Citation: XU Hai-Di, QIU Chun-Tian, ZHANG Qiu-Lin, LIN Tao, NG Mao-Chu, CHEN Yao-Qiang. Influence of Tungsten Oxide on Selective Catalytic Reduction of NO_x with NH₃ over MnO_x -CeO₂ /ZrO₂-TiO₂Monolith Catalyst[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2449-2454. doi: 10.3866/PKU.WHXB20100838 shu

Influence of Tungsten Oxide on Selective Catalytic Reduction of NO_x with NH₃ over MnO_x -CeO₂ /ZrO₂-TiO₂Monolith Catalyst

1.
Key Laboratory of Green Chemistry &Technology of the Ministry of Education, Sichuan University,Chengdu 610064, P. R. China

Received Date: 2 February 2010
Available Online: 1 July 2010
Fund Project: 国家自然科学基金重点项目(20333030) (20333030)国家自然科学基金(20273043)资助 (20273043)

MnO_x-CeO₂/WO₃/ZrO₂-TiO₂monolithic catalyst was prepared by ZrO₂-TiO₂ as support, MnO_x-CeO₂ as active components and WO₃ as the promoter. The influence of the different mass fractions (w) of WO₃ on the NH₃-selective catalytic reduction (NH₃-SCR) of NO_x performance at low temperature was studied. The catalysts were characterized by N2 adsorption-desorption at low temperature, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and NH₃ temperature-programmed desorption (NH₃-TPD). The experimental results showed that, compared with the catalyst without WO₃, the catalyst with 10.0% (w)WO₃ had od texture properties, middle strong acid sites, and higher O_xidation performance. The results of activity test showed that the monolith catalyst had not only od catalytic activity at low temperature but also a wide activity temperature window. The NO_x conversion is more than 90%in the temperature range of 144-374^oC at the space velocity of 10000 h^-1. It shows potential application in de-NO_x at low-temperature.
- Low temperature,
- Selective catalytic reduction,
- Tungsten trioxide,
- Nitrogen oxide,
- Monolithic catalysts
1. [1]
  
  1. Rahkamaa-Tolonena, K.; Maunula, T.; Lomma, M.; Huuhtanen, M.; Keiski, R. L. Catal. Today, 2005, 100: 217
2. [2]
  2. Bosch, H.; Janssen, F. J. J. G.; van den Kerkhof, F. M. G.; Oldenziel, J.; van Ommen, J. C.; Ross, J. R. H. Appl. Catal., 1986, 25: 239
3. [3]
  3. Bosch, H.; Janssen, F. Catal. Today, 1988, 2: 369
4. [4]
  4. Kijlstra,W. S.; Brands, D. S.; Smit, H. I.; Poels, E. K.; Bliek, A. J. Catal., 1997, 171: 219
5. [5]
  5. Blanco, J.; Avila, P.; Suárez, S.; Martín, J. A.; Knapp, C. Appl. Catal. B-Environ., 2000, 28: 235
6. [6]
  6. Qi, G. S.; Yang, R. T. J. Catal., 2003, 217: 434
7. [7]
  7. Ramis, G.; Larrubia, M. A. J. Mol. Catal. A-Chem., 2004, 215 (122): 161
8. [8]
  8. Chen, L.; Li, J. H.; Ge, M. F. J. Phys. Chem. C, 2009, 113: 21177
9. [9]
  9. Ka?par, J.; Fornasiero, P.; Hickey, N. Catal. Today, 2003, 77: 419
10. [10]
  10. Tang, X. L.; Hao, J. M.; Xu, W. G.; Li, J. H. Catal. Commun., 2007, 8: 329
11. [11]
  11. Donovan, A. P.; Balu, S. U.; Panagiotis, G. S. J. Catal., 2004, 221: 421
12. [12]
  12. Li, J. H.; Chen, J.; Ke, R.; Luo, C. K.; Hao, J. M. Catal. Commun., 2007, 8: 1896
13. [13]
  13. Qi, G. S.; Yang, R. T.; Chang, R. Appl. Catal. B-Environ., 2004, 51: 93
14. [14]
  14. Qi, G. S.; Yang, R. T. J. Phys. Chem. B, 2004, 108: 15738
15. [15]
  15. Forzatti, P. Appl. Catal. A-Gen., 2001, 222: 221
16. [16]
  16. Apostolescu, N.; Geiger, B.; Hizbullah, K.; Jan, M. T.; Kureti, S.; Reichert, D.; Schott, F.; Weisweiler, W. Appl. Catal. B-Environ., 2006, 62: 104
17. [17]
  17. Reddy, B. M.; Khan, A. Catal. Rev., 2005, 47(2) : 257
18. [18]
  18. Li, W.; Lin, T.; Zhang, Q. L.; ng, M. C.; Chen, Y. Q. Chin. J. Catal., 2009, 30(2):104 [李伟,林涛, 张秋林, 龚茂初, 陈耀强.催化学报, 2009, 30(2): 104]
19. [19]
  19. Machida, M.; Uto, M.; Kurogi, D.; Kijima, T. Chem. Mater., 2000, 12: 3158
20. [20]
  20. Huang, H. Y.; Yang, R. T. Langmuir, 2001, 17: 4997
21. [21]
  21. Pena, D. A.; Uphade, B. S.; Smirniotis, P. G. J. Catal., 2004, 221: 421
22. [22]
  22. Due-Hansen, J.; Kustov, A. L.; Rasmussen, S. B.; Fehrmann, R.; Christensen, C. H. Appl. Catal. B-Environ., 2006, 66: 161
23. [23]
  23. Tang, X. L. The technology and reaction mechanismof low temperature selective catalytic reduction of NOx. Beijing: Metallurgical Industry Press, 2007: 109 [唐晓龙.低温选择性催化还原NOx技术及反应机理.北京:冶金工业出版社, 2007: 109]
24. [24]
  24. Juan, P. H.; Rafael, A.; Guillermo, M. Appl. Surf. Sci., 2000, 161 (3-4): 301
25. [25]
  25. Falcal, L.; Jerome, P.; Alain, A. Appl. Surf. Sci., 2002, 195: 236
26. [26]
  26. Kijlstra, W. S.; Brand, D. S.; Smit, H. I.; Poels, E. K.; Blief, A. J. Catal., 1997, 171: 208
27. [27]
  27. Kijlstra, W. S.; Brand, D. S.; Smit, H. I.; Poels, E. K.; Blief, A. J. Catal., 1997, 171: 219
28. [28]
  28. Wagner, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F.; Mullenberg, G. E. Handbook of X-ray photoelectron spectroscopy. Eden Prairie: Perking Elmer Corp., 1979
29. [29]
  29. Busca, G.; Larrubia, M. A.; Arrighi, L.; Ramis, G. Catal. Today, 2005, 107-108: 139
30. [30]
  30. Alemany, L. J.; Lietti, L.; Ferlazzo, N.; Forzatti, P.; Busca, G.; Giamello, E.; Bregani, F. J. Catal., 1995, 155: 117
31. [31]
  31. Lietti, L.; Alemany, J. L.; Forzatti, P. Catal. Today, 1996, 29: 143
32. [32]
  32. Lietti, L. Appl. Catal. B-Environ., 1996, 10(4): 281
33. [33]
  33. Ramis, G.; Cristiani, C.; Elmi, M. S.; Villa, P. L.; Busca, G. J. Mol. Catal., 1990, 61: 319
34. [34]
  34. Kobayashi, M.; Miyoshi, K. Appl. Catal. B-Environ., 2007, 72: 253
1. [1]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
4. [4]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
5. [5]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
6. [6]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
7. [7]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
10. [10]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
11. [11]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
12. [12]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
13. [13]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
14. [14]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
15. [15]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
16. [16]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
17. [17]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
18. [18]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
19. [19]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
20. [20]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081

Get Citation

PDF

XML

Metrics

PDF Downloads(1322)
Abstract views(3181)
HTML views(91)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Tungsten Oxide on Selective Catalytic Reduction of NOx with NH3 over MnOx -CeO2 /ZrO2-TiO2Monolith Catalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Tungsten Oxide on Selective Catalytic Reduction of NO_x with NH₃ over MnO_x -CeO₂ /ZrO₂-TiO₂Monolith Catalyst