Citation: YAN Liang-Liang, JIANG Qing-Ning, LIU De-Yu, ZHONG Yan, WEN Fei-Peng, DENG Xiao-Cong, ZHONG Qi-Ling, REN Bin, TIAN Zhong-Qun. Electrocatalytic Oxidation of Formic Acid on Pt-Se HollowNanosphere Modified Glassy Carbon Electrodes[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2337-2342. doi: 10.3866/PKU.WHXB20100835 shu

Electrocatalytic Oxidation of Formic Acid on Pt-Se HollowNanosphere Modified Glassy Carbon Electrodes

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 11 March 2010
Available Online: 30 June 2010
Fund Project: 国家自然科学基金(20663002) (20663002)厦门大学固体表面物理化学国家重点实验室基金(200511)资助项目 (200511)

Platinum-selenium and platinum hollow nanospheres (denoted as (Pt-Se)_HN and Pt_HN, respectively) with different coverages of Se (θ_Se) (θ_Se=0.49, 0.39, 0.06, 0) were prepared using amorphous Se colloids as a sacrificial template. Sulfite was used to completely remove Se from the core-shell nanoparticles. The morphology and structure of the nanoparticles were characterized using various methods, which revealed a hollow structure with a very uniform size distribution and a porous structure on the shell. Assembly of Pt-Se hollownanospheres ((Pt-Se)_HN) on a glassy carbon (GC) electrode produced a (Pt-Se)_HN/GC electrode. The electrocatalytic activity of the electrode for the oxidation of formic acid was compared with the Pt_HN/GCand commercial Pt/C/GCelectrodes by cyclic voltammetry and chronoamperometry. The activity followed the order: (Pt-Se)_HN/GC > Pt_HN/GC >Pt/C/GC. The electrooxidation of formic acid on (Pt-Se)_HN/C, Pt_HN/C, and Pt/C catalysts follows different mechanisms: the former tends to directly oxidize formic acid to CO₂ via weakly adsorbed intermediates, and the latter two via both weakly and strongly adsorbed intermediates. (Pt-Se)_HN with a suitable seleniumcontent showed optimal electrocatalytic activity for the oxidation of formic acid.
- Electrocatalysis,
- Pt-Se hollow nanosphere,
- (Pt-Se)HN/GC electrode,
- Formic acid,
- Oxidation
1. [1]
  
  1. Mao, Z. Q. Fuel cell. Beijing: Chemical Industry Press, 2005: 1-31[毛宗强.燃料电池. 北京:化学工业出版社, 2005: 1-31]
2. [2]
  2. Yi, B. L. Fuel cell: foundmental, technology, application. Beijing:Chemical Industry Press, 2003: 1-7 [衣宝廉. 燃料电池:原理·技术·应用. 北京:化学工业出版社, 2003: 1-7]
3. [3]
  3. Lu, T. H. High-Technology and Industrialization, 2008, 11: 70[陆天虹.高技术与工业, 2008, 11: 70]
4. [4]
  4. Hong, P.; Liao, S. J. Modern Chemical Industry, 2009, 8: 15[洪平, 廖世军.现代化工, 2009, 8: 15]
5. [5]
  5. Ha, S.; Dunbar, Z.; Masel, R. I. J. Power Sources, 2006, 158: 129
6. [6]
  6. Yang, G. X.; Chen, T. T.; Tang, Y.W.; Lu, T. H. Acta Phys. -Chim.Sin., 2009, 25(12): 2450 [杨改秀,陈婷婷,唐亚文,陆天虹.物理化学学报, 2009, 25(12): 2450]
7. [7]
  7. Yu, X. W.; Pickup, P. G. J. Power Sources, 2008, 182: 124
8. [8]
  8. Zhang, S. S.; Yuan, X. Z.; Hin, J. N. C.; Wang, H. J.; Friedrich, K.A.; Schulze, M. J. Power Sources, 2009, 194: 588
9. [9]
  9. Motoo, S. Proceedings of the Symposium chemistry and physics ofelectrocatalysis. McIntyre, J. D. E.;Weaver, M. J.; Yeager, E. B. Eds.San Francisco, 1983, Princeton, NJ: The Electrochemical Society,1984: 331
10. [10]
  10. Rice, C.; Ha, S.; Masel, R. I.;Waszczuk, P.; Wieckowski, A.;Barnard, T. J. Power Sources, 2002, 111: 83
11. [11]
  11. Rice, C.; Ha, S.; Masel, R. I.;Wieckowski, A. J. Power Sources,2003, 115: 229
12. [12]
  12. Uhm, S.; Lee, H. J.; Kwon, Y.; Lee, J. Angew. Chem. Int. Edit.,2008, 47: 10163
13. [13]
  13. Angerstein-Kozlowska, H.; MacDougall, B.; Conway, B. E.J. Electrochem. Soc., 1973, 120: 756
14. [14]
  14. Adzic, R. R.; Simic, D. N.; Despic, A. R.; Drazic, D. M.J. Electroanal. Chem., 1975, 65: 587
15. [15]
  15. Zhang, H. X.; Chao, W.; Wang, J. Y.; Zhai, J. J.; Cai, W. B.J. Phys. Chem. C, 2010, 114: 6446
16. [16]
  16. Llorca, M. J.; Herrero, E.; Feliu, J. M.; Aldaz, A. J. Electroanal.Chem., 1994, 373: 217
17. [17]
  17. Shibata, M.; Motoo, S. J. Electroanal. Chem., 1987, 229: 385
18. [18]
  18. Shibata, M.; Takahashi, O.; Motoo, S. J. Electroanal. Chem., 1988,249: 253
19. [19]
  19. Xia, X. H.; Iwasita, T. J. Electrochem. Soc., 1993, 140: 2559
20. [20]
  20. Chizhikov, D. M.; Shchastlivyi, V. P. Seleniumand selenides(translated fromthe Russion by Elkin, E. M.). London andWellingborough: Collet忆s LTD, 1968: 40
21. [21]
  21. Wang, R. F.; Liao, S. J.; Liu, H. Y.; Meng, H. J. Power Sources,2007, 171: 471
22. [22]
  22. Trasatti, S.; Petrii, O. A. Pure Appl. Chem., 1991, 63: 711
23. [23]
  23. Wu, Y. N.; Liao, S. J. Acta Phys. -Chim. Sin., 2010, 26(3): 669[吴燕妮,廖世军.物理化学学报, 2010, 26(3): 669]
24. [24]
  24. Leiva, E.; Iwasita, T.; Herrero, E.; Feliu, J. M. Langmuir, 1997,13: 6287
25. [25]
  25. Samjeské, G.; Osawa, M. Angew. Chem. Int. Edit., 2005, 44: 5694
26. [26]
  26. Park, I. S.; Lee, K. S.; Choi, J. H.; Park, H. Y.; Sung, Y. E. J. Phys.Chem. C, 2007, 111: 19126
27. [27]
  27. Park, S.; Xie, Y.; Weaver, M. J. Langmuir, 2002, 18: 5792
28. [28]
  28. Kristian, N.; Yan, Y.; Wang, X. Chem. Commun., 2008: 353
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