Citation: CAO Qian-Yong, LU Xin, KUANG Ren-Yun, LI Zhi-Hua, YANG Zhen-Yu. Optical and Electrochemical Properties of Ethynyl-Bridged Ferrocenes with Electron Donor Groups[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2158-2162. doi: 10.3866/PKU.WHXB20100822 shu

Optical and Electrochemical Properties of Ethynyl-Bridged Ferrocenes with Electron Donor Groups

1.
1. Department of Chemistry, Nanchang University, Nanchang 330031, P. R. China;
2. College of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an 343009, Jiangxi Province, P. R. China

Received Date: 5 January 2010
Available Online: 25 June 2010
Fund Project: 国家自然科学基金(20963007) (20963007) 江西省教育厅自然科学基金(GJJ09074) (GJJ09074)

We present the synthesis, optical and electrochemical properties of three ethynyl-bridged ferrocenes with electron donor groups, Fc—C≡C—Ph-(p-OMe) (3a), Fc—C≡C—Ph-(p-NMe₂) (3b) and Fc—C≡C—Ph—(p-NPh₂) (3c). All three compounds show a Fe(II)Cp—C≡C—Ph—(p-R) (Cp=cyclopentadienyl) metal to ligand charge transition (MLCT) in 400-550 nm. Upon oxidation, 3a and 3c show a Cp—C≡C—Ph—(p-R)Fe(III) ligand to metal charge transition (LMCT) in the near-IR range (946 and 1044 nm). A reversible Fc⁺/Fc potential for 3a-3c and an irreversible Ph—NR⁺₂/Ph—NR₂ potential for 3b and 3c are observed by in the cyclic and differential pulse voltammetry. Finally, 3b shows an optical and electrochemical response upon protonation, with a red shift of the MLCT transition, an anodic shift of the Fc⁺/Fc potential, and disappearance of the Ph—NR⁺₂/Ph—NR₂ peak.
- Ferrocene,
- Protonation,
- Absorption spectrum,
- Oxidation,
- Electrochemistry
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