Citation: ZHANG Lei, HU Bo, CHEN Hua, LI Xian-Jun, LI Rui-Xiang. Catalytic Performance of Porous SiO₂·xH₂O Supported RuB Nanoparticles for the Hydrogenation of Quinoline[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2422-2428. doi: 10.3866/PKU.WHXB20100901 shu

Catalytic Performance of Porous SiO₂·xH₂O Supported RuB Nanoparticles for the Hydrogenation of Quinoline

1.
Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received Date: 19 February 2010
Available Online: 6 July 2010
Fund Project: 国家自然科学基金(21072138)资助项目 (21072138)

A porous and hydroxyl group-rich catalyst RuB/SiO₂·xH₂O was prepared by hydrolyzing ethyl silicate, protecting SiO₂·xH₂O with polyvinyl pyrrolidone (PVP), and etching SiO₂·xH₂O with NaOH. The catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), Fourier transforminfrared (FT-IR) spectroscopy, and BET (Brunauer-Emmett-Teller). We found that the catalyst showed excellent performance for the hydrogenation of quinoline under mild condition. At a hydrogen pressure of 3.0 MPa and a reaction temperature of 80 ℃, the conversion of quinoline reached 95% and the selectivity for 1,2,3,4- tetrahydroquinoline was 97%. This porous catalyst also showed an excellent anti-poisoning characteristic. The catalyst can be reused several times. We also investigated the effect of surface hydroxyl groups and the solvent on catalytic activity and selectivity. The results showed that using water as a solvent leads to higher catalyst activity and selectivity for the hydrogenation of quinoline. The mechanism of quinoline hydrogenation over the catalyst is discussed. The coordination of the nitrogen on quinoline onto the surface of ruthenium nanoparticles, the effect of hydrogen bond among the surface hydroxyl groups of the catalyst and the nitrogen present in quinoline and in the water solvent were favorable for the adsorption of the substrate and the desorption of the products fromthe surface of the catalyst.
- Ruthenium,
- /SiO₂·xH₂O,
- Quinoline,
- Hydrogenation,
- Tetrahydroquinoline
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of Porous SiO₂·xH₂O Supported RuB Nanoparticles for the Hydrogenation of Quinoline