Citation: HUANG Yong-Xia, LAI Yue-Kun, SUN Lan, LIN Chang-Jian. Electrochemical Construction and Biological Performance of Micropatterned CaP Films[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2057-2060. doi: 10.3866/PKU.WHXB20100837 shu

Electrochemical Construction and Biological Performance of Micropatterned CaP Films

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Corresponding author: LIN Chang-Jian, cjlin@xmu.edu.cn
Received Date: 29 March 2010
Available Online: 30 June 2010
Fund Project: 国家自然科学基金-重大国际合作研究项目(20620130427) (20620130427)国家自然科学基金项目(20773100) (20773100) 国家重点基础研究发展规划项目(973) (2007CB935603) (973) (2007CB935603)国家科技部国际合作重大项目(2007DFC40440)资助 (2007DFC40440)

Based on surface molecule self-assembly and photocatalytic lithography techniques, superhydrophilic/superhydrophobic micropatterns were fabricated on TiO₂ films. Micropatterned calcium phosphate (CaP) films were successfully fabricated by the as-prepared superhydrophilic/superhydrophobic template combined with the electrochemical deposition method. Scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) indicated that micropatterned CaP films with a high spatial resolution could be constructed using the superhydrophilic/superhydrophobic micropatterns as templates. In vitro MG-63 cell tests of the micropatterned CaP films showed that the cells selectively adhered to the tiny CaP film units, which is promising for the control of the adherent growth of the cells on the tiny units and to achieve a high throughput evaluation of the cell behavior.
- Titania,
- Superhydrophilic/superhydrophobic,
- CaP film,
- Micropattern,
- Biological performance
1. [1]
  
  [1]. Discher, D. E.; Janmey, P.; Wang, Y. L. Science, 2005, 310: 1139
2. [2]
  [2]. Whitesides, G. M.; Ostuni, E.; Takayama, S. Annu. Rev. Biomed. Eng., 2001, 3: 335
3. [3]
  [3]. Wan, Y. Q.; Wang, Y.; Liu, Z. M. Biomaterials, 2005, 26: 4453
4. [4]
  [4]. Li, Y.; Yuan, B.; Ji, H. Angew. Chem. Int. Edit., 2007, 46: 1094
5. [5]
  [5]. Sun, J. G.; Graeter, S. V.; Yu, L. Biomacromolecules, 2008, 9: 2569
6. [6]
  [6]. Harrison, R. G. Anat. Rec., 1912, 6: 181
7. [7]
  [7]. Dusseiller, M. R.; Schlaepfer, D.; Koch, M. Biomaterials, 2005, 26: 5917
8. [8]
  [8]. Lussi, J. W.; Michel, R.; Reviakine, I. Prog. Surf. Sci., 2004, 76: 55
9. [9]
  [9]. Schindler, M.; Ahmed, I.; Kamal, J. Biomaterials, 2005, 26: 5624
10. [10]
  [10]. Hahn, M. S.; Miller, J. S.; West, J. L. Adv. Mater., 2006, 18: 2679
11. [11]
  [11]. Miller, J. S.; Béthencourt, M. I.; Hahn, M. Biotechnol. Bioeng., 2006, 93: 1060
12. [12]
  [12]. Lee, S. H.; Moon, J. J.; West, J. L. Biomaterials, 2008, 29: 2962
13. [13]
  [13]. Teixeira, A. I.; Nealey, P. F.; Murphy, C. J. J. Biomed. Mater. Res. A, 2004, 71A: 369
14. [14]
  [14]. Charest, J. L.; Eliason, M. T.; Garcia, A. J. Biomaterials, 2006, 27: 2487
15. [15]
  [15]. Revzin, A.; Tompkins, R. G.; Toner, M. Langmuir, 2003, 19: 9855
16. [16]
  [16]. Hui, E. E.; Bhatia, S. N. Langmuir, 2007, 23: 4103
17. [17]
  [17]. Tadanaga, K.; Morinaga, J.; Matsuda, A.; Minam, T. Chem. Mater., 2000, 12: 590
18. [18]
  [18]. Zhang, X. T.; Sato, O.; Fujishima, A. Langmuir, 2004, 20: 6065
19. [19]
  [19]. Lai, Y. K.; Lin, C. J.; Wang, H.; Huang, J. Y.; Zhuang, H. F.; Sun, L. Electrochem. Commun., 2008, 10: 387
20. [20]
  [20]. Lai, Y. K.; Huang, J. Y.; ng, J. J.; Huang, Y. X.; Wang, C. L.; Chen, Z.; Lin, C. J. J. Electrochem. Soc., 2009, 156(11): D480
21. [21]
  [21]. Lai, Y. K.; Lin, Z. Q.; Huang, J. Y.; Sun, L.; Chen, Z.; Lin, C. J. New J. Chem., 2010, 34(1): 44
22. [22]
  [22]. Lai, Y. K.; Huang, Y. X.; Wang, H.; Huang, J. Y.; Chen, Z.; Lin, C. J. Colloids Surf. B, 2010, 76: 117
23. [23]
  [23]. Lai, Y. K.; Sun, L.; Zuo, J.; Lin, C. J. Acta Phys. -Chim. Sin., 2004, 20:1063. [赖跃坤, 孙岚, 左娟, 林昌健. 物理化学学报, 2004, 20: 1063
24. [24]
  [24]. Wang, H.; Lin, C. J.; Zhao, D. M.; Hu, R.; Zhang, F.; Lin, L. W. J. Biomed. Mater. Res. Part A, 2008, 87: 698
1. [1]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
2. [2]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
3. [3]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
4. [4]
  Jiatong Li , Linlin Zhang , Peng Huang , Chengjun Ge . Carbon bridge effects regulate TiO₂–acrylate fluoroboron coatings for efficient marine antifouling. Chinese Chemical Letters, 2025, 36(2): 109970-. doi: 10.1016/j.cclet.2024.109970
5. [5]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
6. [6]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
7. [7]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
8. [8]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
10. [10]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
11. [11]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
12. [12]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
13. [13]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
14. [14]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
15. [15]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
16. [16]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
17. [17]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
18. [18]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
19. [19]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
20. [20]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262

Get Citation

PDF

XML

Metrics

PDF Downloads(1313)
Abstract views(2658)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142