Citation: ZHAO Jian-Xi. Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2589-2596. doi: 10.3866/PKU.WHXB20101019 shu

Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters

  • Received Date: 7 June 2010
    Available Online: 27 September 2010

    Fund Project: 国家自然科学基金(20673021, 20873024) 资助项目 (20673021, 20873024)

  • Conductivity is important in the investigation of the micellization behavior of ionic surfactants in an aqueous solution. We review this sensitive technique and discuss methods to determine the critical micelle concentration (cmc) and the degree of dissociation of the micelle( α) in detail. We also investigatea special situation analysis for conductivity curves and premicellar behavior. This method is useful for the investigation of surfactant systems in which strong intermolecular interactions occur.

  • 加载中
    1. [1]

      1. Zana, R. Surfactant solutions, newmethods of investigation. Trans. Tang, S. T.; Cheng, S. J. Beijing: PetroleumIndustry Press, 1992: 221-270 [Zana, R. 表面活性剂溶液研究新方法. 唐善驮,程绍 进, 译.北京: 石油工业出版社, 1992: 221-270]

    2. [2]

      2. Zana, R. J. Colloid Interface Sci., 2002, 248: 203

    3. [3]

      3. Manabe, M. The differential conductivity technique and its application to mixed surfactant solutions for determining ionic constants//Abe, M.; Scamehorn, J. F. Mixed surfactant systems. 2nd ed. NewYork: Marcel Dekker, 2005: Chapter 3

    4. [4]

      4. Rosen, M. J.; Surfactants and interfacial phenomena. 2nd ed. New York: John Wiley&Sons Inc., 1988

    5. [5]

      5. Zana, R. Langmuir, 1996, 12: 1208

    6. [6]

      6. Zheng, Y. Y.; Zhao, J. X.; Zheng, O.; You, Y.; Qiu, Y. Acta Chimica Sinica, 2001, 59(5): 690 [郑玉婴,赵剑曦,郑欧, 游毅,邱羽. 化学学报, 2001, 59(5): 690]

    7. [7]

      7. Bai, G.;Wang, J.;Wang, Y.; Yan, H. J. Phys. Chem. B, 2002, 106: 6614

    8. [8]

      8. Wang, X.; Wang, J.; Wang, Y.; Ye, J.; Yan, H.; Thomas, R. K. J. Phys. Chem. B, 2003, 107: 11428

    9. [9]

      9. Rubingh, D. N. Mixed micelle solutions//Mittal, K. L. Solution chemistry of surfactants. Vol.1. NewYork: Plenum, 1979: 337-354

    10. [10]

      10. Rosen, M. J.; Hua, X. Y. J. Colloid Interface Sci., 1982, 86: 164

    11. [11]

      11. Hua, X. Y.; Rosen, M. J. J. Colloid Interface Sci., 1982, 90: 212

    12. [12]

      12. Manabe, M.; Kawamura, H.; Yamashita, A.; Tokunaga, S. J. Colloid Interface Sci., 1987, 115: 147

    13. [13]

      13. Sugihara, G.; Era, Y.; Funatsu, M.; Kunitake, T.; Lee, S.; Sasaki, Y. J. Colloid Interface Sci., 1997, 187: 435

    14. [14]

      14. Fujiwara, M.; Okano, T.; Nakashima, T. H.; Nakamura, A. A.; Sugihara, G. Colloid Polym. Sci., 1997, 275: 474

    15. [15]

      15. Sugihara, G.; Nakamura, A. A.; Nakashima, T. H.; Araki, Y. I.; Okano, T.; Fujiwara, M. Colloid Polym. Sci., 1997, 275: 790

    16. [16]

      16. Ruiz, C. C. Colloid Polym. Sci., 1999, 277: 701

    17. [17]

      17. Carcía-Mateos, I.; Velázquez, M. M.; Rodríguez, L. J. Langmuir, 1990, 6: 1078

    18. [18]

      18. Zhao, J.; Christian, S. D.; Fung, B. M. J. Phys. Chem. B, 1998, 102: 7613

    19. [19]

      19. Pérez-Rodríguez, M.; Prieto, G.; Rega, C.; Varela, L. M.; Sarmiento, F.; Mosquera, V. Langmuir, 1998, 14: 4422

    20. [20]

      20. Phillips, J. N. Trans. Faraday Soc., 1955, 51: 561

    21. [21]

      21. Williams, R. J.; Phillips, J. N.; Mysels, K. J. Trans. Faraday Soc., 1955, 51: 728

    22. [22]

      22. Carpena, P.; Aguiar, J.; Bernaola-Galván, P.; Ruiz, C. C. Langmuir, 2002, 18: 6054

    23. [23]

      23. Hirata, H.; Hattori, N.; Ishida, M.; Okabayashi, H.; Frusaka, M.; Zana, R. J. Phys. Chem., 1995, 99: 17778

    24. [24]

      24. Quagliotto, P.; Viscardi, G.; Barolo, C.; D'Angelo, D.; Barni, E.; Compari, C.; Duce, E.; Fisicaro, E. J. Org. Chem., 2005, 70: 9857

    25. [25]

      25. Pei, X. M.; Zhao, J. X.; Jiang, R. Colloid Polym. Sci., 2010, 288: 711

    26. [26]

      26. Quagliotto, P.; Barbero, N.; Barolo, C.; Costabello, K.; Marchese, L.; Coluccia, S.; Kalyanasundaram, K.; Viscardi, G. Dyes Pigments, 2009, 82: 124

    27. [27]

      27. Treiner, C.; Makayssi, A. Langmuir, 1992, 8: 794

    28. [28]

      28. Graciani, M. D.; Rodríguez, A.; Moyá, M. L. J. Colloid Interface Sci., 2008, 328: 324

    29. [29]

      29. Evans, H. C. J. Chem. Soc., 1956, 117: 579

    30. [30]

      30. Zhao, J. X.; Zheng, O. Chemistry, 2002, 65: w04 [赵剑曦, 郑欧.化学通报, 2002, 65: w046]

    31. [31]

      31. Ge, X. Y.; Guo, R.; Yan, P. Q. J. Normal Univ. Yangzhou, 1991, 11(4): 34 [葛秀英,郭荣, 严鹏权, 扬州师院学报, 1991, 11 (4): 34]

    32. [32]

      32. Yan, P. Q.; Guo, R.; Shen, M.; Li,W.; Chen, H. Y. Acta Phys.- Chim. Sin., 1994, 10: 175 [严鹏权,郭荣,沈明, 李伟,陈 海燕.物理化学学报, 1994, 10: 175]

    33. [33]

      33. Corrin, M. L.; Harkins, W. D. J. Am. Chem. Soc., 1947, 69: 683

    34. [34]

      34. Zhao, G. X.; Zhu, B. Y. Principles of surfactant action. Beijing: China Light Industry Press, 2003: 264 [赵国玺,朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003: 264]

    35. [35]

      35. Zana, R. J. Colloid Interface Sci., 2002, 246: 182

    36. [36]

      36. Tsubone, K.; Arakawa, Y.; Rosen, M. J. J. Colloid Interface Sci., 2003, 262: 516

    37. [37]

      37. Jiang, Y. C.; Wu, S. K. Acta Chim. Sin., 1990, 48: 447 [姜永才, 吴世康.化学学报, 1990, 48: 447]

    38. [38]

      38. Jiang, Y. C.; Shen, S. L.; Wu, S. K. Acta Chim. Sin., 1991, 49: 32 [姜永才,沈世龙, 吴世康. 化学学报, 1991, 49: 32]

    39. [39]

      39. Jiang, Y. C.; Ye, J. P.; Wu, S. K. Acta Chim. Sin., 1992, 50: 1080 [姜永才,叶建平, 吴世康. 化学学报, 1992, 50: 1080]

    40. [40]

      40. Jiang, Y. C.; Wu, S. K. Acta Phys.-Chim. Sin., 1994, 10: 381 [姜永才,吴世康. 物理化学学报, 1994, 10: 381]

    41. [41]

      41. Hadgiivanova, R.; Diamant, H. J. Phys. Chem. B, 2007, 111: 8854

    42. [42]

      42. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1991, 113: 1451

    43. [43]

      43. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1993, 115: 10083

    44. [44]

      44. Song, L.; Rosen, M. J. Langmuir, 1996, 12: 1149

    45. [45]

      45. Rosen, M. J.; Mathias, J. H.; Davenport, L. Langmuir, 1999, 15: 7340

    46. [46]

      46. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2001, 17: 6148

    47. [47]

      47. Pinazo, A.; Wen, X.; Perez, L.; Infante, M. R.; Franses, E. I. Langmuir, 1999, 15: 3134

    48. [48]

      48. Yoshimura, T.; Nyuta, K.; Esumi, K. Langmuir, 2005, 21: 2682

    49. [49]

      49. Laschewsky, A.; Wattebled, L.; Arotcaréna, M.; Habib-Jiwan, J. L.; Rakotoaly, R. H. Langmuir, 2005, 21: 7170

    50. [50]

      50. Jiang, Y.; Chen, H.; Cui, X. H.; Mao, S. Z.; Liu, M. L.; Luo, P. Y.; Du, Y. R. Langmuir, 2008, 24: 3118

    51. [51]

      51. Barbero, N.; Quagliotto, P.; Barolo, C.; Artuso, E.; Buscaino, R.; Viscardi, G. Dyes Pigments, 2009, 83: 396

    52. [52]

      52. Sakai, T.; Kaneko, Y.; Tsujii, K. Langmuir, 2006, 22: 2039

    53. [53]

      53. Mukerjee, P.; Yang, A. Y. S. J. Phys. Chem., 1976, 80: 1388

    54. [54]

      54. Manabe, M.; Tokunaga, A.; Kawamura, H.; Katsuura, H.; Shiomi, M.; Hiramatsu, K. Colloid Polym. Sci., 2002, 280: 929

    55. [55]

      55. Manabe, M.; Funamoto, M.; Kohgami, F.; Kawamura, H.; Katsuura, H. Colloid Polym. Sci., 2003, 281: 239

    56. [56]

      56. Manabe, M.; Kaneko, M.; Miura, T.; Akiyama, C.; Kawamura, H.; Katsuura, H.; Shiomi, M. Bull. Chem. Soc. Jpn., 2002, 75: 1967

    57. [57]

      57. Zana, R. Langmuir, 2002, 18: 7759

    58. [58]

      58. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2002, 18: 7761


  • 加载中
    1. [1]

      Jiayu Tang Jichuan Pang Shaohua Xiao Xinhua Xu Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021

    2. [2]

      Ru SONGBiao WANGChunling LUBingbing NIUDongchao QIU . Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397

    3. [3]

      Ran HUOZhaohui ZHANGXi SULong CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195

    4. [4]

      Yukai Jiang Yihan Wang Yunkai Zhang Yunping Wei Ying Ma Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033

    5. [5]

      Congying Lu Fei Zhong Zhenyu Yuan Shuaibing Li Jiayao Li Jiewen Liu Xianyang Hu Liqun Sun Rui Li Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097

    6. [6]

      Xinghai Li Zhisen Wu Lijing Zhang Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041

    7. [7]

      Hong Wu Yuxi Wang Hongyan Feng Xiaokui Wang Bangkun Jin Xuan Lei Qianghua Wu Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141

    8. [8]

      Juntao Yan Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024

    9. [9]

      Xinting XIONGZhiqiang XIONGPanlei XIAOXuliang NIEXiuying SONGXiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    10. [10]

      Asif Hassan Raza Shumail Farhan Zhixian Yu Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020

    11. [11]

      Jianbao Mei Bei Li Shu Zhang Dongdong Xiao Pu Hu Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5-xMn0.5V1.5-xZrx(PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023

    12. [12]

      Aoyu Huang Jun Xu Yu Huang Gui Chu Mao Wang Lili Wang Yongqi Sun Zhen Jiang Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007

    13. [13]

      Yi YANGShuang WANGWendan WANGLimiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

    14. [14]

      Kexin Dong Chuqi Shen Ruyu Yan Yanping Liu Chunqiang Zhuang Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

    15. [15]

      Lina Guo Ruizhe Li Chuang Sun Xiaoli Luo Yiqiu Shi Hong Yuan Shuxin Ouyang Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002

    16. [16]

      Hailian Tang Siyuan Chen Qiaoyun Liu Guoyi Bai Botao Qiao Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

    17. [17]

      Quanliang Chen Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133

    18. [18]

      Yuyao Wang Zhitao Cao Zeyu Du Xinxin Cao Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

    19. [19]

      Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020

    20. [20]

      Guoze Yan Bin Zuo Shaoqing Liu Tao Wang Ruoyu Wang Jinyang Bao Zhongzhou Zhao Feifei Chu Zhengtong Li Yusuke Yamauchi Saad Melhi Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006

Metrics
  • PDF Downloads(2248)
  • Abstract views(3353)
  • HTML views(8)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return