Citation: GUO Pei-Zhi, HAN Guang-Ting, WANG Bao-Yan, ZHAO Xiu-Song. Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2557-2562. doi: 10.3866/PKU.WHXB20100834 shu

Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes

1.
1. Laboratory of New Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, School of Chemistry, Chemical Engineering and Environmental Sciences, Qingdao University, Qingdao 266071, Shandong Province, P. R. China;
2. Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, ingapore 117576

Received Date: 3 February 2010
Available Online: 30 June 2010
Fund Project: 国家自然科学基金(20803037) (20803037) 山东省博士基金(2007BS04022) (2007BS04022)山东省自然科学基金(ZR2009BM013) (ZR2009BM013)

Cu₇S₄ nanotubes were synthesized using a biomolecule DL-methionine-assisted hydrothermal method. The morphology and phase of the products can be controlled by adjusting the reaction parameters such as synthesis temperature, reaction time and the molar ratio of the reagents. We found that uniform polycrystal Cu₇S₄ nanotubes with diameters of 100-600 nm and lengths of 40-100 μm can be controllably synthesized at 200^oC when the molar ratio of Cu(NO3)2 to DL-methionine in the synthesis system is 1:2. Similar Cu₇S₄ nanotubes can be obtained from D-or L- methionine systems. The bandgap energy of the Cu₇S₄ nanotubes was measured to be about 2.88 eV, a remarkable blue shift in comparison with that of bulk Cu₇S₄ (2.0 eV). We discussed the relationship between the products and the functional groups in the amphiphilic biomolecules. On the basis of our experimental data, we proposed that the Cu₇S₄ nanotubes were formed versus a self-sacrificing template mechanism.
- Hydrothermal synthesis,
- Cu₇S₄ nanotube,
- Methionine,
- Biomolecule
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Biomolecule-Assisted Hydrothermal Synthesis and Optical Properties of Cu₇S₄ Nanotubes