Citation: YAN ng-Qin, WANG Wei, SUN Zhi-Gang, GUAN Jian-Guo. Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 3120-3126. doi: 10.3866/PKU.WHXB20101027 shu

Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China

Received Date: 7 May 2010
Available Online: 14 September 2010
Fund Project: 国家高技术研究发展计划(863)项目（2006AA032461) (863)项目（2006AA032461)霍英东基金项目(101049)资助 (101049)

Monodispersed superparamagnetic magnetite (Fe₃O₄) sub-microspheres with controlled grain sizes and diameters were obtained by a facile polyol solvothermal method using sodium citrate as an additive. The results show that citric ions, which strongly coordinate with iron atoms on the surface of magnetite, can be effectively adsorbed onto the surface of Fe₃O₄ nanoparticles. Therefore, the growth of the initially formed Fe₃O₄ nanoparticles is restrained and the electrostatic repulsive force changes. Consequently, both the diameter and the magnetic properties of the resultant Fe₃O₄ sub-microspheres can be easily tuned over a relative large range. Simply changing the concentration of citric or ferric ions can change both the diameter of the Fe₃O₄ nanoparticles which construct the resultant sub-microspheres as building blocks and that of the resultant sub-microspheres in a range of 220 -550 nm, resulting in monodispersed superparamagnetic magnetite sub-microspheres.
- Superparamagnetism,
- Monodispersed sub-microspheres,
- Magnetite,
- Diameter control,
- Citrate
1. [1]
  
  1. Jeong, U.; Teng, X. W.;Wang, Y.; Yang, H.; Xia, Y. N. Adv. Mater., 2007, 19: 33
2. [2]
  2. Tartaj, P. Eur. J. Inorg. Chem., 2009: 333
3. [3]
  3. Qiao, R. R.; Yang, C. H.; Gao, M. Y. J. Mater. Chem., 2009, 19: 6274
4. [4]
  4. Ge, J. P.; Hu, Y. X.; Yin, Y. D. Angew. Chem. Int. Edit., 2007, 46: 7428
5. [5]
  5. Xu, X. L.; Friedman, G.; Humfeld, K.; Majetich, S.; Asher, S. Adv. Mater., 2001, 13: 1681
6. [6]
  6. Xu, X. L.; Friedman, G.; Humfeld, K.; Majetich, S.; Asher, S. Chem. Mater., 2002, 14: 1249
7. [7]
  7. Yang, S.; Liu, H. R.; Zhang, Z. C. Langmuir, 2008, 24: 10395
8. [8]
  8. Wen, H. Y.; Gao, G.; Han, Z. R.; Liu, F. Q. Polym. Int., 2008, 57: 584
9. [9]
  9. Sacanna, S.; Philipse, A. P. Langmuir, 2006, 22: 10209
10. [10]
  10. Ge, J. P.; Yin, Y. D. J. Mater. Chem., 2008, 18: 5041
11. [11]
  11. He, P.; Cui, L. L.; Qiang, W. L.; Xu, H.; Gu, H. C. Acta Polym. Sin., 2007: 731 [贺枰, 崔陇兰,强伟丽,徐宏, 古宏晨. 高分子学报, 2007: 731]
12. [12]
  12. Ramírez, L.; Landfester, K. Macromol. Chem. Phys., 2003, 204: 22
13. [13]
  13. Xu, H.; Cui, L. L.; Tong, N. H.; Gu, H. C. J. Am. Chem. Soc., 2006, 128: 15582
14. [14]
  14. Camar , P.; Li, Z. Y.; Xia, Y. N. Soft Matter, 2007, 3: 1215
15. [15]
  15. Cui, L. L.; Xu, H.; He, P.; Sumitomo, K.; Yamaguchi, Y.; Gu, H. C. J. Polym. Sci. A, 2007, 45: 5285
16. [16]
  16. Bai, F.;Wang, D. S.; Huo, Z. Y.; Chen W.; Liu, L. P.; Liang, X.; Chen, C.; Wang, X.; Peng, Q.; Li, Y. D. Angew. Chem. Int. Edit., 2007, 46: 6650
17. [17]
  17. Ge, J. P.; Hu, Y. X.; Biasini, M.; Beyermann, W.; Yin, Y. D. Angew. Chem. Int. Edit., 2007, 46: 4342
18. [18]
  18. Wen, Y. H.; Cheng, C. M.; Gu, H. C. J. Funct. Mater., 2009, 40: 926 [文颖慧,程昌明,古宏晨. 功能材料, 2009, 40: 926]
19. [19]
  19. Liu, X. W.; Hu, Q. Y.; Fang, Z.;Wu, Q.; Xie, Q. B. Langmuir, 2009, 25: 7244
20. [20]
  20. Deng, H.; Li, X. L.; Peng, Q.; Wang, X.; Chen, J. P.; Li, Y. D. Angew. Chem. Int. Edit., 2005, 44: 2782
21. [21]
  21. Zhang, W.; Shen, H.; Xie, M. Q.; Zhu, Y. J.; Hu. S. L.; Deng, Y. Y.; Li, X. J. J. Sun Yatsen Univ.-Nat. Sci. Edit., 2008, 47(2): 58 [张伟,沈辉, 谢民强, 朱燕娟,胡孙林,邓颖宇, 黎宪静.中山大学学报: 自然科学版, 2008, 47(2): 58]
22. [22]
  22. He, T.; Chen, D. R.; Jiao, X. L. Chem. Mater., 2004, 16: 737
23. [23]
  23. Hou, Y. L.; Kondoh, H.; Ohta, T. Chem. Mater., 2006, 17: 3994
24. [24]
  24. Han, D. H.; Wang, J. P.; Feng, Y. B. J. Appl. Phys., 1994, 76: 6591
1. [1]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
2. [2]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
3. [3]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
4. [4]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
5. [5]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
6. [6]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
7. [7]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
8. [8]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
9. [9]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
10. [10]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
11. [11]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
12. [12]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
13. [13]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
14. [14]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332
15. [15]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
16. [16]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
17. [17]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
18. [18]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
19. [19]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
20. [20]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021

Get Citation

PDF

XML

Metrics

PDF Downloads(1645)
Abstract views(2531)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142