Citation: LU Chun-Li, FU Zai-Hui, LIU Ya-Chun, LIU Feng-Lan, QIN Jin-Wei, HE Xiang-Ling, YIN Du-Lin. Selective Oxidation of Ethylbenzene with Hydrogen Peroxide Catalyzed by 5,7-Dibromo-8-quinolinolato Manganese Complexes[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2705-2710. doi: 10.3866/PKU.WHXB20100936 shu

Selective Oxidation of Ethylbenzene with Hydrogen Peroxide Catalyzed by 5,7-Dibromo-8-quinolinolato Manganese Complexes

1.
Key Laboratory of Resource Fine-Processing and Advanced Materials of Hunan Province, Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research of Ministry of Education of China, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, P. R. China

Received Date: 17 February 2010
Available Online: 27 September 2010
Fund Project: 国家自然科学基金(20873040, 20573035)资助项目 (20873040, 20573035)

Two 5,7-dibromo-8-quinolinolato manganese complexes in tetradentate (Q₂Mn^II) and hexadentate (Q₃Mn^III) modes were prepared and then characterized by Fourier transform infrared (FT-IR) spectrometry. We found that both Mn complexes, together with NH₄OAC and HOAc, efficiently catalyzed the oxidation of ethylbenzene to acetophenone by hydrogen peroxide in an acetone -water medium at 20 ^oC. Q₃Mn^IIIshowed much higher catalytic activity for this reaction thanQ₂Mn^II, affordinga 27% ethylbenzene conversion and more than 95% selectivity for acetophenone under optimum conditions.Q₃Mn^IIIwas reused three times without significant deactivation, indicating od stability.
- 5,7-Dibromo-8-guinolinolato Mn(III) complex,
- Hexadentate mode,
- Ethylbenzene,
- Acetophenone,
- Selective oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142