Citation: HUANG Yong-Xia, LAI Yue-Kun, SUN Lan, LIN Chang-Jian. Electrochemical Construction and Biological Performance of Micropatterned CaP Films[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2057-2060. doi: 10.3866/PKU.WHXB20100837 shu

Electrochemical Construction and Biological Performance of Micropatterned CaP Films

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Corresponding author: LIN Chang-Jian, cjlin@xmu.edu.cn
Received Date: 29 March 2010
Available Online: 30 June 2010
Fund Project: 国家自然科学基金-重大国际合作研究项目(20620130427) (20620130427)国家自然科学基金项目(20773100) (20773100) 国家重点基础研究发展规划项目(973) (2007CB935603) (973) (2007CB935603)国家科技部国际合作重大项目(2007DFC40440)资助 (2007DFC40440)

Based on surface molecule self-assembly and photocatalytic lithography techniques, superhydrophilic/superhydrophobic micropatterns were fabricated on TiO₂ films. Micropatterned calcium phosphate (CaP) films were successfully fabricated by the as-prepared superhydrophilic/superhydrophobic template combined with the electrochemical deposition method. Scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) indicated that micropatterned CaP films with a high spatial resolution could be constructed using the superhydrophilic/superhydrophobic micropatterns as templates. In vitro MG-63 cell tests of the micropatterned CaP films showed that the cells selectively adhered to the tiny CaP film units, which is promising for the control of the adherent growth of the cells on the tiny units and to achieve a high throughput evaluation of the cell behavior.
- Titania,
- Superhydrophilic/superhydrophobic,
- CaP film,
- Micropattern,
- Biological performance
1. [1]
  
  [1]. Discher, D. E.; Janmey, P.; Wang, Y. L. Science, 2005, 310: 1139
2. [2]
  [2]. Whitesides, G. M.; Ostuni, E.; Takayama, S. Annu. Rev. Biomed. Eng., 2001, 3: 335
3. [3]
  [3]. Wan, Y. Q.; Wang, Y.; Liu, Z. M. Biomaterials, 2005, 26: 4453
4. [4]
  [4]. Li, Y.; Yuan, B.; Ji, H. Angew. Chem. Int. Edit., 2007, 46: 1094
5. [5]
  [5]. Sun, J. G.; Graeter, S. V.; Yu, L. Biomacromolecules, 2008, 9: 2569
6. [6]
  [6]. Harrison, R. G. Anat. Rec., 1912, 6: 181
7. [7]
  [7]. Dusseiller, M. R.; Schlaepfer, D.; Koch, M. Biomaterials, 2005, 26: 5917
8. [8]
  [8]. Lussi, J. W.; Michel, R.; Reviakine, I. Prog. Surf. Sci., 2004, 76: 55
9. [9]
  [9]. Schindler, M.; Ahmed, I.; Kamal, J. Biomaterials, 2005, 26: 5624
10. [10]
  [10]. Hahn, M. S.; Miller, J. S.; West, J. L. Adv. Mater., 2006, 18: 2679
11. [11]
  [11]. Miller, J. S.; Béthencourt, M. I.; Hahn, M. Biotechnol. Bioeng., 2006, 93: 1060
12. [12]
  [12]. Lee, S. H.; Moon, J. J.; West, J. L. Biomaterials, 2008, 29: 2962
13. [13]
  [13]. Teixeira, A. I.; Nealey, P. F.; Murphy, C. J. J. Biomed. Mater. Res. A, 2004, 71A: 369
14. [14]
  [14]. Charest, J. L.; Eliason, M. T.; Garcia, A. J. Biomaterials, 2006, 27: 2487
15. [15]
  [15]. Revzin, A.; Tompkins, R. G.; Toner, M. Langmuir, 2003, 19: 9855
16. [16]
  [16]. Hui, E. E.; Bhatia, S. N. Langmuir, 2007, 23: 4103
17. [17]
  [17]. Tadanaga, K.; Morinaga, J.; Matsuda, A.; Minam, T. Chem. Mater., 2000, 12: 590
18. [18]
  [18]. Zhang, X. T.; Sato, O.; Fujishima, A. Langmuir, 2004, 20: 6065
19. [19]
  [19]. Lai, Y. K.; Lin, C. J.; Wang, H.; Huang, J. Y.; Zhuang, H. F.; Sun, L. Electrochem. Commun., 2008, 10: 387
20. [20]
  [20]. Lai, Y. K.; Huang, J. Y.; ng, J. J.; Huang, Y. X.; Wang, C. L.; Chen, Z.; Lin, C. J. J. Electrochem. Soc., 2009, 156(11): D480
21. [21]
  [21]. Lai, Y. K.; Lin, Z. Q.; Huang, J. Y.; Sun, L.; Chen, Z.; Lin, C. J. New J. Chem., 2010, 34(1): 44
22. [22]
  [22]. Lai, Y. K.; Huang, Y. X.; Wang, H.; Huang, J. Y.; Chen, Z.; Lin, C. J. Colloids Surf. B, 2010, 76: 117
23. [23]
  [23]. Lai, Y. K.; Sun, L.; Zuo, J.; Lin, C. J. Acta Phys. -Chim. Sin., 2004, 20:1063. [赖跃坤, 孙岚, 左娟, 林昌健. 物理化学学报, 2004, 20: 1063
24. [24]
  [24]. Wang, H.; Lin, C. J.; Zhao, D. M.; Hu, R.; Zhang, F.; Lin, L. W. J. Biomed. Mater. Res. Part A, 2008, 87: 698
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沈阳化工大学材料科学与工程学院沈阳 110142