Citation: SONG Hua, GUO Yun-Tao, LI Feng, YU Hong-Kun. Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni₂P/TiO₂-Al₂O₃ Catalyst[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2461-2467. doi: 10.3866/PKU.WHXB20100937 shu

Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni₂P/TiO₂-Al₂O₃ Catalyst

1.
Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering,Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P. R. China

Received Date: 30 March 2010
Available Online: 3 August 2010
Fund Project: 黑龙江省科技厅(2009G0947-00)资助项目 (2009G0947-00)

We prepared a TiO₂-Al₂O₃ complex support by the sol-gel method. A nickel phosphide catalyst, Ni₂P/ TiO₂-Al₂O₃, was prepared by the impregnation method. The catalysts were characterized by X-ray diffraction (XRD), N₂-adsorption specific surface area measurements (BET), thermogravimetry-differential thermal analysis (TG-DTA), and X-ray photoelectron spectroscopy (XPS). The catalysts were evaluated using a lab-scale continuous flow fixed-bed reactor for simultaneously hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of thiophene and pyridine. The effects of different supports, Ni₂P loading, Ni/P molar ratio, and calcination temperature on catalyst activity for the HDS and HDN were studied. The catalytic activity of the Ni₂P/TiO₂-Al₂O₃ catalyst with a TiO₂ mass fraction of 80%, a Ni₂P loading of 30.0%(w), a Ni/P molar ratio of 1/2 as well as a calcination temperature of 500^oCwas found to be optimal. At a reaction temperature of 360 ^o, a pressure of 3.0 MPa, a hydrogen/oil ratio of 800 (V/V), and a liquid hourly space velocity of 1.5 h^-1, the conversion of thiophene HDS and pyridine HDN were 61.32%and 64.43%, respectively.
- Nickel phosphide,
- Titaniumdioxide,
- Aluminiumtrioxide,
- Hydrodesulfurization,
- Hydrodenitrogenation
1. [1]
  
  1. Abu, I. I.; Smith, K. J. Appl. Catal. A-Gen., 2007, 328: 58
2. [2]
  2. Kwak, C.; Lee, J. J.; Bae, J. S.; Moon, S. H. Appl. Catal. B, 2001, 35: 59
3. [3]
  3. Koranyi, T. I.; Vit, Z.; Nagy, J. B. Catal. Today, 2008, 130: 80
4. [4]
  4. Sawhill, S. J.; Phillips, D. C.; Bussell, M. E. J. Catal., 2003, 215: 208
5. [5]
  5. Stinner, C.; Tang, Z.; Haouas, M.; Weber, T.; Prins, R. J. Catal., 2002, 208: 456
6. [6]
  6. Li, D. Y.; Yu, X. Z.; Chen, C. L.; Xu, N. P.; Wang, Y. R. J. Chem. Eng. Chin. Univ., 2006, 21: 825 [李冬燕,余夕志, 陈长林,徐南平,王延儒.高校化学工程学报, 2006, 21: 825]
7. [7]
  7. Oyama, S. T. J. Catal., 2003, 216: 343
8. [8]
  8. Huang, X. F.; Ji, S. F.; Wu, P. Y.; Liu, Q. Q.; Liu, H.; Zhu, J. Q.; Li, C. Y. Acta Phys. -Chim. Sin., 2008, 24(10): 1773 [黄晓凡, 季生福, 吴平易,刘倩倩,刘辉,朱吉钦, 李成岳.物理化学学报, 2008, 24(10): 1773]
9. [9]
  9. Wei, Y.; Liu, X. X. Petrochem. Technol., 2006, 35(2): 173 [韦以,刘新香. 石油化工, 2006, 35(2): 173]
10. [10]
  10. Song, H.; Yu, H. K.; Wu, X. C.; Guo, Y. T. Chin. J. Catal., 2010, 31(4): 447 [宋华, 于洪坤,武显春,郭云涛.催化学报, 2010, 31(4): 447]
11. [11]
  11. Duan, A. J.; Li, R. L.; Jiang, G. Y.; Gao, J. S.; Zhao, Z.; Wan, G. F.; Zhang, D. Q.; Huang, W. Q.; Chung, K. H. Catal. Today, 2009, 140: 187
12. [12]
  12. Zhang, Q.; Li, B. S.; Sun, G. D.; Zhou, Z. J. J. Photochem. Univ., 2007, 20: 18 [张强,李保山,孙桂大,周志军. 石油化工高等学校学报, 2007, 20: 18]
13. [13]
  13. Hu, G. R.; Xiao, Z. W.; Du, K.; Peng, Z. D.; Deng, X. R. Chin. J. Nonferrous Met., 2007, 17(12): 2014 [胡国荣, 肖政伟,杜柯, 彭忠东,邓新荣.中国有色金属学报, 2007, 17(12): 2014]
14. [14]
  14. Wang, R.; Smith, K. J. Appl. Catal. A-Gen., 2010, 380: 149
15. [15]
  15. Guo, Y. N.; Zeng, P. H.; Ji, S. F.; Wei, N.; Liu, H.; Li, C. Y. Chin. J. Catal., 2010, 31(3): 329 [郭亚男,曾鹏晖,季生福,魏妮, 刘辉,李成岳.催化学报, 2010, 31(3): 329]
16. [16]
  16. Kanama, D.; Oyama, S. T.; Otani, S.; Cox, D. F. Surf. Sci. Spectra, 2001, 8: 220
17. [17]
  17. Bertrand, P. A. J. Vac. Sci. Technol., 1981, 18: 28
18. [18]
  18. Abu, I. I.; Smith, K. J. J. Catal., 2006, 241: 356
19. [19]
  19. Cecilia, J. A.; Infantes-Molina, A.; Rodr侏guez-Castell佼n, E.; Jim佴nez-L佼pez, A. J. Catal., 2009, 263: 4
20. [20]
  20. Zhang, H.; Tan, X.; Zhao, L.; Ma, H. Q. Chemistry, 2005, 68: w095 [张昊,谭欣,赵林, 马红钦.化学通报, 2005, 68: w095]
21. [21]
  21. Oyama, S. T.; Lee, Y. K. J. Catal., 2008, 258: 393
22. [22]
  22. Oyama, S. T.; Wang, X.; Lee, Y. K.; Chun, W. J. J. Catal., 2004, 221: 263
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni₂P/TiO₂-Al₂O₃ Catalyst