Citation: WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling. Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement[J]. Acta Physico-Chimica Sinica, ;2010, 26(11): 2957-2961. doi: 10.3866/PKU.WHXB20101026 shu

Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement

1.
1. State Key Laboratory of Power Transmission Equipment and System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China;
2. School of Material Science and Engineering, Chongqing University, Chongqing 400044, P. R. China

Received Date: 5 May 2010
Available Online: 14 September 2010
Fund Project: 国家自然科学基金(20806096) (20806096)重庆大学211 工程三期创新人才培养建设计划研究生开放实验室支持项目(S-09013)资助 (S-09013)

APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) -displacement (Pt) (SD) method on a conductive glass (FTO) substrate (SD-Pt/FTO). Morphological characterization revealed that the dispersion of Pt particles on the SD-Pt/FTO electrode was significantly improved in comparison with the PY-Pt/FTO electrode prepared by the pyrolysis of Pt salts (PY). Optical current-voltage curves showed that the photoelectric conversion efficiency of DSSC with a SD-Pt/FTO counter electrode increased by 16.5% relative to that with a PY-Pt/ FTO counter electrode. The improvement of DSSC performance with the SD-Pt/FTO electrode is due to its lower electric resistance, and od catalysis resulting from the improved dispersion of Pt particles in the SD process compared with the PY process.
- Dye-sensitized solar cell,
- Electrode,
- Sputtering,
- Pt
1. [1]
  
  1. O'Regan, B.; Grätzel, M. Nature, 1991, 353: 737
2. [2]
  2. Grätzel, M. Nature, 2001, 414: 338
3. [3]
  3. Yang, S. M.; Kou, H. Z.; Wang, L.; Wang, H. J.; Fu, W. H. Acta Phys. -Chim. Sin., 2009, 25: 1219
4. [4]
  [杨术明,寇慧芝,汪玲,王红军,付文红.物理化学学报, 2009, 25: 1219]
5. [5]
  4. Papageorgiou, N. Coordination. Chem. Rev., 2004, 248: 1421
6. [6]
  5. Takurou, N.; Murakami, S. I.; Wang, Q.; Nazeeruddin, M. K.; Bessho, T.; Cesar, I.; Liska, P.; Robin, H. B.; Pascal, C.; P佴ter, P.; Grätzel, M. J. Electrochem. Soc., 2006, 153: A2255
7. [7]
  6. Imoto, K.; Takahashi, K.; Yamaguchi, T.; Komura, T.; Nakamura, J. I.; Murata, K. Sol. Energy Mater. Sol. Cells, 2003, 79: 459
8. [8]
  7. Hino, T.; Ogawa, Y.; Kuramoto, N. Carbon, 2006, 44: 880
9. [9]
  8. Suzuki, K.; Yamaguchi, M.; Kumagai, M.; Yanagida, S. Chem. Lett., 2003, 32: 28
10. [10]
  9. Saito, Y.; Kitamura, T.; Wada, Y.; Yanagida, S. Chem. Lett., 2002, 31: 1060
11. [11]
  10. Saito, Y.; Kubo, W.; Kitamura, T.; Wada, Y.; Yanagida. S. J. Photochem. Photobiol. A-Chem., 2004, 164: 153
12. [12]
  11. Lee, K. M.; Chen, P. Y.; Hsu, C. Y.; Huang, J. H.; Ho, W. H.; Chen, H. C.; Ho, K. C. J. Power Sources, 2009, 188: 313
13. [13]
  12. Papageorgiou, N. Coordination. Chem. Rev., 2004, 248: 1421
14. [14]
  13. Li, P. J.;Wu, J. H.; Lin, J. M.; Huang, M. L.; Lan, Z.; Li, Q. H. Electrochim. Acta, 2008, 53: 4161
15. [15]
  14. Wang, G. Q.; Lin, R. F.; Lin, Y.; Li, X. P.; Zhou, X. W.; Xiao. X. R. Electrochim. Acta, 2005, 50: 5546
16. [16]
  15. Kim, S. S.; Nah, Y. C.; Noh, Y. Y.; Jo, J.; Kim, D. Y. Electrochim. Acta, 2006, 51: 3814
17. [17]
  16. Yoon, C. H.; Vittal, R.; Lee, J.; Chae, W. S.; Kim, K. J. Electrochim. Acta, 2008, 53: 2890
18. [18]
  17. Chena, C. M.; Chena, C. H.; Weib, T. C. Electrochim. Acta, 2009, 55: 1687
19. [19]
  18. Dong, Y. S.; Zhao, W. J.; Li, Y. R.; Li, G. Y. Appl. Surf. Sci., 2006, 252: 5057
20. [20]
  19. Tang, Y. X.; Tao, J.; Zhang, Y. Y.; Wu, T.; Tao, H. J.; Bao, Z. G. Acta Phys. -Chim. Sin., 2008, 24: 2191
21. [21]
  [汤育欣, 陶杰,张焱焱, 吴涛,陶海军,包祖国. 物理化学学报, 2008, 24: 2191]
22. [22]
  20. Liu, Y. X.; Zhao, L. Vacuum, 2003, 4: 16
23. [23]
  [刘翔宇,赵来. 真空, 2003, 4: 16]
24. [24]
  21. Choi, S. M.; Kim, J. H.; Jung, J. Y.; Yoon, E. Y.; Kim, W. B. Electrochim. Acta, 2008, 53: 5804
25. [25]
  22. Paoletti, C.; Cemmia, A.; Giorgi, L.; Giorgi, R.; Pilloni. L.; Serra, E.; Pasquali, M. J. Power Sources, 2008, 183: 84
1. [1]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
2. [2]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
3. [3]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
4. [4]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
7. [7]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
8. [8]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
9. [9]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
10. [10]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
11. [11]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
12. [12]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
13. [13]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
14. [14]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
15. [15]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
16. [16]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
17. [17]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
18. [18]
  Simin Fang , Hong Wu , Wei Liu , Wei Wei , Hongyan Feng , Wan Li . Construction and Application of Teaching Resources for Inorganic and Analytical Chemistry Experimental Course in the Context of Digital Empowerment. University Chemistry, 2024, 39(10): 156-163. doi: 10.3866/PKU.DXHX202402053
19. [19]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
20. [20]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069

Get Citation

PDF

XML

Metrics

PDF Downloads(1592)
Abstract views(3961)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142