Citation: FU Jing, LIN Rui, LV Hong, WANG Xiao-Lei, MA Jian-Xin, QIAO Jin-Li. Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2653-2658. doi: 10.3866/PKU.WHXB20100918 shu

Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes

FU Jing ^1,2 ,
LIN Rui ² ,
LV Hong ² ,
WANG Xiao-Lei ² ,
MA Jian-Xin ^1,2, ,
QIAO Jin-Li ^3,

1.
1. School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, P. R. China;
3. School of Environmental Science and Engineering, Donghua University, Shanghai 201260, P. R. China

Received Date: 16 March 2010
Available Online: 27 September 2010
Fund Project: 上海市浦江人才基金(08PJ14096) (08PJ14096)上海市自然科学基金(09ZR1433300) (09ZR1433300)教育部归国留学人员基金(2009(1001))资助项目 (2009(1001))

Solid alkaline electrolyte membranes were prepared using poly(vinyl alcohol)/poly(vinyl pyrrolidone) (PVA/PVP) by KOH doping. The composition, microstructure, thermal stability, ionic conducitvity and methanol uptake of the composite membranes were investigated in detail. The wholly transparent, homogeneous and compact PVA/PVP/KOH composite membranes were obtained when m(PVA) :m(PVP)=1 :0.5 in a mass ratio and no obvious phase seperation was observed. The ionic conductivity and thermal stability of the PVA/PVP membranes increased greatly with increasing the content of PVP. A high ionic conductivity of 2.01 ×10^-3S·cm^-1was obtained whena mass ratio of m(PVA) :m(PVP)=1 :1 was used. In additon, the methanol uptake of the PVA/PVP/KOH membranes showed almost no change after conditioning at elevated temperatures and it was 4 times lower than that of the Nafion 115 membrane after conditioning at 100 ℃. These membranes are, therefore, promising solid alkaline electrolyte membranes for use in alkaline direct methanol fuel cells at elevated operating temperature.
- Solid alkaline electrolyte membrane,
- Poly(vinyl alcohol),
- Poly(vinyl pyrrolidone),
- Ionicconductivity,
- Methanol uptake,
- Thermal stability
1. [1]
  
  1. Yu, E. H.; Scott, K.; Reeve, R. W. J. Electroanal. Chem., 2003, 547: 17
2. [2]
  2. Abdel, R. M. A.; Abdel, H. R. M.; Khalia, M. W. J. Power Sources, 2004, 134:160
3. [3]
  3. Shibili, S. M. A.; Noel, M. J. Power Sources, 1993, 45: 139
4. [4]
  4. Mosdale, R.; Srinivasan, S. Electrochem. Acta, 1995, 40: 413
5. [5]
  5. Staiti, P.; Poltarzewski, Z.; Alderueei, V. J. Appl. Electrochem., 1992, 22(7): 663
6. [6]
  6. Kang, J. J.; Li, W. Y.; Lin, Y.; Li, X. P.; Xiao, X. R.; Fang, S. B. Poly. Adv. Tech., 2004, 15: 61
7. [7]
  7. Li, L.; Wang, Y. X. J. Membr. Sci., 2005, 262(1): 1
8. [8]
  8. Wang, G. G.; Weng, Y. M.; Chu, D.; Xie, D.; Chen, R. R. J. Membr. Sci., 2009, 326(1): 4
9. [9]
  9. Fang, J.; Shen, P. K. J. Membr. Sci., 2006, 285(1-2): 317
10. [10]
  10. Robert, C. T. S.; John, R. V. Solid State Ionics, 2005, 176: 585
11. [11]
  11. Timothy, N. D.; Robert, C. T. S.; John, R. V. J. Mater. Chem., 2002, 12: 3371
12. [12]
  12. John, R. V.; Robert, C. T. S. Electrochem. Commun., 2006, 8: 839
13. [13]
  13. Wu, H.; Wang, Y. X.;Wang, S. C. Poly. Mater. Sci. Eng., 2001, 17(4): 7 [吴洪,王宇新, 王世昌. 高分子材料科学与工程, 2001, 17(4): 7]
14. [14]
  14. Yang, C. C.; Chiu, S. J.; Chien, W. C.; Chiu, S. S. J. Power Sources, 2010, 195: 2212
15. [15]
  15. Yang, C. C. J. Membr. Sci., 2007, 288(1-2): 51
16. [16]
  16. Yang, C. C.; Che, T. L.; Shwu, J. C. Desalination, 2008, 233: 137
17. [17]
  17. Manea, C.; Mulder, M. J. Membr. Sci., 2002, 206(1-2): 443
18. [18]
  18. Qiao, J. L.; Takeo, H.; Tatsuhiro, O. Polymer, 2005, 46: 10809
19. [19]
  19. Xiong, Y.; Liu, Q. L.; Zhang, Q. G.; Zhu, A. M. J. Power Sources, 2008, 183: 447
20. [20]
  20. Jiang, Z. L.; Pan, M.; Shen, C. H.; Luo, Z. P.; Yuan, R. Z. Poly. Mater. Sci. Eng., 2006, 22(1): 99 [蒋中林, 潘牧, 沈春辉, 罗志平, 袁润章.高分子材料科学与工程, 2006, 22(1): 99]
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