Citation:
ZHANG Xiao-Fei, SHAO Zheng-Feng, MAO Guo-Qiang, HE De-Min, ZHANG Qiu-Min, LIANG Chang-Hai. Naphthalene Hydrogenation Activity over Pd, Pt and Pd-Pt Catalysts and Their Sulfur Tolerance[J]. Acta Physico-Chimica Sinica,
;2010, 26(10): 2691-2698.
doi:
10.3866/PKU.WHXB20101006
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Monometallic Pd and Pt as well as bimetallic Pd:Pt catalysts (Pd1Pt1, Pd1Pt4, and Pd4Pt1) with Pd/Pt molar ratios of 1:1, 1:4, and 4:1 supported on SiO2-Al2O3 were prepared by incipient-wetness impregnation and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), CO chemisorption, and X-ray photoelectron spectroscopy (XPS). Their catalytic activities toward naphthalene hydrogenation and the sulfur tolerance of these catalysts were investigated. We found that naphthalene conversion, selectivity toward decalin, and the trans-/cis-decalin yieldratio on Pd4Pt1 were 98.2%,93.6%,and 7.8,respectively,which are higher than those on Pd(97.5%,59.1%, 4.3) and Pt (96.8%, 39.9%, 2.9). The rate of naphthalene hydrogenation on the three catalysts increased according to: vPd4Pt1>vPd>vPt. In the presence of dibenzothiophene (DBT), the naphthalene conversion and selectivity toward decalin for Pd4Pt1 were still the highest. The trans-/cis-decalin ratio was not affected on the Pt catalyst, but it did decrease slightly on Pd4Pt1 and it decreased observably on the Pd catalyst. The Pd4Pt1 catalyst also presented the highest naphthalene conversion and selectivity toward decalin among the three bimetallic catalysts studied in the presence and absence of DBT.
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