Citation: XU Hai-Di, QIU Chun-Tian, ZHANG Qiu-Lin, LIN Tao, NG Mao-Chu, CHEN Yao-Qiang. Influence of Tungsten Oxide on Selective Catalytic Reduction of NOx with NH3 over MnOx -CeO2 /ZrO2-TiO2Monolith Catalyst[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2449-2454. doi: 10.3866/PKU.WHXB20100838 shu

Influence of Tungsten Oxide on Selective Catalytic Reduction of NOx with NH3 over MnOx -CeO2 /ZrO2-TiO2Monolith Catalyst

  • Received Date: 2 February 2010
    Available Online: 1 July 2010

    Fund Project: 国家自然科学基金重点项目(20333030) (20333030)国家自然科学基金(20273043)资助 (20273043)

  • MnOx-CeO2/WO3/ZrO2-TiO2monolithic catalyst was prepared by ZrO2-TiO2 as support, MnOx-CeO2 as active components and WO3 as the promoter. The influence of the different mass fractions (w) of WO3 on the NH3-selective catalytic reduction (NH3-SCR) of NOx performance at low temperature was studied. The catalysts were characterized by N2 adsorption-desorption at low temperature, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and NH3 temperature-programmed desorption (NH3-TPD). The experimental results showed that, compared with the catalyst without WO3, the catalyst with 10.0% (w)WO3 had od texture properties, middle strong acid sites, and higher Oxidation performance. The results of activity test showed that the monolith catalyst had not only od catalytic activity at low temperature but also a wide activity temperature window. The NOx conversion is more than 90%in the temperature range of 144-374oC at the space velocity of 10000 h-1. It shows potential application in de-NOx at low-temperature.

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