Citation: FENG Jin-Ling, ZHANG Jian-Guo, ZHANG Tong-Lai, CUI Yan. Synthesis, Crystal Structure, Thermal Behavior and Sensitivity of [Mn(AZT)₂(H₂O)₄] (HTNR)₂·4H₂O[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2410-2416. doi: 10.3866/PKU.WHXB20100919 shu

Synthesis, Crystal Structure, Thermal Behavior and Sensitivity of [Mn(AZT)₂(H₂O)₄] (HTNR)₂·4H₂O

1.
1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. The 6th Department, Research Institute of Chemical Defense (PLA), Beijing 102205, P. R. China

Received Date: 1 April 2010
Available Online: 15 July 2010
Fund Project: 国家自然科学基金(20471008) (20471008)

A novel energetic coordination complex of [Mn(AZT)₂(H₂O)₄] (HTNR)₂·4H₂O (AZT=3-azido-1,2,4- triazole, HTNR=2,4,6-trinitro resorcinol) was prepared by the reaction between the acidic manganese (II) salt of 2,4,6-trinitro resorcinol and AZT in an aqueous solution. The complex was characterized by elemental analysis and FTIR spectroscopy. The molecular structure was determined by X-ray single crystal diffraction. The crystal belongs to the triclinic systemwith a Pī space group. The central manganese(II) cation has a slightly distorted octahedron feature. Three-dimension networks were formed and the layers are linked by extensive hydrogen bonding. The thermal decompositionmechanismof [Mn(AZT)₂(H₂O)₄] (HTNR)₂·4H₂O was predicted based on differential scanning calorimetry (DSC) and thermogravimetry-derivative thermogravimetry (TG-DTG) analyses. One endothermic peak and three exothermic peaks are present during the thermal decomposition process with the final residue at 600 ℃being MnO and MnO₂. The kinetic parameters of the exothermic process for the complex were studied using Kissinger's and Ozawa- Doyle's methods. Furthermore, impact sensitivity, flame sensitivity, and friction sensitivity tests reveal that the title complex is sensitive and selective towards external stimulants.
- Crystal structure,
- 3-Azido-1,2,4-triazole,
- Manganese(II) complex,
- Sensitivity,
- Thermal behavior
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Synthesis, Crystal Structure, Thermal Behavior and Sensitivity of [Mn(AZT)2(H2O)4] (HTNR)2·4H2O

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure, Thermal Behavior and Sensitivity of [Mn(AZT)₂(H₂O)₄] (HTNR)₂·4H₂O