Citation: GUO Pei-Zhi, HAN Guang-Ting, WANG Bao-Yan, ZHAO Xiu-Song. Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2557-2562. doi: 10.3866/PKU.WHXB20100834 shu

Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes

1.
1. Laboratory of New Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, School of Chemistry, Chemical Engineering and Environmental Sciences, Qingdao University, Qingdao 266071, Shandong Province, P. R. China;
2. Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, ingapore 117576

Received Date: 3 February 2010
Available Online: 30 June 2010
Fund Project: 国家自然科学基金(20803037) (20803037) 山东省博士基金(2007BS04022) (2007BS04022)山东省自然科学基金(ZR2009BM013) (ZR2009BM013)

Cu₇S₄ nanotubes were synthesized using a biomolecule DL-methionine-assisted hydrothermal method. The morphology and phase of the products can be controlled by adjusting the reaction parameters such as synthesis temperature, reaction time and the molar ratio of the reagents. We found that uniform polycrystal Cu₇S₄ nanotubes with diameters of 100-600 nm and lengths of 40-100 μm can be controllably synthesized at 200^oC when the molar ratio of Cu(NO3)2 to DL-methionine in the synthesis system is 1:2. Similar Cu₇S₄ nanotubes can be obtained from D-or L- methionine systems. The bandgap energy of the Cu₇S₄ nanotubes was measured to be about 2.88 eV, a remarkable blue shift in comparison with that of bulk Cu₇S₄ (2.0 eV). We discussed the relationship between the products and the functional groups in the amphiphilic biomolecules. On the basis of our experimental data, we proposed that the Cu₇S₄ nanotubes were formed versus a self-sacrificing template mechanism.
- Hydrothermal synthesis,
- Cu₇S₄ nanotube,
- Methionine,
- Biomolecule
1. [1]
  
  1. Iijima, S. Nature, 1991, 354: 56
2. [2]
  2. ldberger, J.; He, R.; Zhang, Y.; Lee, S. W.; Yan, H.; Choi, H. J.; Yang, P. D. Nature, 2003, 422: 599
3. [3]
  3. Ebbesen, T. W.; Ajayan, P. M. Nature, 1992, 358: 220
4. [4]
  4. Yuan, Z. H.; Huang, H.; Liu, L.; Fan, S. S. Chem. Phys. Lett., 2001, 345: 39
5. [5]
  5. Hacohen, Y. R.; Grunbaum, E.; Tenne, R.; Sloan, J.; Hutchison, J. L. Nature, 1998, 395: 336
6. [6]
  6. Wu, C. Y.; Yu, S. H.; Chen, S. F.; Liu, G. N.; Liu, B. H. J. Mater. Chem., 2006, 16: 3326
7. [7]
  7. Yoshimura, M.; Somiya, S. Mater. Chem. Phys., 1991, 61: 1
8. [8]
  8. Xu, A.W.; Fang, Y. P.; You, L. P.; Liu, H. Q. J. Am. Chem. Soc., 2003, 125: 1494
9. [9]
  9. Yamamoto, T.; Kubota, E.; Taniguchi, A.; Dev, S.; Tanaka, K.; Osakada, K. Chem. Mater., 1992, 4: 570
10. [10]
  10. Behboudnia, M.; Khanbabaee, B. J. Cryst. Growth, 2007, 304: 158
11. [11]
  11. Guo, P. Z.; Li, H. L.; Yu, J. Q.; Sun, H.; Zhao, X. S. Chin. J. Inorg. Chem., 2008, 24: 1387 [郭培志,李洪亮, 于建强,孙红,赵修松. 无机化学学报, 2008, 24: 1387]
12. [12]
  12. Zhang, W. X.; Xu, J.; Yang, Z. H.; Ding, S. X. Chem. Phys. Lett., 2007, 434: 256
13. [13]
  13. Li, B. X.; Xie, Y.; Xue, Y. J. Phys. Chem. C, 2007, 111: 12181
14. [14]
  14. Sigman Jr., M. B.; Korgel, B. A. Chem. Mater., 2005, 17: 1655
15. [15]
  15. Zhao, N. N.; Qi, L. M. Adv. Mater., 2006, 18: 359
16. [16]
  16. Cao, H. L.; Qian, X. F.; Wang, C.; Ma, X. D.; Yin, J.; Zhu, Z. K. J. Am. Chem. Soc., 2005, 127: 16024
17. [17]
  17. An, C. H.; Wang, S. T.; He, J.; Wang, Z. X. J. Cryst. Growth, 2008, 310: 266
18. [18]
  18. Tan, C. H.; Zhu, Y. L.; Lu, R.; Xue, P. C.; Bao, C. Y.; Liu, X. L.; Fei, Z. P.; Zhao, Y. Y. Mater. Chem. Phys., 2005, 91: 44
19. [19]
  19. Zhang, Y. C.; Qiao, T.; Hu, X. Y.; Zhou, W. D. Mater. Res. Bull., 2005, 40: 1696
20. [20]
  20. Lu, Q. Y.; Gao, F.; Zhao, D. Y. Nano Lett., 2002, 2: 725
21. [21]
  21. Tong, H.; Zhu, Y. J.; Yang, L. X.; Li, L.; Zhang, L. Angew. Chem. Int. Edit., 2006, 45: 7739
22. [22]
  22. Lu, Q. Y.; Gao, F.; Komareni, S. J. Am. Chem. Soc., 2004, 126: 54
23. [23]
  23. Liu, S. Z.; Xiong, S. L.; Bao, K. Y.; Cao, J.; Qian, Y. T. J. Phys. Chem. C, 2009, 113: 13002
24. [24]
  24. Znhn, S.; Canary, J. W. Science, 2000, 288: 1404
25. [25]
  25. Silverstein, R. M.; Webster, F. X; Kiemle, D. J. Spectrometric identification of organic compounds. 7th ed. Pennsylvanian: Lehigh Press, 2005: 82-108
26. [26]
  26. Guo, P. Z.; Liu, M. H.; Nakahara, H.; Ushida, K. ChemPhysChem, 2006, 7: 385
27. [27]
  27. Zhang, W.; Lu, C.; Zou, Y.; Xie, J.; Ren, X.; Zhu, H.; Meng, Q. J. Colloid Interface Sci., 2002, 249: 301
28. [28]
  28. Bebin, P.; Prud忆homme, R. E. Chem. Mater., 2003, 15: 965
29. [29]
  29. Chen, H. Y.; Chen, L.; Lin, J.; Tan, K. L.; Li, J. Inorg. Chem., 1997, 36: 1417
30. [30]
  30. Zhang, Y.; Qiao, Z. P.; Chen. X. M. J. Solid State Chem., 2002, 167: 249
31. [31]
  31. Zhang, F.; Wong, S. S. Chem. Mater., 2009, 21: 4541
32. [32]
  32. Roy, P.; Mondal, K.; Srivastava, S. K. Cryst. Growth Des., 2008, 8: 1530
33. [33]
  33. Yamagishi, A. J. Phys. Chem., 1981, 85: 2665
34. [34]
  34. Adams, A.; Bucknall, R. M.; Fenton, D. E.; Garcia, M.; Oakes, J. Polyhedron, 1998, 17: 4169
35. [35]
  35. Burford, A.; Eleman, M. D.; Mahony, D. E.; Morash, M. Chem. Commun., 2003: 146
36. [36]
  36. Klokkenburg, M.; Vonk, C.; Claesson, E. M.; Meeldijk, J. D.; Erne, B. H.; Philipse, A. P. J. Am. Chem. Soc., 2004, 126: 16706
37. [37]
  37. Butter, K.; Bomans, P. H. H.; Frederik, P. M.; Vroege, G. J.; Philipse, A. P. Nat. Mater., 2003, 2: 88
38. [38]
  38. Konishi, Y.; Nomura, T.; Satoh, D. Ind. Eng. Chem. Res., 2004, 43: 2088
1. [1]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
2. [2]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
3. [3]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
6. [6]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
7. [7]
  Feiyang Liu , Liuhong Song , Miaoyu Fu , Zhi Zheng , Gang Xie , Junlong Zhao . Tryptophan’s Employment Journey. University Chemistry, 2024, 39(9): 16-21. doi: 10.12461/PKU.DXHX202404037
8. [8]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
9. [9]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
10. [10]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
11. [11]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
12. [12]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
13. [13]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
14. [14]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
15. [15]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
16. [16]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
17. [17]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
18. [18]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
19. [19]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
20. [20]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371

Get Citation

PDF

XML

Metrics

PDF Downloads(1273)
Abstract views(2752)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu7S4 Nanotubes

Metrics

通讯作者: 陈斌, bchen63@163.com

Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes