Citation: JIANG Yong, QIU Rong. Numerical Analysis of the Effect of Carbon Monoxide Addition on Soot Formation in an Acetylene/Air Premixed Flame[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2121-2129. doi: 10.3866/PKU.WHXB20100823 shu

Numerical Analysis of the Effect of Carbon Monoxide Addition on Soot Formation in an Acetylene/Air Premixed Flame

JIANG Yong ,
QIU Rong

1.
State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, P. R. China

Received Date: 3 February 2010
Available Online: 25 June 2010
Fund Project: 国家自然科学基金(50876097) (50876097)教育部新世纪优秀人才支持计划(NCET-06-0546)资助项目 (NCET-06-0546)

The effect of carbon monoxide addition on soot formation in an acetylene/air premixed flame was investigated by detailed numerical simulation. This work focused on both the temperature effect and chemical effect of carbon monoxide addition on soot formation by comparing the results of flames with different CO contents. We find that the addition of carbon monoxide consistently reduces the formation of soot. The soot volume fraction and nucleation rate increase until a threshold temperature is reached and then decrease as the temperature increases. Considering that soot formation took place at the active site by H-abstraction mechanism, the addition of CO promotes the formation of soot. The concentration of H radicals increases and the concentration of OH radicals decreases because of the increased forward rate of the reaction OH+CO=CO₂+H. For soot formation to occur by the C-addition mechanism, the degradation rates of C₂H₂ tends to decrease and this promotes the formation of soot along with CO addition. On the other hand, the addition of CO may greatly reduce the volume fraction of C₂H₂ in fuel resulting in a lower surface growth rate.
- Soot,
- Acetylene,
- Carbon monoxide,
- Fuel enrichment,
- Modeling
1. [1]
  
  [1]. Yamamoto, M.; Duan, S.; Senkan, S. Combust. Flame, 2007, 151: 532
2. [2]
  [2]. Kunioshi, N.; Komori, S.; Fukutani, S. Combust. Flame, 2006, 147: 1
3. [3]
  [3]. Joo, H. I.; Gülder, õ. L. Proc. Combust. Inst., 2009, 32: 769
4. [4]
  [4]. Kim, Y.; Hatsushika, H.; Muskett, R. R.; Yamazaki, K. Atmos. Environ., 2005, 39: 3513
5. [5]
  [5]. Xu, F.; Sunderland, P. B.; Faeth, G. M. Combust. Flame, 1997, 108: 471
6. [6]
  [6]. Guo, H.; Smallwood, G. J.; Liu, F.; Ju, Y.; Gülder, õ. L. Proc. Combust. Inst., 2005, 30: 303
7. [7]
  [7]. Ren, J. Y.; Qin, W.; E lfopoulos, F. N.; Tsotsis, T. T. Combust. Flame, 2001, 124: 717
8. [8]
  [8]. Coppens, F. H. V.; Ruyck, J. D.; Konnov, A. A. Combust. Flame, 2007, 149: 409
9. [9]
  [9]. Guo, H.; Smallwood, G. J.; Gülder, õ. L. Proc. Combust. Inst., 2007, 31: 1197
10. [10]
  [10]. Wu, C. Y.; Chao, Y. C.; Cheng, T. S.; Chen, C. P.; Ho, C. T. Combust. Flame, 2009, 156: 362
11. [11]
  [11]. Gülder, õ. L.; Snelling, D. R.; Sawchuk, R. A. Proc. Combust. Inst., 1996, 26: 2351
12. [12]
  [12]. Glassman, I. Proc. Combust. Inst., 1998, 27: 1589
13. [13]
  [13]. Guo, H.; Liu, F.; Smallwood, G. J.; Gülder, õ. L. Proc. Combust. Inst., 2002, 29: 2359
14. [14]
  [14]. Guo, H.; Liu, F.; Smallwood, G. J.; Gülder, õ. L. Combust. Flame, 2006, 145: 324
15. [15]
  [15]. Pandey, P.; Pundir, B. P.; Panigrahi, P. K. Combust. Flame, 2007, 148: 249
16. [16]
  [16]. Guo, H.; Thomson, K. A.; Smallwood, G. J. Combust. Flame, 2009, 156: 1135
17. [17]
  [17]. Du, D. X.; Axelbaum, R. L.; Law, C. K. Combust. Flame, 1995, 102: 11
18. [18]
  [18]. Bhatt, J. S.; Lindstedt, R. P. Proc. Combust. Inst., 2009, 32: 713
19. [19]
  [19]. Appel, J.; Bockhorn, H.; Frenklach, M. Combust. Flame, 2000, 121: 122
20. [20]
  [20]. Kazakov, A.; Frenklach, M. Combust. Flame, 1998, 114: 484
21. [21]
  [21]. Frenklach, M. Chem. Eng. Sci., 2002, 57: 2229
22. [22]
  [22]. Lindstedt, R. P.; Louloudi, S. A. Proc. Combust. Inst., 2005, 30: 775
23. [23]
  [23]. Zhao, B.; Yang, Z.; Johnston, M. V.; Wang, H.; Wexler, A. S.; Balthasar, M.; Kraft, M. Combust. Flame, 2003, 133: 173
24. [24]
  [24]. Smooke, M. D.; McEnally, C. S.; Pfefferle, L. D.; Hall, R. J.; Colket, M. B. Combust. Flame, 1999, 117: 117
25. [25]
  [25]. Park, S. H.; Rogak, S. N.; Bushe, W. K.; Wen, J. Z.; Thomson, M. J. Combust. Theor. Model., 2005, 9: 499
26. [26]
  [26]. Zhang, Q.; Guo, H.; Liu, F.; Smallwood, G. J.; Thomson, M. J. Proc. Combust. Inst., 2009, 32: 761
27. [27]
  [27]. Mueller, M. E.; Blanquart, G.; Pitsch, H. Proc. Combust. Inst., 2009, 32: 785
28. [28]
  [28]. Blanquart, G.; Pitsch, H. Combust. Flame, 2009, 156: 1614
29. [29]
  [29]. Jiang, Y.; Qiu, R.; Fan, W. C. Journal of Combustion Science and Technology, 2005, 11:218. [蒋勇, 邱榕, 范维澄. 燃烧科学与技术, 2005, 11: 218]
30. [30]
  [30]. Bowman, C. T.; Hanson, R. K.; Davidson, D. F.; Gardiner, W. C.; Lissianski, V.; Smith, G. P.; lden, D. M.; Frenklach, M.; ldenberg, M. GRI 2.11 detailed mechanism. http://www.me.berkeley.edu/gri_mech/, Berkley CA, USA
31. [31]
  [31]. Marinov, N. M.; Pitz, W. J.; Westbrook, C. K.; Vincitore, A. M.; Castaldi, M. J.; Senkan, S. M.; Melius, C. F. Combust. Flame, 1998, 114: 192
32. [32]
  [32]. SkjΦth-Rasmussen, M.; Glarborg, P.; Φstberg, M.; Johannessen, J.; Livbjerg, H.; Jensen, A.; Christensen, T. Combust. Flame, 2004, 136: 91
33. [33]
  [33]. Koylü, U. õ.; Faeth, G. M.; Farias, T. L.; Carvalho, M. G. Combust. Flame, 1995, 100: 621
34. [34]
  [34]. Kee, R. J.; Rupley, F. M.; Miller, J. A. Chemkin-II: a Fortran chemical kinetics package for the analysis of gas-phase chemical kinetics. Report SAND89-8009, Sandia, 1989
35. [35]
  [35]. Kee, R. J.; Grcar, J. F.; Smooke, M. D.; Miller, J. A. PREMIX: a Fortran program for modeling steady laminar one-dimensional premixed flames. Report SAND85-8240, Sandia, 1985
36. [36]
  [36]. Wang, H.; Frenklach, M. Combust. Flame, 1997, 110: 173
37. [37]
  [37]. Wieschnowsky, U.; Bockhorn, H.; Fetting, F. Proc. Combust. Inst., 1989, 22: 343
38. [38]
  [38]. Castaldi, M. J.; Senkaw, S. M. Combust. Sci. Technol., 1996, 116: 167
39. [39]
  [39]. Tregrossi, A.; Ciajolo, A.; Barbella, R. Combust. Flame, 1999, 117: 553
1. [1]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
2. [2]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
3. [3]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
4. [4]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
5. [5]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
6. [6]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
7. [7]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
8. [8]
  Qiying Xia , Guokui Liu , Yunzhi Li , Yaoyao Wei , Xia Leng , Guangli Zhou , Aixiang Wang , Congcong Mi , Dengxue Ma . Construction and Practice of “Teaching-Learning-Assessment Integration” Model Based on Outcome Orientation: Taking “Structural Chemistry” as an Example. University Chemistry, 2024, 39(10): 361-368. doi: 10.3866/PKU.DXHX202311007
9. [9]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
10. [10]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
11. [11]
  Hongsheng Tang , Yonghe Zhang , Dexiang Wang , Xiaohui Ning , Tianlong Zhang , Yan Li , Hua Li . A Wonderful Journey through the Kingdom of Hazardous Chemicals. University Chemistry, 2024, 39(9): 196-202. doi: 10.12461/PKU.DXHX202403098
12. [12]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
13. [13]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
14. [14]
  Liuchuang Zhao , Wenbo Chen , Leqian Hu . Discussion on Improvement of Teaching Contents about Common Evaluation Parameters in Analytical Chemistry. University Chemistry, 2024, 39(2): 379-391. doi: 10.3866/PKU.DXHX202308079
15. [15]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
16. [16]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
17. [17]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
18. [18]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
19. [19]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
20. [20]
  Jiangjuan Shao , Xuan Li , Jingdan Weng , Xiaolei Chen , Fei Xu , Yulu Ma , Nianguang Li , Shizhong Zheng . Improvement in the Experimental Teaching Design of Physical and Chemical Identification and Quantification of Mineral Drugs. University Chemistry, 2024, 39(10): 137-142. doi: 10.3866/PKU.DXHX202312079

Get Citation

PDF

XML

Metrics

PDF Downloads(1108)
Abstract views(3031)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142