Citation: ZHAO Jian-Xi. Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2589-2596. doi: 10.3866/PKU.WHXB20101019 shu

Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters

ZHAO Jian-Xi

1.
Institute of Colloid Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 7 June 2010
Available Online: 27 September 2010
Fund Project: 国家自然科学基金(20673021, 20873024) 资助项目 (20673021, 20873024)

Conductivity is important in the investigation of the micellization behavior of ionic surfactants in an aqueous solution. We review this sensitive technique and discuss methods to determine the critical micelle concentration (cmc) and the degree of dissociation of the micelle( α) in detail. We also investigatea special situation analysis for conductivity curves and premicellar behavior. This method is useful for the investigation of surfactant systems in which strong intermolecular interactions occur.
- Ionic surfactant,
- Conductivity,
- Characteristic parameters
1. [1]
  
  1. Zana, R. Surfactant solutions, newmethods of investigation. Trans. Tang, S. T.; Cheng, S. J. Beijing: PetroleumIndustry Press, 1992: 221-270 [Zana, R. 表面活性剂溶液研究新方法. 唐善驮,程绍进, 译.北京: 石油工业出版社, 1992: 221-270]
2. [2]
  2. Zana, R. J. Colloid Interface Sci., 2002, 248: 203
3. [3]
  3. Manabe, M. The differential conductivity technique and its application to mixed surfactant solutions for determining ionic constants//Abe, M.; Scamehorn, J. F. Mixed surfactant systems. 2nd ed. NewYork: Marcel Dekker, 2005: Chapter 3
4. [4]
  4. Rosen, M. J.; Surfactants and interfacial phenomena. 2nd ed. New York: John Wiley&Sons Inc., 1988
5. [5]
  5. Zana, R. Langmuir, 1996, 12: 1208
6. [6]
  6. Zheng, Y. Y.; Zhao, J. X.; Zheng, O.; You, Y.; Qiu, Y. Acta Chimica Sinica, 2001, 59(5): 690 [郑玉婴,赵剑曦,郑欧, 游毅,邱羽. 化学学报, 2001, 59(5): 690]
7. [7]
  7. Bai, G.;Wang, J.;Wang, Y.; Yan, H. J. Phys. Chem. B, 2002, 106: 6614
8. [8]
  8. Wang, X.; Wang, J.; Wang, Y.; Ye, J.; Yan, H.; Thomas, R. K. J. Phys. Chem. B, 2003, 107: 11428
9. [9]
  9. Rubingh, D. N. Mixed micelle solutions//Mittal, K. L. Solution chemistry of surfactants. Vol.1. NewYork: Plenum, 1979: 337-354
10. [10]
  10. Rosen, M. J.; Hua, X. Y. J. Colloid Interface Sci., 1982, 86: 164
11. [11]
  11. Hua, X. Y.; Rosen, M. J. J. Colloid Interface Sci., 1982, 90: 212
12. [12]
  12. Manabe, M.; Kawamura, H.; Yamashita, A.; Tokunaga, S. J. Colloid Interface Sci., 1987, 115: 147
13. [13]
  13. Sugihara, G.; Era, Y.; Funatsu, M.; Kunitake, T.; Lee, S.; Sasaki, Y. J. Colloid Interface Sci., 1997, 187: 435
14. [14]
  14. Fujiwara, M.; Okano, T.; Nakashima, T. H.; Nakamura, A. A.; Sugihara, G. Colloid Polym. Sci., 1997, 275: 474
15. [15]
  15. Sugihara, G.; Nakamura, A. A.; Nakashima, T. H.; Araki, Y. I.; Okano, T.; Fujiwara, M. Colloid Polym. Sci., 1997, 275: 790
16. [16]
  16. Ruiz, C. C. Colloid Polym. Sci., 1999, 277: 701
17. [17]
  17. Carcía-Mateos, I.; Velázquez, M. M.; Rodríguez, L. J. Langmuir, 1990, 6: 1078
18. [18]
  18. Zhao, J.; Christian, S. D.; Fung, B. M. J. Phys. Chem. B, 1998, 102: 7613
19. [19]
  19. Pérez-Rodríguez, M.; Prieto, G.; Rega, C.; Varela, L. M.; Sarmiento, F.; Mosquera, V. Langmuir, 1998, 14: 4422
20. [20]
  20. Phillips, J. N. Trans. Faraday Soc., 1955, 51: 561
21. [21]
  21. Williams, R. J.; Phillips, J. N.; Mysels, K. J. Trans. Faraday Soc., 1955, 51: 728
22. [22]
  22. Carpena, P.; Aguiar, J.; Bernaola-Galván, P.; Ruiz, C. C. Langmuir, 2002, 18: 6054
23. [23]
  23. Hirata, H.; Hattori, N.; Ishida, M.; Okabayashi, H.; Frusaka, M.; Zana, R. J. Phys. Chem., 1995, 99: 17778
24. [24]
  24. Quagliotto, P.; Viscardi, G.; Barolo, C.; D'Angelo, D.; Barni, E.; Compari, C.; Duce, E.; Fisicaro, E. J. Org. Chem., 2005, 70: 9857
25. [25]
  25. Pei, X. M.; Zhao, J. X.; Jiang, R. Colloid Polym. Sci., 2010, 288: 711
26. [26]
  26. Quagliotto, P.; Barbero, N.; Barolo, C.; Costabello, K.; Marchese, L.; Coluccia, S.; Kalyanasundaram, K.; Viscardi, G. Dyes Pigments, 2009, 82: 124
27. [27]
  27. Treiner, C.; Makayssi, A. Langmuir, 1992, 8: 794
28. [28]
  28. Graciani, M. D.; Rodríguez, A.; Moyá, M. L. J. Colloid Interface Sci., 2008, 328: 324
29. [29]
  29. Evans, H. C. J. Chem. Soc., 1956, 117: 579
30. [30]
  30. Zhao, J. X.; Zheng, O. Chemistry, 2002, 65: w04 [赵剑曦, 郑欧.化学通报, 2002, 65: w046]
31. [31]
  31. Ge, X. Y.; Guo, R.; Yan, P. Q. J. Normal Univ. Yangzhou, 1991, 11(4): 34 [葛秀英,郭荣, 严鹏权, 扬州师院学报, 1991, 11 (4): 34]
32. [32]
  32. Yan, P. Q.; Guo, R.; Shen, M.; Li,W.; Chen, H. Y. Acta Phys.- Chim. Sin., 1994, 10: 175 [严鹏权,郭荣,沈明, 李伟,陈海燕.物理化学学报, 1994, 10: 175]
33. [33]
  33. Corrin, M. L.; Harkins, W. D. J. Am. Chem. Soc., 1947, 69: 683
34. [34]
  34. Zhao, G. X.; Zhu, B. Y. Principles of surfactant action. Beijing: China Light Industry Press, 2003: 264 [赵国玺,朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003: 264]
35. [35]
  35. Zana, R. J. Colloid Interface Sci., 2002, 246: 182
36. [36]
  36. Tsubone, K.; Arakawa, Y.; Rosen, M. J. J. Colloid Interface Sci., 2003, 262: 516
37. [37]
  37. Jiang, Y. C.; Wu, S. K. Acta Chim. Sin., 1990, 48: 447 [姜永才, 吴世康.化学学报, 1990, 48: 447]
38. [38]
  38. Jiang, Y. C.; Shen, S. L.; Wu, S. K. Acta Chim. Sin., 1991, 49: 32 [姜永才,沈世龙, 吴世康. 化学学报, 1991, 49: 32]
39. [39]
  39. Jiang, Y. C.; Ye, J. P.; Wu, S. K. Acta Chim. Sin., 1992, 50: 1080 [姜永才,叶建平, 吴世康. 化学学报, 1992, 50: 1080]
40. [40]
  40. Jiang, Y. C.; Wu, S. K. Acta Phys.-Chim. Sin., 1994, 10: 381 [姜永才,吴世康. 物理化学学报, 1994, 10: 381]
41. [41]
  41. Hadgiivanova, R.; Diamant, H. J. Phys. Chem. B, 2007, 111: 8854
42. [42]
  42. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1991, 113: 1451
43. [43]
  43. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1993, 115: 10083
44. [44]
  44. Song, L.; Rosen, M. J. Langmuir, 1996, 12: 1149
45. [45]
  45. Rosen, M. J.; Mathias, J. H.; Davenport, L. Langmuir, 1999, 15: 7340
46. [46]
  46. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2001, 17: 6148
47. [47]
  47. Pinazo, A.; Wen, X.; Perez, L.; Infante, M. R.; Franses, E. I. Langmuir, 1999, 15: 3134
48. [48]
  48. Yoshimura, T.; Nyuta, K.; Esumi, K. Langmuir, 2005, 21: 2682
49. [49]
  49. Laschewsky, A.; Wattebled, L.; Arotcaréna, M.; Habib-Jiwan, J. L.; Rakotoaly, R. H. Langmuir, 2005, 21: 7170
50. [50]
  50. Jiang, Y.; Chen, H.; Cui, X. H.; Mao, S. Z.; Liu, M. L.; Luo, P. Y.; Du, Y. R. Langmuir, 2008, 24: 3118
51. [51]
  51. Barbero, N.; Quagliotto, P.; Barolo, C.; Artuso, E.; Buscaino, R.; Viscardi, G. Dyes Pigments, 2009, 83: 396
52. [52]
  52. Sakai, T.; Kaneko, Y.; Tsujii, K. Langmuir, 2006, 22: 2039
53. [53]
  53. Mukerjee, P.; Yang, A. Y. S. J. Phys. Chem., 1976, 80: 1388
54. [54]
  54. Manabe, M.; Tokunaga, A.; Kawamura, H.; Katsuura, H.; Shiomi, M.; Hiramatsu, K. Colloid Polym. Sci., 2002, 280: 929
55. [55]
  55. Manabe, M.; Funamoto, M.; Kohgami, F.; Kawamura, H.; Katsuura, H. Colloid Polym. Sci., 2003, 281: 239
56. [56]
  56. Manabe, M.; Kaneko, M.; Miura, T.; Akiyama, C.; Kawamura, H.; Katsuura, H.; Shiomi, M. Bull. Chem. Soc. Jpn., 2002, 75: 1967
57. [57]
  57. Zana, R. Langmuir, 2002, 18: 7759
58. [58]
  58. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2002, 18: 7761
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
3. [3]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
6. [6]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
7. [7]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
8. [8]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
9. [9]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
10. [10]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
11. [11]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
12. [12]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
13. [13]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
14. [14]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
15. [15]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
16. [16]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073
17. [17]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
18. [18]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
19. [19]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
20. [20]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034

Get Citation

PDF

XML

Metrics

PDF Downloads(2248)
Abstract views(3301)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142