Citation: LI Jian-Ling, GAO Fei, ZHANG Ya-Kun, HE Li-Zhi, HAN Gui-Mei, WANG Xin-Dong. Electropolymerization of Nickel Complexes with Schiff Bases: Effect of Sweep Rate on Anodic Polymerization[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2647-2652. doi: 10.3866/PKU.WHXB20100940 shu

Electropolymerization of Nickel Complexes with Schiff Bases: Effect of Sweep Rate on Anodic Polymerization

1.
Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, P. R. China

Received Date: 4 May 2010
Available Online: 27 September 2010
Fund Project: 北京市自然科学基金(2093039) (2093039)

Anodic electrochemical polymerization of N,N'-ethylenbis (salicylideneaminato) nickel(II) ([Ni(salen)]) in tetrabutylammonium perchlorate (TBAP)/acetonitrile (AN) was investigated by the linear sweep potential method. The sweep rate ranged from 5 to 150 mV·s^-1. The effect of sweep rate on the growth of poly[Ni(salen)] was studied by Coulomb analysis. The morphologies of poly[Ni(salen)] were characterized by field emission scanning electron microscopy (FESEM). The relationship between the growth rate of poly[Ni(salen)] (dΓ/dm) and the sweep rate (v) fits the exponential degradation equation. The content of the redox center for poly[Ni(salen)], grown at sweep rate of 20 mV·s^-1, reaches a maximum and then decreases as the sweep rate increases because monomer diffusion restricts the growth of poly[Ni(salen)]. We studied the effect of polymerization sweep rate on the kinetics of the as-grown poly[Ni (salen)] by cyclic voltammetry. The charge diffusion coefficient (D) of poly[Ni(salen)] grown at a sweep rate of 20 mV·s^-1 was found to be the highest.
- Electropolymerization,
- Schiff base,
- Transition metal complex,
- Doping level,
- Charge diffusioncoefficient
1. [1]
  
  1. Dahm, C. E.; Peters, D. G. Anal. Chem., 1994, 66: 3117
2. [2]
  2. Abdirisak, A. I.; Armando, G.; Elio, V. Electrochimica Acta, 1997, 42: 2065
3. [3]
  3. Giulio, B.; Alessandra, C.; Alesandro, S.; Giorgio, S. Green Chem., 2009, 11: 1517
4. [4]
  4. Samiran, B.; Kwang, E. J.; Song, Y. J.; Wha, S. A. New J. Chem., 2010, 34: 156
5. [5]
  5. Zhou, X.; Sheare, J.; Rokita, S. E. J. Am. Chem. Soc., 2000, 122: 9046
6. [6]
  6. Khairul, I. A.; James, D. G.; Getachew, A. W.; Sahba, K.; Subhrangsu, S. M. Org. Biomol. Chem., 2009, 7: 926
7. [7]
  7. Henderson, M. J.; Hillman, A. R.; Vieil, E. J. Phys. Chem. B, 1999, 103: 8899
8. [8]
  8. Martins, M.; Freire, C.; Hillman, A. R. Chem. Commun., 2003, (3): 434
9. [9]
  9. Tedim, J.; Carneiro, A.; Bessada, R.; Patricio, S.; Magalhaes, A. L.; Freire, C.; Gurman, S. J.; Hillman, A. R. J. Electroanal. Chem., 2007, 610: 46
10. [10]
  10. Dahm, C. E.; Peters, D. G. J. Electroanal. Chem., 1996, 406: 119
11. [11]
  11. Dahm, C. E.; Peters, D. G.; Simonet, J. J. Electroanal. Chem., 1996, 410: 163
12. [12]
  12. ldsby, K. A.; Blaho, J. K.; Hoferkamp, L. A. Polyhedron, 1989,8: 113
13. [13]
  13. ldsby, K. A.; Hoferkamp, L. A. Chem. Mater., 1989, 1: 348
14. [14]
  14. Audebert, P.; Hapiot, P.; Capdevielle, P.; Maumy, M. J. Electroanal. Chem., 1992, 338: 269
15. [15]
  15. Boas, M. V.; Freire, C.; Castro, B. D.; Christensen, P. A.; Hillman, A. R. Inorg. Chem., 1997, 36: 4919
16. [16]
  16. Holm, R. H.; Everett, G. W.; Chakravorty, A. Prog. Inorg. Chem., 1966, 7: 183
17. [17]
  17. Petr, A.; Dunsch, L.; Neudeck, A. J. Electroanal. Chem., 1996, 412: 153
18. [18]
  18. Tchepurnaya, I. A.; Vasilieva, S. V.; Logvinov, S. A.; Timonov, A. M.; Amadelli, R.; Bartak, D. Langmuir, 2003, 19: 9005
19. [19]
  19. Martins, M.; Boas, M. V.; Castro, B. D.; Hillman, A. R.; Freire, C. Electrochimica Acta, 2005, 51: 304
20. [20]
  20. Aubert, P. H.; Audebert, P.; Roche, M.; Capdeville, P.; Maumy, M.; Ricart, G. Chem. Mater., 2001, 13: 2223
21. [21]
  21. Bard, A. J.; Faulkner, L. R. Electrochemical methods: fundamentals and applications. 2nd ed. NewYork: Wiley Press, 1991: 471-533 (Chapter 12: Electrode Reactions with Coupled Homogeneous Chemical Reactions)
22. [22]
  22. Boas, M. V.; Freire, C.; Castro, B. D.; Hillman, A. R. J. Phys. Chem. B, 1998, 102: 8522
23. [23]
  23. Cynthia, G. Z. Handbook of electrochemistry. Oxford: Elsevier Press, 2007: 440-441 (Chapter 11: Classical Experiments)
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
4. [4]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
7. [7]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
8. [8]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
9. [9]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
10. [10]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
11. [11]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
12. [12]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
13. [13]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
14. [14]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
15. [15]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
16. [16]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
17. [17]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
18. [18]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
19. [19]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
20. [20]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086

Get Citation

PDF

XML

Metrics

PDF Downloads(1335)
Abstract views(3047)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142