreover, linear sweep voltammetry and transient photocurrent response curves indicated that the 1D TiO₂ nanowire film electrode had better photoelectrochemical performance than the TiO₂ nanoparticle electrode. This technique provides a new method for the fabrication of 1D TiO₂ nanowire films on different non-Ti heterogeneous substrates.
- Direct currentmagnetron sputtering,
- Titaniumthin film,
- TiO₂,
- Nanowire,
- Hydrothermalmethod
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Preparation and Characterization of One-Dimensional TiO₂ Nanowire Films on a Flexible Stainless Steel Substrate