Citation: HU Ren-Zhi, ZHANG Qun, CHEN Yang. Temperature Dependence of Reactions of C2(a3Πu) Radical with Several Unsaturated Hydrocarbons[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2619-2624. doi: 10.3866/PKU.WHXB20100938 shu

Temperature Dependence of Reactions of C2(a3Πu) Radical with Several Unsaturated Hydrocarbons

  • Received Date: 7 April 2010
    Available Online: 27 September 2010

    Fund Project: 国家自然科学基金(20673107, 20873133) (20673107, 20873133) 国家重点基础研究发展规划项目(973)(2007CB815203, 2010CB923302) (973)(2007CB815203, 2010CB923302)中国科学院知识创新工程(KJCX2-YW-N24)资助 (KJCX2-YW-N24)

  • We studied the temperature dependence on the gas phase reactions of theC2(a3Πu) radical with several unsaturated hydrocarbons (C2H4 (k1),C2H2 (k2),C3H6 (k3), and 2-C4H8 (k4)) by means of pulsed laser photolysis-laser induced fluorescence (PLP-LIF) technique. The bimolecular rate constants for these reactions were obtained in the temperature range of 298-673 K. The obtained kinetics data were used to derive the following Arrhenius expressions: k1(T)=(4.53 ±0.05) ×10-11exp[(196.41 ±5.20)/T], k2(T)=(3.94 ±0.04) ×10-11exp[(143.04 ±4.28)/T], k3(T)=(7.96 ±0.17) ×10-11 exp[(185.10 ±8.86)/T], and k4(T)=(1.04 ±0.02) ×10-10exp[(180.34 ±7.67)/T], where all error estimates are ±2σ and represent the precision of the fit. The observed bimolecular rate constants along with the negative temperature dependences of k(T) allow us to reacha conclusion that the reactions of C2(a3Πu) with these unsaturated hydrocarbons in the temperature range of 298-673 K proceed via an addition mechanism.

     

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    1. [1]

      1. Baronavski, A. P.; McDonald, J. R. J. Chem. Phys., 1977, 66: 3300

    2. [2]

      2. McKellar, A. J. R. Astron. Soc. Can., 1960, 54: 97

    3. [3]

      3. Brault, J. W.; Delbouille, L.; Grevesse, N.; Roland, G.; Sauval, A. J.; Testerman, L. Astron. Astrophys., 1982, 108: 201

    4. [4]

      4. A'Hearn, M. F.; Millis, R. C.; Schleicher, D. O.; Osip, D. J.; Birch, P. V. Icarus, 1995, 118: 223

    5. [5]

      5. Bakker, E. J.; van Dishoeck, E. F.; Waters, L. B. F.M.; Schoenmaker, T. Astron. Astrophys., 1997, 323: 469

    6. [6]

      6. Cecchi-Pestellini, C.; Dalgarno, A. Mon. Not. R. Astron. Soc., 2002, 331: L31

    7. [7]

      7. Oka, T.; Thorburn, J. A.; McCall, B. J.; Friedman, S. D.; Hobbs, L. M.; Sonnentrucker, P.; Welty, D. E.; York, D. G. Astrophys. J., 2003, 582: 823

    8. [8]

      8. Rennick, C. J.; Smith, J. A.; Ashfold, M. N. R.; Orr-Ewing, A. J. Chem. Phys. Lett., 2004, 383: 518

    9. [9]

      9. rdillo-Vazquez, F. J.; Albella, J. M. J. Appl. Phys., 2003, 94: 6085

    10. [10]

      10. Ballik, E. A.; Ramsay, D. A. Astrophys. J., 1963, 137: 84

    11. [11]

      11. Herzberg, G. Molecular spectra and molecular structure I. Spectra of diatomic molecules. Princeton: van Nostrand, 1950

    12. [12]

      12. Krause, H. F. J. Chem. Phys., 1979, 70: 3871

    13. [13]

      13. Donnelly, V. M.; Pasternack, L. Chem. Phys., 1979, 39: 427

    14. [14]

      14. Pasternack, L.; McDonald, J. R. Chem. Phys., 1979, 43: 173

    15. [15]

      15. Reisler, H.; Mangir, M.; Wittig, C. J. Chem. Phys., 1979, 71: 2109

    16. [16]

      16. Reisler, H.; Mangir, M.; Wittig, C. Chem. Phys., 1980, 47: 49

    17. [17]

      17. Mangir, M. S.; Reisler, H.; Wittig, C. J. Chem. Phys., 1980, 73: 829

    18. [18]

      18. Reisler, H.; Mangir, M. S.; Wittig, C. J. Chem. Phys., 1980, 73: 2280

    19. [19]

      19. Pasternack, L.; Baronavski, A. P.; McDonald, J. R. J. Chem. Phys., 1980, 73: 3508

    20. [20]

      20. Pasternack, L.; Pitts,W. M.; McDonald, J. R. Chem. Phys., 1981, 57: 19

    21. [21]

      21. Pitts, W. M.; Pasternack, L.; McDonald, J. R. Chem. Phys., 1982, 68: 417

    22. [22]

      22. Kruse, T.; Roth, P. Int. J. Chem. Kin., 1999, 31: 11

    23. [23]

      23. Becker, K. H.; Donner, B.; Dinis, C. M. F.; Geiger, H.; Schmidt, F.; Wiesen, P. Z. Phys. Chem., 2000, 214: 503

    24. [24]

      24. Fontijn, A.; Fernandez, A.; Ristanovic, A.; Randall, M. Y.; Jankowiak, J. T. J. Phys. Chem. A, 2001, 105: 3182

    25. [25]

      25. Ristanovic, A.; Fernandez, A.; Fontijn, A. J. Phys. Chem. A, 2002, 106: 8291

    26. [26]

      26. Huang, C. S.; Zhu, Z. Q.; Xin, Y.; Pei, L. S.; Chen, C. X.; Chen, Y. J. Chem. Phys., 2004, 120: 2225

    27. [27]

      27. Huang, C. S.; Zhao, D. F.; Pei, L. S.; Chen, C. X.; Chen, Y. Chem. Phys. Lett., 2004, 389: 230

    28. [28]

      28. Huang, C. S.; Li, Z. X.; Zhao, D. F.; Xin, Y.; Pei, L. S.; Chen, C. X.; Chen, Y. Chin. Sci. Bull., 2004, 49: 438

    29. [29]

      29. Huang, C. S.; Zhu, Z. Q.; Wang, H. L.; Pei, L. S.; Chen, Y. J. Phys. Chem. A, 2005, 109: 3921

    30. [30]

      30. Hu, R. Z.; Zhang, Q.; Chen, Y. J. Chem. Phys., 2010, 132: 164312

    31. [31]

      31. Daugey, N.; Caubet, P.; Bergeat, A.; Costes, M.; Hickson, K. M. Phys. Chem. Chem. Phys., 2008, 10: 729

    32. [32]

      32. Páramo, A.; Canosa, A.; Le Picard, S. D.; Sims, I. R. J. Phys. Chem. A, 2006, 110: 3121

    33. [33]

      33. Páramo, A.; Canosa, A.; Le Picard, S. D.; Sims, I. R. J. Phys. Chem. A, 2008, 112: 9591

    34. [34]

      34. http://webbook.nist. v.

    35. [35]

      35. Ochimizu, T.; Seki, K.; Yagi, M.; Halpern, J. B.; Okabe, H. Chem. Phys. Lett., 1999, 313: 451

    36. [36]

      36. Berman, M. R.; Fleming, J. W.; Harvey, A. B.; Lin, M. C. Chem. Phys., 1982, 73: 27

    37. [37]

      37. Lichtin, D.; Lin, M. C. Chem. Phys., 1986, 104: 325

    38. [38]

      38. Atkinson, R. Chem. Rev., 1985, 85: 69

    39. [39]

      39. Gu, X. B.; Guo, Y.; Zhang, F. T.; Mebel, A. M.; Kaiser, R. I. Faraday Discuss., 2006, 133: 245

    40. [40]

      40. Gu, X. B.; Guo, Y.; Zhang, F. T.; Mebel, A. M.; Kaiser, R. I. Chem. Phys., 2007, 335: 95

    41. [41]

      41. Kaiser, R. I.; Balucani, N.; Charkin, D. O.; Mebel, A. M. Chem. Phys. Lett., 2003, 382: 112

    42. [42]

      42. Gu, X. B.; Guo, Y.; Mebel, A. M.; Kaiser, R. I. J. Phys. Chem. A, 2006, 110: 11265

    43. [43]

      43. Leonori, F.; Petrucci, R.; Hickson, K. M.; Se lini, E.; Le Picard, S. D.; Balucani, N.; Foggi, P.; Casavecchia, P. Planet. Space Sci., 2008, 56: 1658

    44. [44]

      44. Kaiser, R. I.; Le, T. N.; Nguyen, T. L.; Mebel, A. M.; Balucani, N.; Lee, Y. T.; Stahl, F.; Schleyer, P. V.; Schaefer, H. F. Faraday Discuss., 2001, 119: 51

    45. [45]

      45. Guo, Y.; Kislov, V. V.; Gu, X.; Zhang, F.; Mebel, A. M.; Kaiser, R. I. Astrophys. J., 2006, 653: 1577

    46. [46]

      46. McKee, K.; Blitz, M. A.; Hughes, K. J.; Pilling, M. J.; Qian, H. B.; Taylor, A.; Seakins, P. W. J. Phys. Chem. A, 2003, 107: 5710

    47. [47]

      47. Choi, N.; Blitz, M. A.; McKee, K.; Pilling, M. J.; Seakins, P. W. Chem. Phys. Lett., 2004, 384: 68

    48. [48]

      48. Gannon, K. L.; Glowacki, D. R.; Blitz, M. A.; Hughes, K. J.; Pilling, M. J.; Seakins, P. W. J. Phys. Chem. A, 2007, 111: 6679


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