Citation: HUANG Yan, ZHANG Xing-Wang, LEI Le-Cheng. Preparation, Characterization and Catalytic Activity for ortho- Dichlorobenzene Ozonation of Fe-, Mn-Doped Xerogels[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2443-2448. doi: 10.3866/PKU.WHXB20100840 shu

Preparation, Characterization and Catalytic Activity for ortho- Dichlorobenzene Ozonation of Fe-, Mn-Doped Xerogels

1.
Institute of Industrial Ecology and Environment, Department of Chemical and Biological Engineering,Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 25 February 2010
Available Online: 2 July 2010
Fund Project: 国家自然科学基金(20836008, U0633003) (20836008, U0633003) 浙江省科技计划项目(2007C13061) (2007C13061)国家高技术研究发展计划(2007AA06Z339, 2008BAC32B06,2007AA06A409)资助 (2007AA06Z339, 2008BAC32B06,2007AA06A409)

Metal-doped xerogels were synthesized by the sol-gel method and their catalytic performance was evaluated for the catalytic ozonation of simulated micro-polluted water containing ortho-dichlorobenzene (o-DCB). The obtained samples were characterized by X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), X-ray diffraction (XRD), scanning electron microscopy (SEM), mercury porosimetry and nitrogen adsorption. Results show that Fe³⁺ oxides and Mn³⁺ oxides are present in the Fe-doped xerogel (XFe) and the Mn-doped xerogel (XMn), respectively. No obvious diffraction peaks corresponding to a metallic phase were present in the XRD patterns of the xerogels. Also, the metallic particles were found to be small; therefore, the metallic particles were well distributed over the xerogel supports. Catalytic ozonation experiments indicated that the removal rate of o-DCB was 44% with single ozonation, and this increased to 58% and 72% with catalytic ozonation using XFe and XMn, respectively, which suggests that metal-doped xerogels are promising catalysts for the ozonation process. We also investigated metal leaching from the metal-doped xerogel to the water solution to test the stability of the catalysts, and about 2%and 8%metal leaching for XFe and XMn was obtained within 5 h.
- Sol-gel method,
- Xerogel,
- Characterization,
- Catalytic ozonation,
- ortho-Dichlorobenzene
1. [1]
  
  1. Lei, L. C.; Gu, L.; Zhang, X.W.; Su, Y. L. Appl. Catal. A, 2007, 327: 287
2. [2]
  2. Gu, L.; Zhang, X.W.; Lei, L. C. Ind. Eng. Chem. Res., 2008, 47: 6809
3. [3]
  3. Liang, T.; Ma, J.; Wang, S. J.; Yang, Y. X.; Zhang, J. Environ. Sci.- China, 2007, 28: 2004 [梁涛,马军,王胜军, 杨忆新, 张静.环境科学, 2007, 28: 2004]
4. [4]
  4. Faria, P. C. C.; Monteiro, D. C. M.; 譫rf觔o, J. J. M.; Pereira, M. F.R. Chemosphere, 2009, 74: 818
5. [5]
  5. Zhang, T.; Li, C. J.; Ma, J.; Tian, H.; Qiang, Z. M. Appl. Catal. B, 2008, 82: 131
6. [6]
  6. Gruttadauria, M.; Liotta, L. F.; Di Carlo, G.; Pantaleo, G.; Deganello, G.; Lo Meo, P.; Aprile, C.; Noto, R. Appl. Catal. B, 2007, 75: 281
7. [7]
  7. Leitner, N. K. V.; Delouane, B.; Legube, B.; Luck, F. Ozone Sci. Eng., 1999, 21: 261
8. [8]
  8. Gu, L. Study on synergistic degradation of aqueous organic contaminants by adsortpion-catalytic ozonation system[D]. Hangzhou: Zhejiang University, 2009 [古励. 吸附-催化臭氧氧化协同降解液相有机污染物的研究.杭州: 浙江大学, 2009]
9. [9]
  9. Cao, S.; Chen, G.; Hu, X.; Yue, P. L. Catal. Today, 2003, 88: 37
10. [10]
  10. Beltran, F. J.; Rivas, F. J.; Montero-de-Espinosa, R. Water Res., 2005, 39: 3553
11. [11]
  11. Faria, P. C. C.; Orfao, J. J. M.; Pereira, M. F. R. Catal. Commun., 2008, 9: 2121
12. [12]
  12. Pekala, R. W. J. Mater. Sci., 1989, 24: 3221
13. [13]
  13. Pekala, R. W.; Schaefer, D. W. Macromolecules, 1993, 26: 5487
14. [14]
  14. Pekala, R. W.; Alviso, C. T.; Kong, F. M.; Hulsey, S. S. J. Non- Cryst. Solids, 1992, 145: 90
15. [15]
  15. Pekala, R. W.; Alviso, C. T.; Lemay, J. D. J. Non-Cryst. Solids, 1990, 125: 67
16. [16]
  16. Moreno-Castilla, C.; Maldonado-Hodar, F. J. Carbon, 2005, 43: 455
17. [17]
  17. Moreno-Castilla, C.; Maldonado-Hodar, F. J.; Rivera-Utrilla, J.; Rodriguez-Castellon, E. Appl. Catal. A, 1999, 183: 345
18. [18]
  18. Aguado-Serrano, J.; Rojas-Cervantes, M. L.; Martin-Aranda, R. M.; Lopez-Peinado, A. J.; mez-Serrano, V. Appl. Surf. Sci., 2006, 252: 6075
19. [19]
  19. Job, N.; Ferauche, F.; Pirard, R.; Pirard, J. P. Stud. Surf. Sci. Catal., 2002, 143: 619
20. [20]
  20. Sanchez-Polo, M.; Rivera-Utrilla, J.; von Gunten, U. Water Res., 2006, 40: 3375
21. [21]
  21. Orge, C. A.; Sousa, J. P. S.; n?alves, F.; Freire, C.; órf?o, J. J. M.; Pereira, M. F. R. Catal. Lett., 2009, 132: 1
22. [22]
  22. Moreno-Castilla, C.; Maldonado-Hodar, F. J.; Perez-Cadenas, A. F. Langmuir, 2003, 19: 5650
23. [23]
  23. Birdsall, C. M.; Jenkins, A. C.; Spadinger, E. Anal. Chem., 1952, 24: 662
24. [24]
  24. Lin, T. C.; Seshadri, G.; Kelber, J. A. Appl. Surf. Sci., 1997, 119: 83
25. [25]
  25. Pakula, M.; Biniak, S.; Swiatkowski, A. Langmuir, 1998, 14: 3082
26. [26]
  26. Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben, K. D. Handbook of X-ray photoelectron spectroscopy. 2nd ed. Eden Prairie: Perkin-Elmer Corporation, 1992
27. [27]
  27. Kónya, Z.; Kiss, J.; Oszkó, A.; Siska, A.; Kiricsi, I. Phys. Chem. Chem. Phys., 2001, 3: 155
28. [28]
  28. Chen, H.; Sayari, A.; Adnot, A.; Larachi, F. Appl. Catal. B, 2001, 32: 195
29. [29]
  29. Maldonado-Hódar, F. J.; Moreno-Castilla, C.; Pérez-Cadenas, A. F. Microporous Mesoporous Mat., 2004, 69: 119
30. [30]
  30. Al-Muhtaseb, S. A.; Ritter, J. A. Adv. Mater., 2003, 15: 101
31. [31]
  31. Job, N.; Pereira, M. F. R.; Lambert, S.; Cabiac, A.; Delahay, G.; Colomer, J. F.; Marien, J.; Figueiredo, J. L.; Pirard, J. P. J. Catal., 2006, 240: 160
1. [1]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
2. [2]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
3. [3]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
4. [4]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
5. [5]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
6. [6]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
7. [7]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
8. [8]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
9. [9]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
10. [10]
  Haoxiang Zhang , Zhihan Zhao , Yongchen Jin , Zhiqiang Niu , Jinlei Tian . Synthesis of an Efficient Absorbent Gel: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(11): 251-258. doi: 10.12461/PKU.DXHX202401084
11. [11]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
12. [12]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
13. [13]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
14. [14]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
15. [15]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
16. [16]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
17. [17]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
18. [18]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
19. [19]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
20. [20]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057

Get Citation

PDF

XML

Metrics

PDF Downloads(1021)
Abstract views(2897)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142